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Zhu, Jia-Ning (author), Liu, K. (author), Riemslag, A.C. (author), Tichelaar, F.D. (author), Borisov, Evgenii (author), Yao, Xiyu (author), Popovich, Anatoly (author), Huizenga, R.M. (author), Hermans, M.J.M. (author), Popovich, V. (author)Superelastic metallic materials possessing large recoverable strains are widely used in automotive, aerospace and energy conversion industries. Superelastic materials working at high temperatures and with a wide temperature range are increasingly required for demanding applications. Until recently, high-temperature superelasticity has only...journal article 2023
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Wenderich, Kasper (author), Zhu, Kaijian (author), Bu, Yibin (author), Tichelaar, F.D. (author), Mul, Guido (author), Huijser, Annemarie (author)Despite the promising performance of Ru nanoparticles or nanoclusters on nanostructured TiO<sub>2</sub> in photocatalytic and photothermal reactions, a mechanistic understanding of the photophysics is limited. The aim of this study is to uncover the nature of light-induced processes in Ru/TiO<sub>2</sub> and the role of UV versus visible...journal article 2023
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Zhu, Jia-Ning (author), Zhu, Weijia (author), Borisov, Evgenii (author), Yao, Xiyu (author), Riemslag, A.C. (author), Goulas, Constantinos (author), Popovich, Anatoly (author), Yan, Z. (author), Tichelaar, F.D. (author), Mainali, D.P. (author), Hermans, M.J.M. (author), Popovich, V. (author)Additive manufacturing of NiTi shape memory alloys has attracted attention in recent years, due to design flexibility and feasibility to achieve four-dimensional (4D) function response. To obtain customized 4D functional responses in NiTi structures, tailorable phase transformation temperatures and stress windows as well as one-way or two-way...journal article 2023
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Tichelaar, Deniz (author)This paper looks at the concept of extraction of raw materials, labour and communities, as it applies to the Balochistan province of Pakistan, with an emphasis on the port city of Gwadar. Extraction and its spatial consequences are explored with reference to the situation on the ground in Gwadar. Looking at Gwadar through the lense of statecraft...master thesis 2022
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Bizinoto Ferreira Bosco, G. (author), van den Biesen, J. K. (author), Boers, C. D. (author), Simone, G. (author), Kao, C.C. (author), Tichelaar, F.D. (author), Boshuizen, B. (author), van der Kolk, E. (author)Silicon-aluminum-oxigen (SiAlO) coatings doped with Sm<sup>2+</sup> and prepared by reactive magnetron co-sputtering of Si, Al, and Sm targets, are attractive for luminescence solar concentrator applications but suffer from the low absorption between 300 and 600 nm. This article reports that the main cause of low absorption is a high...journal article 2022
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Cao, L. (author), Procel Moya, P.A. (author), Alcañiz Moya, A. (author), Yan, J. (author), Tichelaar, F.D. (author), Özkol, E. (author), Zhao, Y. (author), Han, C. (author), Yang, G. (author), Yao, Z. (author), Zeman, M. (author), Santbergen, R. (author), Mazzarella, L. (author), Isabella, O. (author)Thin films of transition metal oxides such as molybdenum oxide (MoO<sub>x</sub>) are attractive for application in silicon heterojunction solar cells for their potential to yield large short-circuit current density. However, full control of electrical properties of thin MoO<sub>x</sub> layers must be mastered to obtain an efficient hole...journal article 2022
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Li, M. (author), Fu, S. (author), Saedy, S. (author), Rajendrakumar, Aparna (author), Tichelaar, F.D. (author), Kortlever, R. (author), van Ommen, J.R. (author)Preparing supported nanoparticles with a well-defined structure, uniform particle size, and composition using conventional catalyst synthesis methods, such as impregnation, precipitation, and deposition-precipitation is challenging. Furthermore, these liquid phase methods require significant solvent consumption, which has sustainable issues...journal article 2022
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Fu, Y. (author), Fang, H. (author), Monaco, F. (author), Cloetens, P. (author), Tichelaar, F.D. (author), van Meel, J.G. (author), Brück, E.H. (author), van der Zwaag, S. (author), van Dijk, N.H. (author)Constant stress creep experiments at 550 °C were performed on a high-purity Fe-3Au-4W (wt.%) ternary alloy with about 1 at.% supersaturation for Au and W in order to study self healing of grain-boundary cavities by both Au-rich and W-rich precipitates. Using synchrotron X-ray nano-tomography, the development of the creep cavities and the...journal article 2022
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Kosari, A. (author), Ahmadi, M. (author), Tichelaar, F.D. (author), Visser, P. (author), Gonzalez Garcia, Y. (author), Zandbergen, H.W. (author), Terryn, H.A. (author), Mol, J.M.C. (author)Cerium-based compounds have been studied for decades as non-toxic candidates for the protection of aerospace aluminium alloys (AAs) like AA2024-T3. However, the complex heterogeneous microstructure of these alloys has hindered a thorough understanding of the subsequent stages of corrosion protection provided by this class of inhibitors. Thus,...journal article 2021
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Verma, N. (author), Delhez, R. (author), van der Pers, N.M. (author), Tichelaar, F.D. (author), Bottger, A.J. (author)In this work, we studied the mechanical and thermal stability of ~100 nm Pd thin films magnetron sputter deposited on a bare oxidized Si(100) wafer, a sputtered Titanium (Ti) intermediate layer, and a spin-coated Polyimide (PI) intermediate layer. The dependence of the film stability on the film morphology and the film-substrate interaction...journal article 2021
