Charge Carrier Dynamics in Cs₂AgBiBr₆ Double Perovskite

Charge Carrier Dynamics in Cs₂AgBiBr₆ Double Perovskite

Bartesaghi, D. (TU Delft ChemE/Opto-electronic Materials; Material Innovation Institute (M2i))
Slavney, Adam H. (Stanford University)
Gelvez Rueda, M.C. (TU Delft ChemE/Opto-electronic Materials)
Connor, Bridget A. (Stanford University)
Grozema, F.C. (TU Delft ChemE/Opto-electronic Materials)
Karunadasa, Hemamala I. (Stanford University)
Savenije, T.J. (TU Delft ChemE/Opto-electronic Materials)

2018

Double perovskites, comprising two different cations, are potential nontoxic alternatives to lead halide perovskites. Here, we characterized thin films and crystals of Cs₂AgBiBr₆ by time-resolved microwave conductance (TRMC), which probes formation and decay of mobile charges upon pulsed irradiation. Optical excitation of films results in the formation of charges with a yield times mobility product, φΣμ > 1 cm²/Vs. On excitation of millimeter-sized crystals, the TRMC signals show, apart from a fast decay, a long-lived tail. Interestingly, this tail is dominant when exciting close to the bandgap, implying the presence of mobile charges with microsecond lifetimes. From the temperature and intensity dependence of the TRMC signals, we deduce a shallow trap state density of around 10¹⁶/cm³ in the bulk of the crystal. Despite this high concentration, trap-assisted recombination of charges in the bulk appears to be slow, which is promising for photovoltaic applications.

http://resolver.tudelft.nl/uuid:f559ca47-3190-423d-954d-4b007d6417dc

https://doi.org/10.1021/acs.jpcc.8b00572

1932-7447

The Journal of Physical Chemistry C, 122 (9), 4809-4816

Institutional Repository

journal article

© 2018 D. Bartesaghi, Adam H. Slavney, M.C. Gelvez Rueda, Bridget A. Connor, F.C. Grozema, Hemamala I. Karunadasa, T.J. Savenije