Print Email Facebook Twitter Biomass pyrolysis TGA assessment with an international round robin Title Biomass pyrolysis TGA assessment with an international round robin Author Anca-Couce, Andrés (Graz University of Technology) Tsekos, C. (TU Delft Large Scale Energy Storage) Retschitzegger, Stefan (BEST – Bioenergy and Sustainable Technologies) Zimbardi, Francesco (ENEA - Italian National Agency for New Technologies, Energy and Sustainable Economic Development) Funke, Axel (Karlsruhe Institut für Technologie) Banks, Scott (Aston University) Kraia, Tzouliana (Centre for Research and Technology-Hellas) Marques, Paula (Unidade de Bioenergia) Scharler, Robert (Graz University of Technology; BEST – Bioenergy and Sustainable Technologies) de Jong, W. (TU Delft Large Scale Energy Storage) Kienzl, Norbert (BEST – Bioenergy and Sustainable Technologies) Date 2020 Abstract The large variations found in literature for the activation energy values of main biomass compounds (cellulose, hemicellulose and lignin) in pyrolysis TGA raise concerns regarding the reliability of both the experimental and the modelling side of the performed works. In this work, an international round robin has been conducted by 7 partners who performed TGA pyrolysis experiments of pure cellulose and beech wood at several heating rates. Deviations of around 20 – 30 kJ/mol were obtained in the activation energies of cellulose, hemicellulose and conversions up to 0.9 with beech wood when considering all experiments. The following method was employed to derive reliable kinetics: to first ensure that pure cellulose pyrolysis experiments from literature can be accurately reproduced, and then to conduct experiments at different heating rates and evaluate them with isoconversional methods to detect experiments that are outliers and to validate the reliability of the derived kinetics and employed reaction models with a fitting routine. The deviations in the activation energy values for the cases that followed this method, after disregarding other cases, were of 10 kJ/mol or lower, except for lignin and very high conversions. This method is therefore proposed in order to improve the consistency of data acquisition and kinetic analysis of TGA for biomass pyrolysis in literature, reducing the reported variability. Subject BiomassFittingIsoconversionalPyrolysisRound robinTGA To reference this document use: http://resolver.tudelft.nl/uuid:f4502f84-5f39-40c6-8118-625901ff6ae9 DOI https://doi.org/10.1016/j.fuel.2020.118002 ISSN 0016-2361 Source Fuel: the science and technology of fuel and energy, 276 Part of collection Institutional Repository Document type journal article Rights © 2020 Andrés Anca-Couce, C. Tsekos, Stefan Retschitzegger, Francesco Zimbardi, Axel Funke, Scott Banks, Tzouliana Kraia, Paula Marques, Robert Scharler, W. de Jong, Norbert Kienzl Files PDF 1_s2.0_S0016236120309984_main.pdf 2.01 MB Close viewer /islandora/object/uuid:f4502f84-5f39-40c6-8118-625901ff6ae9/datastream/OBJ/view