An approach to develop set-on-demand 3D printable limestone-calcined clay-based cementitious materials using calcium nitrate

The implementation of extrusion-based 3D concrete printing (3DCP) in large-scale constructions is currently limited by concerns regarding rheology control and the sustainability of this process. To address these issues, this study presents an approach to develop limestone-calcined clay-based cementitious (LC3) materials accelerated by Ca(NO...

Improving structural build-up of limestone-calcined clay-cement pastes by using inorganic additives

In 3D concrete printing, fast structuration is a prerequisite for ideal buildability. This paper aims to study the impact of inorganic additives, i.e., CaCl₂ and gypsum, on structural build-up and very early-age hydration of limestone-calcined clay-cement (LC3) pastes within the first 70–80 min. Results show that, increasing the...

A review of methods on buildability quantification of extrusion-based 3D concrete printing: From analytical modelling to numerical simulation

Herein, different kinds of methods for buildability quantification of 3D concrete printing are reviewed, including experimental approaches, analytical modelling, and numerical simulations. A brief introduction on printing process is first given. This discusses the material properties in different stages. Material printability, which...

Effect of curing methods during a long time gap between two printing sessions on the interlayer bonding of 3D printed cementitious materials

A good bond between the layers of 3D printed cementitious materials is a prerequisite for having high structural rigidity for the printed elements. However, the influence of printing process on an interlayer bond is still not well understood. This study investigates the influence of curing methods (i.e., air curing, plastic film covering, wet...

Feasibility study of using desalination brine to control the stiffness and early-age hydration of 3D printable cementitious materials

This paper proposes the use of desalination brine as a setting and hydration activator in set-on-demand 3D concrete printing. A series of tests were conducted to investigate the effect of adding different concentrations of desalination brine on stiffness evolution and early-age hydration of Portland cement mortars (PC mixtures) and limestone...

A review of printing strategies, sustainable cementitious materials and characterization methods in the context of extrusion-based 3D concrete printing

This paper aims to provide a systematical review of the available printing strategies, sustainable cementitious materials and characterization methods for extrusion-based 3D concrete printing (3DCP). The printing strategies, consisting of printing setup, process, and material requirements, were summarized initially. In the material aspect,...

3D printing of calcined clay-limestone-based cementitious materials

This paper aims to investigate the influences of high Portland cement substitutions (>60 wt%) by low-grade calcined clay (CC) and limestone (LF) on 3D concrete printability, stiffness evolution and early-age hydration. Results show that, with the same dosage of admixtures (superplasticizer and viscosity modifier), increasing LF and CC...

Improving printability of limestone-calcined clay-based cementitious materials by using viscosity-modifying admixture

In 3D concrete printing (3DCP), it is necessary to meet contradicting rheological requirements: high fluidity during pumping and extrusion, and high stability and viscosity at rest to build the layered structure. In this paper, the impact of the hydroxypropyl methylcellulose (HPMC)-based viscosity-modifying admixture (VMA) on the 3D printability...

Effect of different grade levels of calcined clays on fresh and hardened properties of ternary-blended cementitious materials for 3D printing

This study aims to investigate the influences of different grades of calcined clay on 3D printability, compressive strength (7 days), and hydration of limestone and calcined clay-based cementitious materials. Calcined clays that contained various amounts of metakaolin were achieved by blending low-grade calcined clay (LGCC) and high-grade...

Limestone and Calcined Clay-Based Sustainable Cementitious Materials for 3D Concrete Printing: A Fundamental Study of Extrudability and Early-Age Strength Development

The goal of this study is to investigate the effects of different grades of calcined clay on the extrudability and early-age strength development under ambient conditions. Four mix designs were proposed. Three of them contained high, medium, and low grades of calcined clay, respectively, and one was the reference without calcined clay. In terms...