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Kosari, A. (author), Tichelaar, F.D. (author), Visser, P. (author), Taheri, P. (author), Zandbergen, H.W. (author), Terryn, H.A. (author), Mol, J.M.C. (author)Lithium salts have been proposed as promising environmentally friendly alternatives to carcinogenic hexavalent chromium-based inhibitors for the corrosion protection of aerospace aluminium alloys (AAs). Incorporated into organic coatings, lithium salts are released at damaged locations to establish a conversion layer in which distinct...journal article 2021
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Kosari, A. (author), Tichelaar, F.D. (author), Visser, P. (author), Zandbergen, H.W. (author), Terryn, H.A. (author), Mol, J.M.C. (author)Lithium leaching coatings have recently been developed as eco-friendly active corrosion protection technology for aerospace aluminium alloys (AAs) by the formation of a conversion layer at coating defects. While general conversion layer formation characteristics were studied and reported before, here we study the local layer formation process...journal article 2021
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Kosari, A. (author), Zandbergen, H.W. (author), Tichelaar, F.D. (author), Visser, P. (author), Terryn, H.A. (author), Mol, J.M.C. (author)Liquid-phase transmission electron microscopy (LP-TEM) has provided corrosion scientists with a unique opportunity to directly correlate nanoscopic morphological and compositional evolutions to the corresponding electrochemical response of corroding thin TEM specimens. Electrochemical liquid cell designs are key components of a LP-TEM study...journal article 2021
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Zhao, Y. (author), Mazzarella, L. (author), Procel Moya, P.A. (author), Han, C. (author), Tichelaar, F.D. (author), Yang, G. (author), Weeber, A.W. (author), Zeman, M. (author), Isabella, O. (author)Low parasitic absorption and high conductivity enable (n)-type hydrogenated nanocrystalline silicon [(n)nc-Si:H], eventually alloyed with oxygen [(n)nc-SiO<sub>x</sub>:H], to be deployed as window layer in high-efficiency silicon heterojunction (SHJ) solar cells. Besides the appropriate opto-electrical properties of these nanocrystalline...journal article 2021
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Franz, R.P.M. (author), Tichelaar, F.D. (author), Uslamin, E. (author), Pidko, E.A. (author)Catalyst passivation refers to the formation of a protective oxide layer on the active metal particles that prevents their oxidation when exposed to air. Common passivation procedures, when applied to Ni/ Al2O3 catalysts, typically result in a significant decrease of the overall Ni surface area and, accordingly, the catalytic activity....journal article 2021
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Fu, Y. (author), Kwakernaak, C. (author), Sloof, W.G. (author), Tichelaar, F.D. (author), Brück, E.H. (author), van der Zwaag, S. (author), van Dijk, N.H. (author)Autonomous healing of creep-induced grain boundary cavities by Au-rich and W-rich precipitates was studied in a Fe-3Au-4W (wt pct) alloy at a fixed temperature of 823 K (550 °C) with different applied stresses. The ternary alloy, with two supersaturated healing solutes, serves as a model system to study the interplay between two separate...journal article 2020
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Kosari, A. (author), Visser, P. (author), Tichelaar, F.D. (author), Eswara, S. (author), Audinot, J. N. (author), Wirtz, T. (author), Zandbergen, H.W. (author), Terryn, H.A. (author), Mol, J.M.C. (author)This work focuses on the cross-sectional characterization of the protective conversion layer formed on AA2024-T3 by lithium-leaching from a polyurethane coating in a corrosive environment. The layer shows a multi-layered arrangement comprising nanoscopic local phases. Transmission electron microscopy (TEM) and complementary high-resolution...journal article 2020
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Kosari, A. (author), Zandbergen, H.W. (author), Tichelaar, F.D. (author), Visser, P. (author), Terryn, H.A. (author), Mol, J.M.C. (author)Identifying corrosion initiation events in metals and alloys demands techniques that can provide temporal and spatial resolution simultaneously. Transmission electron microscopy (TEM) enables one to obtain microstructural and chemical descriptors of materials at atomic/nanoscopic level and has been used in corrosion studies of many metal...review 2020
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Kosari, A. (author), Zandbergen, H.W. (author), Tichelaar, F.D. (author), Visser, P. (author), Taheri, P. (author), Terryn, H.A. (author), Mol, J.M.C. (author)Dealloying is involved in materials science responsible for fabrication of nanoscale structures beneficially but for corrosion degradations detrimentally. Detailed understanding related to the latter is critical for designing corrosion-resistance alloys and dedicated inhibition systems. Thus, direct nanoscopic observations of nano-structural...journal article 2020
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Kosari, A. (author), Tichelaar, F.D. (author), Visser, P. (author), Zandbergen, H.W. (author), Terryn, H.A. (author), Mol, J.M.C. (author)Nanoscopic characterization of heterogeneous intermetallic particles (IMPs) which microstructurally and compositionally evolve during local corrosion is crucial in unravelling the mechanisms and sequence of initial and local corrosion events. Herein, we study site-specific initiation events focused on microscopic constituent intermetallic...journal article 2020