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Goetze, Joris (author), Yarulina, I. (author), Gascon, Jorge (author), Kapteijn, F. (author), Weckhuysen, Bert M. (author)In small-pore zeolite catalysts, where the size of the pores is limited by eight-ring windows, aromatic hydrocarbon pool molecules that are formed inside the zeolite during the Methanol-to-Olefins (MTO) process cannot exit the pores and are retained inside the catalyst. Hydrocarbon species whose size is comparable to the size of the zeolite...journal article 2018
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Goetze, Joris (author), Meirer, Florian (author), Yarulina, I. (author), Gascon, Jorge (author), Kapteijn, F. (author), Ruiz-Martínez, Javier (author), Weckhuysen, Bert M. (author)The nature and evolution of the hydrocarbon pool (HP) species during the Methanol-to-Olefins (MTO) process for three small-pore zeolite catalysts, with a different framework consisting of large cages interconnected by small eight-ring windows (CHA, DDR, and LEV) was studied at reaction temperatures between 350 and 450 °C using a combination...journal article 2017
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Sun, X. (author), Olivos Suarez, A.I. (author), Oar-Arteta Gonzalez, L. (author), Rozhko, E. (author), Osadchii, D. (author), Bavykina, A.V. (author), Kapteijn, F. (author), Gascon, Jorge (author)A Co@N-doped carbon (Co@ NC) hybrid was synthesized by thermal decomposition of the metal–organic framework (MOF) ZIF-67 under N2 atmosphere. These hybrid materials exhibit outstanding catalytic activity and chemoselectivity for the conversion of a wide range of substituted nitroarenes to their corresponding anilines under relatively mild...journal article 2017
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Santos, Vera P. (author), Borgers, Liam (author), Sartipi, Sina (author), van der Linden, B. (author), Dugulan, A.I. (author), Chojecki, A (author), Davidian, T (author), Ruitenbeek, M (author), Meima, GR (author), Kapteijn, F. (author), Makkee, M. (author), Gascon, Jorge (author)tA series of Fe-Ti mixed oxide model catalysts containing different Ti/Fe ratios were synthesized andapplied as catalysts for the High Temperature Fischer-Tropsch reaction (HTFTS). XRD, H2-TPR and in situMössbauer and XAFS spectroscopy were applied to evaluate the role of Ti on the physical and chemicalproperties of Fe within the mixed metal...journal article 2017
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Liu, Chong (author), Van Santen, Rutger A. (author), Poursaeidesfahani, A. (author), Vlugt, T.J.H. (author), Pidko, Evgeny A. (author), Hensen, Emiel J M (author)The alkylation of isobutane with light alkenes plays an essential role in modern petrochemical processes for the production of high-octane gasoline. In this study we have employed periodic DFT calculations combined with microkinetic simulations to investigate the complex reaction mechanism of isobutane–propene alkylation catalyzed by zeolitic...journal article 2017
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Skupien, E. (author), Berger, R.J. (author), Santos, V.P. (author), Gascon, J. (author), Makkee, M. (author), Kreutzer, M.T. (author), Kooyman, P.J. (author), Moulijn, J.A. (author), Kapteijn, F. (author)Benzyl alcohol oxidation was carried out in toluene as solvent, in the presence of the potentially inhibiting oxidation products benzaldehyde and benzoic acid. Benzoic acid, or a product of benzoic acid, is identified to be the inhibiting species. The presence of a basic potassium salt (K2CO3 or KF) suppresses this inhibition, but promotes the...journal article 2014
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- Silberova, B.A.A. (author), Makkee, M. (author), Moulijn, J.A. (author) journal article 2007