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Fröhlich, D. (author), Pantatosaki, E. (author), Kolokathis, P.D. (author), Markey, K (author), Reinsch, H. (author), Baumgartner, M. (author), van der Veen, M.A. (author), De Vos, D.E. (author), Stock, N (author), Papadopoulos, G.K. (author), Henninger, S.K. (author), Janiak, C. (author)Aluminium isophthalate CAU-10-H [Al(OH)(benzene-1,3-dicarboxylate)]·nH2O exhibits water adsorption characteristics which make it a promising adsorbent for application in heat-exchange processes. Herein we prepared a stable coating of this MOF and evaluated its long-term stability under closed-cycle conditions for 10 000 water adsorption and...journal article 2016
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Second harmonic generation microscopy reveals hidden polar organization in fluoride doped MIL-53(Fe)Markey, K. (author), Putzeys, T. (author), Horcajada, P. (author), Devic, T. (author), Guillou, N. (author), Wübbenhorst, M. (author), Van Cleuvenbergen, S. (author), Verbiest, T. (author), De Vos, D.E. (author), Van der Veen, M.A. (author)Polar metal–organic frameworks have potential applications as functional non-linear optical, piezoelectric, pyroelectric and ferroelectric materials. Using second harmonic generation microscopy we found that fluoride doping of the microporous iron(III) terephthalate MOF MIL-53(Fe) induces a polar organization in its structure, which was not...journal article 2016