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Kiecana, A. (author), Kwakernaak, C. (author), van Dijk, N.H. (author), Brück, E.H. (author)The effect of the heat treatment on the magnetism, magnetocaloric effect and microstructure formation has been systematically studied in Fe-rich (Mn,Fe)<sub>y</sub>(P,Si) melt-spun ribbons (1.80 ≤ y ≤ 2.00). XRD, SEM and EDS measurements demonstrate that a metal deficiency prompts the stable (Mn,Fe)Si phase, whereas in the metal-rich region...journal article 2023
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Zhang, F. (author), Smits, Sebastian (author), Kiecana, A. (author), Batashev, I. (author), Shen, Q. (author), van Dijk, N.H. (author), Brück, E.H. (author)The influence of doping with the 5d transition metal W has been studied in the quaternary (Mn,Fe)<sub>2</sub>(P,Si) based giant magnetocaloric compounds, which is one of the most promising systems for magnetic refrigeration. It is found that W substitution can separately decrease the Curie temperature T<sub>C</sub> and retain the thermal...journal article 2023
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Zhang, F. (author), Batashev, I. (author), van Dijk, N.H. (author), Brück, E.H. (author)The influence of off-stoichiometry and of doping with the 5d transition metal Ta has been studied in the quaternary (Mn,Fe)<sub>2</sub>(P,Si)-based compound, which is one of the most promising materials systems for magnetic refrigeration. It is found that Ta substitution can decrease the transition temperature T<sub>tr</sub>, while the...journal article 2023
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Shen, Q. (author), Zhang, F. (author), Dugulan, A.I. (author), van Dijk, N.H. (author), Brück, E.H. (author)In this work, the magnetocaloric effect and negative thermal expansion in melt-spun Fe<sub>2</sub>Hf<sub>0.83</sub>Ta<sub>0.17</sub> Laves phase alloys were studied. Compared to arc-melted alloys, which undergo a first-order magnetoelastic transition from the ferromagnetic to the antiferromagnetic phase, melt-spun alloys exhibit a second...journal article 2023
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Kiecana, A. (author), Schaefers, W. (author), Thijs, M. (author), Dankelman, B.J.R. (author), Ojiyed, H. (author), Batashev, I. (author), Zhang, F. (author), van Dijk, N.H. (author), Brück, E.H. (author)Structural, magnetic and magnetocaloric properties of Mn<sub>3</sub>Sn<sub>1-</sub><sub>x</sub>Zn<sub>x</sub>C antiperovskite carbides have been studied. With increasing Zn content the first-order magnetic transition (FOMT) is weakened. The Curie temperature (T<sub>C</sub>) reduces first from 273 to 197 K and when x > 0.3, T<sub>C</sub>...journal article 2023
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Wu, Z. (author), De Krom, Tom (author), Colombi, G. (author), Chaykina, D. (author), Van Hattem, Gijs (author), Schut, H. (author), Dickmann, Marcel (author), Brück, E.H. (author), Dam, B. (author), Eijt, S.W.H. (author)Rare-earth (RE) oxyhydride thin films show a color-neutral, reversible photochromic effect at ambient conditions. The origin of the photochromism is the topic of current investigations. Here, we investigated the lattice defects, electronic structure, and crystal structure of photochromic YHxOy and GdHxOy thin films deposited by magnetron...journal article 2022
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Ariëns, M.I. (author), van de Water, L. G.A. (author), Dugulan, A.I. (author), Brück, E.H. (author), Hensen, E. J.M. (author)Copper promotion of chromium-doped iron oxide prepared via co-precipitation for high-temperature water–gas shift (WGS) catalysis is investigated. Low-temperature Mössbauer spectra demonstrate that copper doping delays hematite (α-Fe<sub>2</sub>O<sub>3</sub>) formation in the fresh catalyst, favoring the formation of small crystallites of...journal article 2022
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Shen, Q. (author), Batashev, I. (author), Ojiyed, Hamutu (author), Zhang, F. (author), van Dijk, N.H. (author), Brück, E.H. (author)The influence of excess Mn on the magnetoelastic ferromagnetic-to-antiferromagnetic transition T<sub>t</sub> in the magnetocaloric compound (Mn,Cr)<sub>2</sub>Sb has been studied. With increasing excess Mn the magnetoelastic transition temperature for (Mn,Cr)<sub>2</sub>Sb initially increases and then decreases. This trend is accompanied by a...journal article 2022
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Zhang, F. (author), Taake, Chris (author), Huang, B. (author), You, X. (author), Ojiyed, Hamutu (author), Shen, Q. (author), Dugulan, A.I. (author), Caron, Luana (author), van Dijk, N.H. (author), Brück, E.H. (author)In the field of nanoscale magnetocaloric materials, novel concepts like micro-refrigerators, thermal switches, microfluidic pumps, energy harvesting devices and biomedical applications have been proposed. However, reports on nanoscale (Mn,Fe)<sub>2</sub>(P,Si)-based materials, which are one of the most promising bulk materials for solid-state...journal article 2022
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You, X. (author), Maschek, M. (author), van Dijk, N.H. (author), Brück, E.H. (author)The phase diagram of the magnetocaloric Mn<sub>x</sub> Fe<sub>2−x</sub> P<sub>1−y</sub> Si<sub>y</sub> quaternary compounds was established by characterising the structure, thermal and magnetic properties in a wide range of compositions (for a Mn fraction of 0.3 ≤ x < 2.0 and a Si fraction of 0.33 ≤ y ≤ 0.60). The highest ferromagnetic...journal article 2022
