Searched for:
(1 - 11 of 11)
document
Sun, X. (author), Olivos Suarez, A.I. (author), Oar-Arteta Gonzalez, L. (author), Rozhko, E. (author), Osadchii, D. (author), Bavykina, A.V. (author), Kapteijn, F. (author), Gascon Sabate, J. (author)
A Co@N-doped carbon (Co@ NC) hybrid was synthesized by thermal decomposition of the metal–organic framework (MOF) ZIF-67 under N2 atmosphere. These hybrid materials exhibit outstanding catalytic activity and chemoselectivity for the conversion of a wide range of substituted nitroarenes to their corresponding anilines under relatively mild...
journal article 2017
document
Seshan, V. (author), Ullien, D. (author), Castellanos-Gomez, A. (author), Sachdeva, S. (author), Murthy, D.H.K. (author), Savenije, T.J. (author), Ahmad, H.A. (author), Nunney, T.S. (author), Janssens, S.D. (author), Haenen, K. (author), Nesládek, M. (author), Van der Zant, H.S.J. (author), Sudhölter, E.J.R. (author), De Smet, L.C.P.M. (author)
A high-temperature procedure to hydrogenate diamond films using molecular hydrogen at atmospheric pressure was explored. Undoped and doped chemical vapour deposited (CVD) polycrystalline diamond films were treated according to our annealing method using a H2 gas flow down to ?50 ml/min (STP) at ?850?°C. The films were extensively evaluated by...
journal article 2013
document
Ten Dam, J. (author), Djanashvili, K. (author), Kapteijn, F. (author), Hanefeld, U. (author)
Screening of four commercial catalysts (Pt/Al2O3, Pt/SiO2, Pd/Al2O3, and Pd/SiO2) and four acidic additives (hydrochloric, tungstic, phosphotungstic, and silicotungstic acids) shows that the combination of a platinum hydrogenation catalyst with tungsten containing acidic additives yields 1,3-propanediol from aqueous glycerol. The performance of...
journal article 2012
document
Alan, T. (author), Yokosawa, T. (author), Gaspar, J. (author), Pandraud, G. (author), Paul, O. (author), Creemer, F. (author), Sarro, P.M. (author), Zandbergen, H.W. (author)
Transmission electron microscopy (TEM) of (de-)hydrogenation reactions is crucial to characterize efficiency of hydrogen storage materials. The nanoreactor, a micromachined channel with 15-nm-thick windows, effectively confines the gas flow to an electron-transparent chamber during TEM of reactions. Realistic experiments require very high...
journal article 2012
document
Westerwaal, R.J. (author), Nyqvist, R.G. (author), Haije, W.G. (author)
For the daily use of hydrogen storage materials, not only their intrinsic storage properties are important, but also equally important is the performance under practical conditions. Besides the techniques already available for the fundamental characterization of storage materials, there is a growing need to test storage materials under...
journal article 2011
document
Leegwater, H. (author), Schut, H. (author), Egger, W. (author), Baldi, A. (author), Dam, B. (author), Eijt, S.W.H. (author)
We obtained evidence for the partial chemical segregation of as-deposited and hydrogenated Mg1?yTiy films (0 ? y ? 0.30) into nanoscale Ti and Mg domains using positron Doppler-broadening. We exclusively monitor the hydrogenation of Mg domains, owing to the large difference in positron affinity for Mg and Ti. The electron momentum distribution...
journal article 2010
document
Wank, M.A. (author), Van Swaaij, R.A.C.M.M. (author), Van de Sanden, M.C.M. (author)
The surface roughness evolution of hydrogenated amorphous silicon (a-Si:H) films has been studied using in situ spectroscopic ellipsometry for a temperature range of 150–400?°C. The effect of external rf substrate biasing on the coalescence phase is discussed and a removal/densification of a hydrogen-rich layer is suggested to explain the...
journal article 2009
document
Eijt, S.W.H. (author), Kind, R. (author), Singh, S. (author), Schut, H. (author), Legerstee, W.J. (author), Hendrikx, R.W.A. (author), Svetchnikov, V.L. (author), Westerwaal, R.J. (author), Dam, B. (author)
We report positron depth-profiling studies on the hydrogen sorption behavior and phase evolution of Mg-based thin films. We show that the main changes in the depth profiles resulting from the hydrogenation to the respective metal hydrides are related to a clear broadening in the observed electron momentum densities in both Mg and Mg2Ni films....
journal article 2009
document
Simons, C. (author)
Chemical production processes often require wasteful and expensive isolation as well as purification of intermediates. Catalytic cascades offer a unique opportunity to eliminate these inefficient and polluting steps, in particular when carefully orchestrated, involving enzymes and chemocatalysts. This thesis describes our efforts towards a...
doctoral thesis 2007
document
Zieverink, M.M.P. (author)
Abstract not available
doctoral thesis 2007
document
Chang, T. (author), Huijser, J.M. (author), Maassen, N. (author), De Winter, A. (author)
Document(en) uit de collectie Chemische Procestechnologie
report 2002
Searched for:
(1 - 11 of 11)