Searched for: author:"Kapteijn, F."
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Andres Garcia, E. (author), Dikhtiarenko, Alla (author), Fauth, Francois (author), Silvestre-Albero, Joaquin (author), Ramos-Fernandez, Enrique V. (author), Gascon Sabate, J. (author), Corma, Avelino (author), Kapteijn, F. (author)
Clathrates are well-known compounds whose low thermal stability makes them extremely rare and appreciated. Although their formation mechanism is still surrounded by many uncertainties, these ice-like structures have the potential to be an alternative for transport and storage of different gases, especially methane. For the formation of...
journal article 2019
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Karakiliç, Pelin (author), Toyoda, Ryo (author), Kapteijn, F. (author), Nijmeijer, Arian (author), Winnubst, Louis (author)
The transformation of microporous, amorphous silica membranes into b-oriented silicalite-1 (MFI) zeolite layers via in-situ crystallisation was investigated. The effect of synthesis parameters, such as the type and concentration of the silica precursor, crystallisation time and temperature, on the morphology of silicalite-1 (MFI) zeolite...
journal article 2019
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Vollmer, I. (author), Kosinov, N. (author), Szecsenyi, Agnes (author), Li, G. (author), Yarulina, I. (author), Abou-Hamad, Edy (author), Gurinov, Andrei (author), Ould-Chikh, Samy (author), Aguilar-Tapia, Antonio (author), Hazemann, Jean-Louis (author), Pidko, E.A. (author), Hensen, Emiel J M (author), Kapteijn, F. (author), Gascon Sabate, J. (author)
The active sites on the methane dehydroaromatization (MDA) catalyst Mo/HZSM-5 are very hard to characterize, because they are present in various geometries and sizes and only form under reaction conditions with methane at 700 °C. To address these issues an experimental strategy is presented that enables distinguishing different active sites...
journal article 2019
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Carvalho Pereira, Joana P.C. (author), Andres Garcia, E. (author), Kapteijn, F. (author), van der Wielen, L.A.M. (author), Straathof, Adrie J.J. (author)
Biobased 2-butanol offers high potential as biofuel, but its toxicity toward microbial hosts calls for efficient techniques to alleviate product inhibition in fermentation processes. Aiming at the selective recovery of 2-butanol, the feasibility of a process combining in situ vacuum stripping followed by vapor adsorption has been assessed...
journal article 2019
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Poursaeidesfahani, A. (author), Andres Garcia, E. (author), de Lange, M.F. (author), Torres-Knoop, Ariana (author), Rigutto, Marcello (author), Nair, Nitish (author), Kapteijn, F. (author), Gascon Sabate, J. (author), Dubbeldam, D. (author), Vlugt, T.J.H. (author)
A mathematical model is used to predict adsorption isotherms from experimentally measured breakthrough curves. Using this approach, by performing only breakthrough experiments for a mixture of two (or more) components, one can obtain pure component adsorption isotherms up to the pressure of the experiment. As a case study, the adsorption of...
journal article 2019
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Wang, Y. (author), Kapteijn, F. (author), Makkee, M. (author)
. The transient...
journal article 2018
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Liu, X. (author), Wang, X. (author), Bavykina, A.V. (author), Chu, L. (author), Shan, M. (author), Sabetghadam, Anahid (author), Miro, H. (author), Kapteijn, F. (author), Gascon Sabate, J. (author)
The preparation and the performance of mixed matrix membranes based on metal-organic polyhedra (MOPs) are reported. MOP fillers can be dispersed as discrete molecular units (average 9 nm in diameter) when low filler cargos are used. In spite of the low doping amount (1.6 wt %), a large performance enhancement in permeability, aging resistance...
