Molecular architecture control in synthesis of spherical Ln-containing nanoparticles

Zhang, W.; Martinelli, J.; Mayer, F.; Bonnet, C.S.; Szeremeta, F.; Djanashvili, K.

doi:doi:10.1039/C5RA09374K

Molecular architecture control in synthesis of spherical Ln-containing nanoparticles

Title

Molecular architecture control in synthesis of spherical Ln-containing nanoparticles

Author

Zhang, W.
Martinelli, J.
Mayer, F.
Bonnet, C.S.
Szeremeta, F.
Djanashvili, K.

Faculty

Applied Sciences

Department

Biotechnology

Date

2015-08-10

Abstract

Among the procedures to prepare lanthanide-containing nanoparticles a gap exists in the range between 5 and 40 nm. The miniemulsion technique presented here is intended to fill this discontinuity and offers a facile method that can be applied for the preparation of nanoparticles for various applications, e.g. medical imaging, optics and catalysis. We demonstrate that formation of nanodroplets under emulsion conditions is the key step in the size control of the nanoparticles. The type of surfactant and the nature of the dispersed and continuous phases strongly influence the interfacial activity and, consequently, the size of the final solid particles that result from the subsequent thermal decomposition. Moreover, the choice of the surfactant determines the final elemental composition of the particles, leading to either lanthanide oxides or oxysulfates when using Brij® 35 or sodium dodecyl sulfate, respectively. Nanoparticles of holmium and gadolinium were prepared and their applicability as magnetic resonance imaging contrast agents is shown.

Subject

Gold for Gold
Open Access

To reference this document use:

http://resolver.tudelft.nl/uuid:c94c960f-a114-46b7-8061-b36d1114b08e

DOI

https://doi.org/10.1039/C5RA09374K

Publisher

RSC Publishing

ISSN

2046-2069

Source

RSC Advances, 2015,5