Title
On the formation mechanisms and properties of MAX phases: A review
Author
Zhang, Z. (TU Delft Novel Aerospace Materials; Harbin Institute of Technology)
Duan, X. (TU Delft OLD Surface and Interface Engineering; Harbin Institute of Technology)
Jia, Dechang (Harbin Institute of Technology)
Zhou, Y. (TU Delft PLD Infra & construction; Harbin Institute of Technology)
van der Zwaag, S. (TU Delft Novel Aerospace Materials) 
Date
2021-07
Abstract
MAX phases are a family of ternary carbide or nitride ceramics possessing a layered crystal structure and, due to their chemical bonds having a mixed covalent-ionic-metallic nature, have unique properties combining those of metals and ceramics. In this review, the formation mechanisms of MAX phases from elemental and compound powders are reviewed in detail, as the formation mechanisms are closely related to the unique properties of well-synthesized MAX phases. The stability of MAX phases in some harsh external environments is significantly influenced by the defect population, allowing the mechanisms of defect formation and migration to strongly influence their self-healing performance and radiation tolerance. The properties of MAX phases can be tailored by creating solid solutions, which have lattice distortions, and texturing which results in the preferential orientation of plate-like grains.
Subject
Formation mechanisms
MAX phases
Point defects
Solid solutions
Texture
To reference this document use:
http://resolver.tudelft.nl/uuid:10562ad6-ef0c-417c-9c89-f9668cc8eba6
DOI
https://doi.org/10.1016/j.jeurceramsoc.2021.02.002
Embargo date
2021-09-13
ISSN
0955-2219
Source
Journal of the European Ceramic Society, 41 (7), 3851-3878
Bibliographical note
Green Open Access added to TU Delft Institutional Repository ‘You share, we take care!’ – Taverne project https://www.openaccess.nl/en/you-share-we-take-care Otherwise as indicated in the copyright section: the publisher is the copyright holder of this work and the author uses the Dutch legislation to make this work public.
Part of collection
Institutional Repository
Document type
review
Rights
© 2021 Z. Zhang, X. Duan, Dechang Jia, Y. Zhou, S. van der Zwaag