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Kavun, Vitalii (author), Uslamin, E. (author), van der Linden, B. (author), Canossa, Stefano (author), Goryachev, A. (author), Bos, Emma E. (author), Garcia Santaclara, J. (author), Smolentsev, Grigory (author), Repo, Eveliina (author), van der Veen, M.A. (author)Titanium-based metal-organic framework, NH2-MIL-125(Ti), has been widely investigated for photocatalytic applications but has low activity in the hydrogen evolution reaction (HER). In this work, we show a one-step low-cost postmodification of NH2-MIL-125(Ti) via impregnation of Co(NO3)2. The resulting Co@NH2-MIL-125(Ti) with embedded single...journal article 2023
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Garcia Santaclara, J. (author)The fascinating chemical and physical properties of MOFs have recently stimulated exploration of their application for photocatalysis. Despite the intense research effort, the efficiencies of most photocatalytic MOFs for solar fuel generation are still very modest. In this introduction we analyse the current status of the field and stress the...doctoral thesis 2017
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Garcia Santaclara, J. (author), Olivos Suarez, A.I. (author), du Fossé, Indy (author), Houtepen, A.J. (author), Hunger, J (author), Kapteijn, F. (author), Gascon, Jorge (author), van der Veen, M.A. (author)The highly porous titanium based metal–organic framework NH2-MIL-125(Ti) has recently attracted significant attention in the field of photocatalysis as a promising material for H+ reduction. This work reveals charge transfer upon visible light illumination from this MOF to two different charge acceptors, as an alternative to sacrificial electron...journal article 2017
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Garcia Santaclara, J. (author), Kapteijn, F. (author), Gascon, Jorge (author), van der Veen, M.A. (author)The fascinating chemical and physical properties of MOFs have recently stimulated exploration of their application for photocatalysis. Despite the intense research effort, the efficiency of most photocatalytic MOFs for solar fuel generation is still very modest. In this highlight we analyse the current status of the field and stress the...journal article 2017
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Nasalevich, M. (author), Hendon, Christopher H. (author), Garcia Santaclara, J. (author), Svane, Katrine (author), van der Linden, B. (author), Veber, Sergey L. (author), Fedin, Matvey V. (author), Houtepen, A.J. (author), van der Veen, M.A. (author), Kapteijn, F. (author), Walsh, Aron (author), Gascon, Jorge (author)Metal-organic frameworks (MOFs) containing d<sup>0</sup> metals such as NH<sub>2</sub>-MIL-125(Ti), NH<sub>2</sub>-UiO-66(Zr) and NH<sub>2</sub>-UiO-66(Hf) are among the most studied MOFs for photocatalytic applications. Despite structural similarities, we demonstrate that the electronic properties of these MOFs are markedly different. As...journal article 2016