Searched for: author%3A%22Juan-Alca%C3%B1iz%2C+J.%22
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Serra-Crespo, P. (author), Dikhtiarenko, A. (author), Stavitski, E. (author), Juan-Alcañiz, J. (author), Kapteijn, F. (author), Coudert, F.X. (author), Gascon, J. (author)
We report a series of powder X-ray diffraction experiments performed on the soft porous crystals MIL-53(Al) and NH2-MIL-53(Al) in a diamond anvil cell under different pressurization media. Systematic refinements of the obtained powder patterns demonstrate that these materials expand along a specific direction while undergoing total volume...
journal article 2014
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Juan-Alcaniz, J. (author)
The last few decades have witnessed the unprecedented explosion of a new research field built around Metal-Organic Frameworks (MOFs). MOFs are crystalline porous solids consisting of metal ions (also named clusters) coordinated to often rigid organic molecules (also called ligands) to form one- two-, or three- dimensional structures. This...
doctoral thesis 2013
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Juan-Alcaniz, J. (author), Gielisse, R. (author), Lago, A.B. (author), Ramos-Fernandez, E.V. (author), Serra-Crespo, P. (author), Devic, T. (author), Guillou, N. (author), Serre, C. (author), Kapteijn, F. (author), Gascon, J. (author)
In this work, the inclusion of free sulfonic acid groups in highly stable MOFs is explored. The synthesized catalysts have been applied in a model esterification reaction. Two metal organic frameworks bearing sulfonic acid moieties are investigated: HSO3-MIL-101(Cr) synthesized following different approaches and a new structure based on HSO3-bdc...
journal article 2013