Structural and Optical Properties of Thin Film β-Ta upon Exposure to Hydrogen to Asses Its Applicability as Hydrogen Sensing Material

Here, we study the structural and optical properties of tetragonal β-tantalum-sputtered thin films both ex situ and when exposed to hydrogen, with a focus on optical hydrogen sensing applications. Using optical transmission measurements, out-of-plane and in-plane X-ray diffraction, and X-ray and neutron reflectometry, we show that thin film β...

Tuning the Properties of Thin-Film TaRu for Hydrogen-Sensing Applications

Accurate, cost-efficient, and safe hydrogen sensors will play a key role in the future hydrogen economy. Optical hydrogen sensors based on metal hydrides are attractive owing to their small size and costs and the fact that they are intrinsically safe. These sensors rely on suitable sensing materials, of which the optical properties change...

Tantalum-Palladium: Hysteresis-Free Optical Hydrogen Sensor Over 7 Orders of Magnitude in Pressure with Sub-Second Response

Hydrogen detection in a reliable, fast, and cost-effective manner is a prerequisite for the large-scale implementation of hydrogen in a green economy. Thin film Ta_1−yPd_y is presented as an effective optical sensing material with extremely wide sensing ranges covering at least 7 orders of magnitude in hydrogen pressure....

Direct Comparison of PdAu Alloy Thin Films and Nanoparticles upon Hydrogen Exposure

Nanostructured metal hydrides are able to efficiently detect hydrogen in optical sensors. In the literature, two nanostructured systems based on metal hydrides have been proposed for this purpose each with its own detection principle: continuous sub-100 nm thin films read out via optical reflectance/transmittance changes and nanoparticle arrays...