Print Email Facebook Twitter A highly selective and stable ZnO-ZrO2 solid solution catalyst for CO2 hydrogenation to methanol Title A highly selective and stable ZnO-ZrO2 solid solution catalyst for CO2 hydrogenation to methanol Author Wang, Jijie (Dalian University of Technology) Li, G. (TU Delft ChemE/Catalysis Engineering; Dalian University of Technology) Li, Zelong (Dalian University of Technology) Tang, Chizhou (Dalian University of Technology) Feng, Zhaochi (Dalian University of Technology) An, Hongyu (Chinese Academy of Sciences) Liu, Hailong (Dalian University of Technology) Liu, Taifeng (Dalian University of Technology) Li, Can (Dalian University of Technology) Date 2017 Abstract Although methanol synthesis via CO hydrogenation has been industrialized, CO2 hydrogenation to methanol still confronts great obstacles of low methanol selectivity and poor stability, particularly for supported metal catalysts under industrial conditions. We report a binary metal oxide, ZnO-ZrO2 solid solution catalyst, which can achieve methanol selectivity of up to 86 to 91% with CO2 single-pass conversion of more than 10% under reaction conditions of 5.0 MPa, 24,000 ml/(g hour), H2/CO2 = 3:1 to 4:1, 320° to 315°C. Experimental and theoretical results indicate that the synergetic effect between Zn and Zr sites results in the excellent performance. The ZnO-ZrO2 solid solution catalyst shows high stability for at least 500 hours on stream and is also resistant to sintering at higher temperatures. Moreover, no deactivation is observed in the presence of 50 ppm SO2 or H2S in the reaction stream. To reference this document use: http://resolver.tudelft.nl/uuid:219f5cf0-cc0e-442e-b627-7979ad910920 DOI https://doi.org/10.1126/sciadv.1701290 ISSN 2375-2548 Source Science Advances, 3 (10) Part of collection Institutional Repository Document type journal article Rights © 2017 Jijie Wang, G. Li, Zelong Li, Chizhou Tang, Zhaochi Feng, Hongyu An, Hailong Liu, Taifeng Liu, Can Li Files PDF e1701290.full.pdf 2.56 MB Close viewer /islandora/object/uuid%3A219f5cf0-cc0e-442e-b627-7979ad910920/datastream/OBJ/view