Machine learning assisted discovery of high-efficiency self-healing epoxy coating for corrosion protection

Machine learning is a powerful means for the rapid development of high-performance functional materials. In this study, we presented a machine learning workflow for predicting the corrosion resistance of a self-healing epoxy coating containing ZIF-8@Ca microfillers. The orthogonal Latin square method was used to investigate the effects of the...

Application of game theory in risk management of urban natural gas pipelines

This paper presents a game theory methodology for risk management of urban natural gas pipelines, which is a collaborative participation mechanism of the stakeholders, including government, pipeline companies, and the public. Firstly, the involvement proportion of stakeholders in risk management under rational conditions is estimated by the...

Towards weathering and corrosion resistant, self-warning and self-healing epoxy coatings with tannic acid loaded nanocontainers

In this work, an active protective epoxy coating with weathering resistant, corrosion-warning, and self-healing properties was developed by incorporating tannic acid (TA) loaded mesoporous silica (MSN-TA) nanocontainers. The introduction of MSN-TA nanocontainers could alleviate the coating degradation via scavenging the radicals generated...

Biosynthesis of cyclic ketones by a H₂O₂ self-sufficient cascade reaction

In the present work we propose a bienzymatic cascade for the oxyfunctionalisation of cycloalkanes to cyclic alcohols/cyclic ketones. By combining a H₂O₂-dependent peroxygenase with a O₂-consuming and H₂O₂-producing alcohol oxidase an overall aerobic oxidation system was established. A...

Slight Multielement Doping-Induced Structural Order-Disorder Transition for High-Performance Layered Na-Ion Oxide Cathodes

To realize concurrently the high-energy density and excellent cycling stability, maximum utilization of redox couple, minimization of detrimental phase transition, and structural degradation of O3-type layered oxide cathodes are critical for developing Na-ion batteries. Ni²⁺/Ni⁴⁺ redox couple showing multielectron...

Rapid extraction of pavement aggregate gradation based on point clouds using deep learning networks

Usage of asphalt mixture with poor gradation will most likely lead to pavement deficiency. There is a growing need for rapid and non-destructive methods to extract pavement aggregate gradation. In this study, a deep learning-based method that utilizes point clouds data for gradation extraction was proposed. Firstly, a data enhancement...

Experimental and Theoretical Studies of the Site Occupancy and Luminescence of Ce³⁺in LiSr₄(BO₃)₃for Potential X-ray Detecting Applications

Ce3+-doped LiSr4(BO3)3 phosphors have been prepared by a high-temperature solid-state reaction method, and structural refinement of the host compound has been performed. The excitation and emission spectra in the vacuum ultraviolet-ultraviolet-visible range at cryogenic temperatures reveal that Ce3+ ions preferentially occupy eight...

A Bienzymatic Cascade for the Complete Hydrolysis of Phthalic Acid Esters

Phthalic acid esters (PAEs) are widely used as plastic additives to increase the flexibility and durability of plastics. Constantly leaching out from plastics, PAEs are ubiquitously found in the environment. As PAEs exhibit biological activities such as being endocrine disruptive, the quest for efficient degradation strategies continues. Here...

Fabrication of a Nanosize Hematite Pigment via Waste Ferrous Sulfate Recycling Using Sulfur Reduction

Nanometer-sized hematite was prepared via a two-step process. In the first step, FeSO₄·7H₂O was oxidized to Fe₂(SO₄)₃ by oxygen in an acidic solution. In the second step, the Fe₂(SO₄)₃ was reduced to nanosize hematite with sulfur vapor at 550 °C. The...

Impacts of the Silk Road pattern on the interdecadal variations of the atmospheric heat source over the Tibetan Plateau

This study aimed to investigate the relationship between the boreal summer Silk Road Pattern (SRP) and the atmospheric heat (<Q1>) over the Tibetan Plateau (TP) region, using 5 reanalysis datasets over the period 1979–2019. Our results indicate an interdecadal change of boreal summer SRP over the Eurasian region, with a regime shift in...

Abundant grain boundaries activate highly efficient lithium ion transportation in high rate Li₄Ti₅O₁₂ compact microspheres

It is a huge challenge for high-tap-density electrodes to achieve high volumetric energy density but without compromising the ionic transportation. Herein, we prepared compact Li₄Ti₅O₁₂ (LTO) microspheres consisting of densely packed primary nanoparticles. The real space distribution of lithium ions inside the...

An Efficient Strategy for the Production of Epoxidized Oils: Natural Deep Eutectic Solvent-Based Enzymatic Epoxidation

Poor H ₂ O ₂ -resistance by enzymes is a key bottleneck in the epoxidation process of oil by enzymatic methods. In this study, the stability of three lipases, from Aspergillus oryzae lipase (AOL), Aspergillus fumigatus lipase B (AflB), and marine Janibacter (MAJ1), in the presence of H ₂ O ₂ was...

Set organic pollution as an impact category to achieve more comprehensive evaluation of life cycle assessment in wastewater-related issues

For wastewater-related issues (WRI), life cycle assessment (LCA) is often used to evaluate environmental impacts and derive optimization strategies. To promote the application of LCA for WRI, it is critical to incorporate local impact of water pollutants. Organic pollution, a main type of water pollution, has not been given much consideration...

Production and immobilization of lipase PCL and its application in synthesis of α‐linolenic acid‐rich diacylglycerol

α‐Linolenic acid‐rich diacylglycerol has been demonstrated with promising health promotion functions. This study examined the production, immobilization of lipase PCL, and its application in the synthesis of diacylglycerol by esterification of α‐linolenic acid with glycerol. The resin ECR8806 was selected as an effective support for the...

Optimization of culturing conditions for isolated Arthrobacter sp. ZXY-2, an effective atrazine-degrading and salt-adaptive bacterium

The increasing salinity in aquatic environments has had a negative impact on the biodegradation of atrazine, an extensively used herbicide which has been proven to pollute soil and water ecosystems. In the present study, a novel atrazine-degrading strain (ZXY-2) was isolated from industrial wastewater and identified as the Arthrobacter genus...

Structural modulation and electronic structural features in the charge ordered state of La0.5Sr1.5MnO4

Advances in chloride diffusion of concrete exposed to marine field environment

For elaborating the research significance, goal, content and representative results of the concrete marine field exposure experiments all over the world, we have collected a large number of research literature since 1905. The longest exposure test for concrete has reached 62 years and, most importantly, concrete exposure experiments have made...