High aspect ratio surface micro-machining using carbon nanotubes

High aspect ratio surface micro-machining using carbon nanotubes

SHANKAR, SHREYAS (TU Delft Electrical Engineering, Mathematics and Computer Science; TU Delft Electronic Components, Technology and Materials)

Vollebregt, S. (mentor)
Mo, J. (graduation committee)
van Driel, W.D. (graduation committee)
French, P.J. (graduation committee)

Delft University of Technology

Electrical Engineering

2021-10-25

Silicon-based MEMS technology has been the standard for developing 2D and 3D
micro-structures for many years. There are 2 main classifications of MEMS manufacturing technologies, viz. bulk micro-machining, and surface micro-machining.
These techniques have its own set of drawbacks. Bulk micro-machining affects the structural integrity of the wafer because bulk silicon is being etched. Surface micro-machining is limited by the maximum thickness of the method of thin-film deposition (usually a few microns). The current silicon-based MEMS sensors can also fail when it comes to harsh environment sensing. Due to this, the sensors would require many supporting infrastructures such as radiation shield, cooling system and shock-proof packaging.
One way to circumvent this problem is by designing sensors using materials that would not require as much supporting infrastructure. Silicon carbide (SiC) has proved to be a viable candidate to be used in such harsh environments. This is
because it is found to be mechanically robust, chemically inert and with good wear resistance. However, bulk micro-machining with SiC is extremely challenging due to the high difficulty in etching. Many techniques have been tested to etch SiC, but they all have considerable drawbacks or low etch rates. Thus, to make high aspect ratio structures using SiC we will require a new technique where carbon nanotubes (CNT) can be used as a framework in the fabrication process for high aspect ratio surface micro-machining. CNTs can be grown to lengths of several micrometres to millimetres while their diameter is in the order of a few nanometres. Bundles of these tubes were found to have excellent conductance with high current densities, and their behaviour can be either metallic or semiconducting depending on their chiral vector. These unique properties make CNTs a very interesting material to be integrated into conventional MEMS technology. Although a single nanotube has excellent properties, bundles of nanotubes show a ‘foam-like’ property since they are held together by weak van der Waals’ forces. Thus, to realize mechanical structures with CNTs, we will have to coat the nanotube bundles with a filler material. This has previously been demonstrated to allow tuning of the mechanical properties of the composite. SiC would be an attractive filler candidate for harsh environment sensors. Due to the porous nature of nanotubes, it is possible to infiltrate the forest by deposition of a nanoscale coating. The deposition of the filler material is done by means of low pressure chemical vapor deposition (LPCVD) since a low pressure and deposition rate will enable the nanotube forest to get completely infiltrated and more uniformly coated. The goal of this research is to fabricate the first sensor using this technique, viz. a comb type capacitive accelerometer and test its performance and resilience to harsh environments by using SiC as coating. This technique will enable the user of a thicker layer for the proof mass and combs, resulting in a higher performance and potentially, resistance to harsh environments.

Carbon nanotubes
Silicon carbide
nanocomposites
micro-machining

http://resolver.tudelft.nl/uuid:99221f7d-d49e-44e5-9a4f-d1cd0b34044b

2022-10-25

Student theses

master thesis

© 2021 SHREYAS SHANKAR