Print Email Facebook Twitter Cross-sectional characterization of the conversion layer formed on AA2024-T3 by a lithium-leaching coating Title Cross-sectional characterization of the conversion layer formed on AA2024-T3 by a lithium-leaching coating Author Kosari, A. (TU Delft (OLD) MSE-6) Visser, P. (Akzo Nobel) Tichelaar, F.D. (TU Delft QN/Afdelingsbureau; Kavli institute of nanoscience Delft) Eswara, S. (Luxembourg Institute of Science and Technology) Audinot, J. N. (Luxembourg Institute of Science and Technology) Wirtz, T. (Luxembourg Institute of Science and Technology) Zandbergen, H.W. (TU Delft QN/Zandbergen Lab; Kavli institute of nanoscience Delft) Terryn, H.A. (TU Delft (OLD) MSE-6; Vrije Universiteit Brussel) Mol, J.M.C. (TU Delft (OLD) MSE-6) Date 2020 Abstract This work focuses on the cross-sectional characterization of the protective conversion layer formed on AA2024-T3 by lithium-leaching from a polyurethane coating in a corrosive environment. The layer shows a multi-layered arrangement comprising nanoscopic local phases. Transmission electron microscopy (TEM) and complementary high-resolution secondary ion mass spectroscopy (SIMS) were employed to observe the cross-sections of the entire layer formed at different locations of a 1-mm-wide scribe, in terms of morphology, structure and chemical composition. The conversion layer was comprised of two ubiquitous sublayers; a thin dense layer (i.e. 150 nm) adjacent the alloy substrate and a porous layer. The former represents an amorphous lithium-containing pseudoboehmite phase, Li-pseudoboehmite, whereas the latter is composed of amorphous and crystalline products; an outer columnar layer merely seen on the peripheral region is also crystalline. Through a sandwich structure and the d(003) basal spacing, the crystalline phases were identified as Li-Al layered double hydroxide. Although lithium was found uniformly spread within different regions, the local phases with no/low concentration of lithium were revealed with energy filtered TEM and confirmed with SIMS analysis. Subject AA2024-T3Energy Filtered TEMHigh Resolution TEMLayered double hydroxideLeachable lithium carbonateSIMS To reference this document use: http://resolver.tudelft.nl/uuid:050fdc7a-fc0d-4740-93c7-bcb8fa819e49 DOI https://doi.org/10.1016/j.apsusc.2020.145665 ISSN 0169-4332 Source Applied Surface Science, 512 Part of collection Institutional Repository Document type journal article Rights © 2020 A. Kosari, P. Visser, F.D. Tichelaar, S. Eswara, J. N. Audinot, T. Wirtz, H.W. Zandbergen, H.A. Terryn, J.M.C. Mol Files PDF 1_s2.0_S0169433220304219_main.pdf 5.48 MB Close viewer /islandora/object/uuid:050fdc7a-fc0d-4740-93c7-bcb8fa819e49/datastream/OBJ/view