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Lai, J. (author), You, X. (author), Law, Jiayan (author), Franco, Victorino (author), Huang, B. (author), Bessas, Dimitrios (author), Maschek, M. (author), Zeng, Dechang (author), van Dijk, N.H. (author), Brück, E.H. (author)
Large thermal hysteresis in the (Mn,Fe)2(P,Si) system hinders an efficient heat exchange and thus limits the magnetocaloric applications. Substitution of manganese by vanadium in the Mn1-x1Vx1Fe0.95P0.593Si0.33B0.077 and Mn1-x2Vx2Fe0.95P0.563Si0.36B0.077 compounds enable a significant reduction in the thermal hysteresis without losing the giant...
journal article 2022
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Lai, J. (author), You, X. (author), Dugulan, A.I. (author), Huang, B. (author), Liu, J. (author), Maschek, M. (author), van Eijck, L. (author), van Dijk, N.H. (author), Brück, E.H. (author)
The first-order magneto-elastic transition in the Mn–Fe–P–Si alloys can be tailored by vanadium substitution. Alloys with a suitable V substitution provide an excellent magnetocaloric effect with minor hysteresis in low magnetic fields up to 1.2 T. Mössbauer measurements show that the hyperfine field is reduced by V substitution. Neutron...
journal article 2020
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Bessas, D. (author), Maschek, M. (author), Yibole, . (author), Lai, J. (author), Souliou, S. M. (author), Dugulan, A.I. (author), Sergueev, I. (author), van Dijk, N.H. (author), Brück, E.H. (author)
The lattice dynamics in MnFe0.95Si0.50P0.50 were investigated experimentally using Fe57 nuclear inelastic scattering and inelastic x-ray scattering across the first-order magnetic transition which occurs close to room temperature. The lattice dynamics characterization was supported by a macroscopic magnetic characterization, an x-ray...
journal article 2018
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Lai, J. (author), Huang, B. (author), Miao, X.F. (author), Nguyên, V.T. (author), You, X. (author), Maschek, M. (author), van Eijck, L. (author), Zeng, D. (author), van Dijk, N.H. (author), Brück, E.H. (author)
Approaching the border of the first order transition and second order transition is significant to optimize the giant magnetocaloric materials performance. The influence of vanadium substitution in the Mn<sub>1.2-x</sub>V<sub>x</sub>Fe<sub>0.75</sub>P<sub>0.5</sub>Si<sub>0.5</sub> alloys is investigated for annealing temperatures of 1323,...
journal article 2019
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Lai, J. (author), Huang, B. (author), You, X. (author), Maschek, M. (author), Zhou, Guofu (author), van Dijk, N.H. (author), Brück, E.H. (author)
The Fe<sub>2</sub>P type Mn–Fe–P–Si alloys exhibit a giant magneto-elastic first-order transition, but the large hysteresis limits their performance. Crystal structure evolution and magnetocaloric performance were investigated by varying the Mn and Fe contents at a constant V substitution of 0.02 in Fe<sub>2</sub>P-type (Mn<sub>1.17-x</sub>Fe...
journal article 2024
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