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Zhang, F. (author), Westra, Kevin (author), Shen, Q. (author), Batashev, I. (author), Kiecana, A. (author), van Dijk, N.H. (author), Brück, E.H. (author)The novel all-d-metal Ni(Co)MnTi based magnetic Heusler alloys provide an adjustable giant magnetocaloric effect and good mechanical properties. We report that the second-order magnetic phase transition can be tailored in this all-d-metal NiCoMnTi based Heusler system by optimizing the Mn/Ti ratio, resulting in a reversible ferromagnetic-to...journal article 2022
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Zhang, F. (author), Batashev, I. (author), van Dijk, N.H. (author), Brück, E.H. (author)The all-d-metal Ni-(Co)-Mn-Ti-based Heusler alloys are found to show a giant magnetocaloric effect near room temperature and are thereby potential materials for solid-state refrigeration. However, the relative large thermal hysteresis and the moderate ferromagnetic magnetization provides limitations for real applications. In the present study...journal article 2022
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Zhang, F. (author), Batashev, I. (author), Shen, Q. (author), Wu, Z. (author), Smith, Ronald I. (author), de Wijs, Gilles A. (author), van Dijk, N.H. (author), Brück, E.H. (author)The quarternary (Mn,Fe)<sub>2</sub>(P,Si)-based materials with a giant magnetocaloric effect (GMCE) at the ferromagnetic transition T<sub>C</sub> are promising bulk materials for solid-state magnetic refrigeration. In the present study we demonstrate that doping with the light elements fluorine and sulfur can be used to adjust T<sub>C</sub>...journal article 2022
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Kiecana, A. (author), Batashev, I. (author), Dugulan, A.I. (author), Kwakernaak, C. (author), Pieter, L. (author), Zhang, F. (author), van Dijk, N.H. (author), Brück, E.H. (author)The effect of Co and Ni doping on the structure, magnetic and magnetocaloric properties of Fe-rich (Mn,Fe)<sub>2</sub>(P,Si) compounds was studied. With increasing Co and Ni content, both the Curie temperature (T<sub>c</sub>) and the thermal hysteresis (ΔT<sub>hys</sub>) decreased, whereas the hexagonal P-62 m crystal structure was maintained...journal article 2022
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Miao, Xuefei (author), Gong, Yong (author), Zhang, F. (author), You, Yurong (author), Caron, Luana (author), Qian, Fengjiao (author), Xu, Feng (author), van Dijk, N.H. (author), Brück, E.H. (author)Magnetocaloric materials undergoing reversible phase transitions are highly desirable for magnetic refrigeration applications. (Mn,Fe)<sub>2</sub>(P,Si) alloys exhibit a giant magnetocaloric effect accompanied by a magnetoelastic transition, while the noticeable irreversibility causes drastic degradation of the magnetocaloric properties...journal article 2022
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Bao, L. L. (author), Yibole, H. (author), Xu, J. (author), Ou, Z. Q. (author), Haschuluu, O. (author), Tegus, O. (author), van Dijk, N.H. (author), Brück, E.H. (author), Guillou, F. (author)In view of the interest that (Fe,Co)<sub>2</sub>(P,Si) compounds have as potential permanent magnets, their structural and magnetic phase diagrams are explored focusing on establishing the range where the hexagonal Fe<sub>2</sub>P-type structure is observed. In Fe<sub>1.93-x</sub>Co<sub>x</sub>P<sub>1-y</sub>Si<sub>y</sub>, the highest Si...journal article 2022
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Li, Yan (author), Huang, B. (author), Lin, Guoxing (author), Chen, Jincan (author), Brück, E.H. (author)MnFeP(As, Ge, Si) series compounds are three kinds of MnFe-based magnetocaloric materials, which have giant magnetocaloric effect. In this work, the experimental characteristic curves of new style Mn-Fe-P-Si materials, numbered as 1: Mn<sub>1.32</sub>Fe<sub>0.67</sub>P<sub>0.52</sub>Si<sub>0.49</sub>, 2: Mn<sub>1.37</sub>Fe<sub>0.63</sub>P...journal article 2022
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Lai, J. (author), You, X. (author), Law, Jiayan (author), Franco, Victorino (author), Huang, B. (author), Bessas, Dimitrios (author), Maschek, M. (author), Zeng, Dechang (author), van Dijk, N.H. (author), Brück, E.H. (author)Large thermal hysteresis in the (Mn,Fe)2(P,Si) system hinders an efficient heat exchange and thus limits the magnetocaloric applications. Substitution of manganese by vanadium in the Mn1-x1Vx1Fe0.95P0.593Si0.33B0.077 and Mn1-x2Vx2Fe0.95P0.563Si0.36B0.077 compounds enable a significant reduction in the thermal hysteresis without losing the giant...journal article 2022
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Ariëns, M.I. (author), Van De Water, L. G.A. (author), Dugulan, A.I. (author), Brück, E.H. (author), Hensen, E. J.M. (author)A set of doped iron oxides (chromium, aluminum, gallium, indium, manganese, zinc, niobium) were prepared by a one-step coprecipitation/calcination approach evaluated for their WGS activity under industrially relevant conditions and characterized in detail. The WGS activity after ageing the doped catalyst for 4 days at 25 bar follows the order...journal article 2022
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Fu, Y. (author), Fang, H. (author), Monaco, F. (author), Cloetens, P. (author), Tichelaar, F.D. (author), van Meel, J.G. (author), Brück, E.H. (author), van der Zwaag, S. (author), van Dijk, N.H. (author)Constant stress creep experiments at 550 °C were performed on a high-purity Fe-3Au-4W (wt.%) ternary alloy with about 1 at.% supersaturation for Au and W in order to study self healing of grain-boundary cavities by both Au-rich and W-rich precipitates. Using synchrotron X-ray nano-tomography, the development of the creep cavities and the...journal article 2022