Title
Life-cycle assessment of marine biofuels from thermochemical liquefaction of different olive residues in Spain
Author
Chandrasekaran, S. (TU Delft BT/Biotechnology and Society)
Wammes, Puck (Student TU Delft)
Posada Duque, J.A. (TU Delft BT/Biotechnology and Society)
Contributor
Kokossis, Antonis (editor)
Georgiadis, Michael C. (editor)
Pistikopoulos, Efstratios N. (editor)
Date
2023
Abstract
Advanced biofuels from thermochemical liquefaction, such as pyrolysis (PY) and Hydrothermal liquefaction (HTL), of olive residues in the Andalusian region of Spain (specifically in the province of Jaen) can potentially play a crucial role in the reduction of greenhouse gas (GHG) emissions in the maritime sector. In this study, an attributional life-cycle assessment (ALCA) was performed to estimate and compare the GHG emissions for producing marine biofuels via pyrolysis and HTL from olive pomace (COP) and pruning biomass (OTPB), to provide 1 megajoule (MJ) of marine biofuel, as a functional unit. For convenience, the different technology-feedstock combination scenarios are represented as scenario 1 (PY_COP), scenario 2 (PY_OTPB), scenario 3 (HTL_COP), and scenario 4 (HTL_OTPB). The life-cycle GHG emissions of the biofuels were 42.0, 44.1, 22.1, and 32.1 g CO2-eq/MJ for PY_COP, PY_OTPB, HTL_COP and HTL_OTPB scenarios, respectively, corresponding to 47–73% GHG emissions reduction compared with petroleum fuels. The scenarios were also evaluated based on other impact categories such as Sulphur dioxide in the air, Nitrogen oxides in the air, Particulates in the air, and Non-methane volatile organic compounds (NMVOCs) in the air. The scenarios reduced the SO2 emissions, Nitrogen emissions, NVMOCs, and particulates in the air by at least 50%, 90%, 20%, and 25% respectively in comparison to fossil fuels. A contribution analysis revealed that olive cultivation and upgrading as hot spots for emission in pyrolysis-based systems. Likewise, HTL conversion and upgrading steps were emitting more emissions for an HTL-based system. Therefore, marine biofuel obtained through the thermochemical conversion of olive residues has better environmental performance on a life cycle basis, with a preference for HTL based system over pyrolysis.
Subject
Greenhouse gas emissions
hydrothermal liquefaction
Life-cycle assessment
Marine biofuels
Pyrolysis
To reference this document use:
http://resolver.tudelft.nl/uuid:f4f0ce00-006f-48db-bd4c-f45793faa7a1
DOI
https://doi.org/10.1016/B978-0-443-15274-0.50541-2
Publisher
Elsevier
Embargo date
2024-02-01
Source
Computer Aided Chemical Engineering
Series
Computer Aided Chemical Engineering, 1570-7946, 52
Bibliographical note
Green Open Access added to TU Delft Institutional Repository ‘You share, we take care!’ – Taverne project https://www.openaccess.nl/en/you-share-we-take-care Otherwise as indicated in the copyright section: the publisher is the copyright holder of this work and the author uses the Dutch legislation to make this work public.
Part of collection
Institutional Repository
Document type
book chapter
Rights
© 2023 S. Chandrasekaran, Puck Wammes, J.A. Posada Duque