Near-infrared light-driven asymmetric photolytic reduction of ketone using inorganic-enzyme hybrid biocatalyst

Effective photolytic regeneration of the NAD(P)H cofactor in enzymatic reductions is an important and elusive goal in biocatalysis. It can, in principle, be achieved using a near-infrared light (NIR) driven artificial photosynthesis system employing H₂O as the sacrificial reductant. To this end we utilized TiO₂/reduced...

Precision Engineering of the Co-immobilization of Enzymes for Cascade Biocatalysis

The design and orderly layered co-immobilization of multiple enzymes on resin particles remain challenging. In this study, the SpyTag/SpyCatcher binding pair was fused to the N-terminus of an alcohol dehydrogenase (ADH) and an aldo-keto reductase (AKR), respectively. A non-canonical amino acid (ncAA), p-azido-L-phenylalanine (p-AzF), as the...

Continuous Fatty Acid Decarboxylation using an Immobilized Photodecarboxylase in a Membrane Reactor

The realm of photobiocatalytic alkane biofuel synthesis has burgeoned recently; however, the current dearth of well-established and scalable production methodologies in this domain remains conspicuous. In this investigation, we engineered a modified form of membrane-associated fatty acid photodecarboxylase sourced from Micractinium conductrix...

Rapid extraction of pavement aggregate gradation based on point clouds using deep learning networks

Usage of asphalt mixture with poor gradation will most likely lead to pavement deficiency. There is a growing need for rapid and non-destructive methods to extract pavement aggregate gradation. In this study, a deep learning-based method that utilizes point clouds data for gradation extraction was proposed. Firstly, a data enhancement...

A data-driven high spatial resolution model of biomass accumulation and crop yield: Application to a fragmented desert-oasis agroecosystem

Information on crop yield is important for food security, in particular under the conditions of climate change and growing population worldwide. We developed a new fully distributed, high spatial resolution, model of biomass accumulation and crop yield applicable to a highly heterogeneous desert-oasis agroecosystem. The bulk of required input...

A Bienzymatic Cascade for the Complete Hydrolysis of Phthalic Acid Esters

Phthalic acid esters (PAEs) are widely used as plastic additives to increase the flexibility and durability of plastics. Constantly leaching out from plastics, PAEs are ubiquitously found in the environment. As PAEs exhibit biological activities such as being endocrine disruptive, the quest for efficient degradation strategies continues. Here...

Fabrication of a Nanosize Hematite Pigment via Waste Ferrous Sulfate Recycling Using Sulfur Reduction

Nanometer-sized hematite was prepared via a two-step process. In the first step, FeSO₄·7H₂O was oxidized to Fe₂(SO₄)₃ by oxygen in an acidic solution. In the second step, the Fe₂(SO₄)₃ was reduced to nanosize hematite with sulfur vapor at 550 °C. The...

A two-dimensional ordinary state-based peridynamic model for surface fatigue crack propagation in railheads

Based on ordinary state-based peridynamic theory, a 2D peridynamic model has been established to investigate fatigue crack propagation in railheads. The proposed model is verified in terms of rail deformation under a quasi-static load and the ductile material-related fatigue failure model. Good agreements have been achieved between a finite...

Fan-Out Panel-Level PCB-Embedded SiC Power MOSFETs Packaging

In this article, a novel fan-out panel-level printed circuit board (PCB)-embedded package for phase-leg silicon carbide (SiC) metal-oxide-semiconductor field-effect transistor (MOSFET) power module is presented. Electro-thermo-mechanical co-design was conducted, and the maximum package parasitic inductance was found to be about 1.24 nH at 100...

Microwave roasting of blast furnace slag for carbon dioxide mineralization and energy analysis

For both the waste treatment of large quantities of blast furnace (BF) slag and carbon dioxide (CO₂) that are discharged in ironworks, mineral carbonation by BF slag was proposed in this decade. However, it has not been widely used due to its high energy consumption and low production efficiency. In this study, a microwave roasting...

A data-driven approach for optimal design of integrated air quality monitoring network in a chemical cluster

The chemical industry is of paramount importance to the world economy and this industrial sector represents a substantial income source for developing countries. However, the chemical plants producing inside an industrial district pose a great threat to the surrounding atmospheric environment and human health. Therefore, designing an...

Hazardous Source Estimation Using an Artificial Neural Network, Particle Swarm Optimization and a Simulated Annealing Algorithm

Locating and quantifying the emission source plays a significant role in the emergency management of hazardous gas leak accidents. Due to the lack of a desirable atmospheric dispersion model, current source estimation algorithms cannot meet the requirements of both accuracy and efficiency. In addition, the original optimization algorithm can...

Removal of Microcystis aeruginosa by UV-activated persulfate: Performance and characteristics

Cyanobacteria blooms in source waters have become a worldwide issue for drinking water production. UV-activated persulfate (UV/PS) technology was firstly applied to remove cultivated Microcystis aeruginosa (M. aeruginosa) in bench scale. The presence of persulfate significantly enhanced both cytoclasis and algal organic matter mineralization...