journal article 2018
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Wang, R. (author), Sun, X. (author), Ould-Chikh, Samy (author), Osadchii, D. (author), Kapteijn, F. (author), Gascon Sabate, J. (author)
A nitrogen-doped carbon was synthesized through the pyrolysis of the well-known metal-organic framework ZIF-8, followed by a subsequent acid treatment, and has been applied as a catalyst in the electrochemical reduction of carbon dioxide. The resulting electrode shows Faradaic efficiencies to carbon monoxide as high as ∼78%, with hydrogen...
journal article 2018
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Etxeberria Benavides, M. (author), David, Oana (author), Johnson, Timothy (author), Łozińska, Magdalena M. (author), Orsi, Angelica (author), Wright, Paul A. (author), Mastel, Stefan (author), Hillenbrand, Rainer (author), Kapteijn, F. (author), Gascon Sabate, J. (author)
capture could be easily implemented in existing power plants....
journal article 2018
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Goetze, Joris (author), Yarulina, I. (author), Gascon Sabate, J. (author), Kapteijn, F. (author), Weckhuysen, Bert M. (author)
In small-pore zeolite catalysts, where the size of the pores is limited by eight-ring windows, aromatic hydrocarbon pool molecules that are formed inside the zeolite during the Methanol-to-Olefins (MTO) process cannot exit the pores and are retained inside the catalyst. Hydrocarbon species whose size is comparable to the size of the zeolite...
journal article 2018
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Melián-Cabrera, Ignacio (author), Espinosa, Silvia (author), Mentruit, Cristina (author), Murray, Blaine (author), Falco, Lorena (author), Socci, Joseph (author), Kapteijn, F. (author), Moulijn, J.A. (author)
O decomposition under industrial tail-gas conditions. In the synthesis procedure, we evaluate the very demanding constraints for scale-up; i.e. large reactor volumes are typically needed, and long processing times and considerable amounts...
journal article 2018
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Shan, M. (author), Liu, X. (author), Wang, X. (author), Yarulina, I. (author), Seoane de la Cuesta, B. (author), Kapteijn, F. (author), Gascon Sabate, J. (author)
capture or reduce energy intensity in other...
journal article 2018
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Shan, M. (author), Seoane de la Cuesta, B. (author), Pustovarenko, O. (author), Wang, X. (author), Liu, X. (author), Yarulina, I. (author), Abou-Hamad, Edy (author), Kapteijn, F. (author), Gascon Sabate, J. (author)
and the dependency on the filler porosity. BILPs with two different porosities (BILP-101 and RT-BILP-101) were synthesized through controlling the...
journal article 2018
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Sabetghadam Esfahani, A. (author), Liu, X. (author), Orsi, Angelica (author), Lozinska, Magdalena M. (author), Johnson, Timothy (author), Jansen, K.M.B. (author), Wright, Paul A. (author), Carta, M (author), McKeown, NB (author), Kapteijn, F. (author), Gascon Sabate, J. (author)
Membrane separation for gas purification is an energy-efficient and environment-friendly technology. However, the development of high performance membranes is still a great challenge. In principle, mixed matrix membranes (MMMs) have the potential to overcome current materials limitations, but in practice there is no straightforward method to...
journal article 2018
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Birdja, Yuvraj Y. (author), Vos, Rafaël E. (author), Wezendonk, T.A. (author), Jiang, Lin (author), Kapteijn, F. (author), Koper, M.T.M. (author)
2 journal article 2018
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Sabetghadam, Anahid (author), Liu, X. (author), Benzaqui, Marvin (author), Gkaniatsou, Effrosyni (author), Orsi, Angelica (author), Lozinska, Magdalena M. (author), Sicard, Clemence (author), Johnson, Timothy (author), Steunou, Nathalie (author), Wright, Paul A. (author), Serre, Christian (author), Gascon Sabate, J. (author), Kapteijn, F. (author)
-MIL-53(Al), MIL-69(Al), MIL-96(Al) and ZIF-94) with various chemical functionalities, topologies, and dimensionalities...
journal article 2018
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Vollmer, I. (author), Yarulina, I. (author), Kapteijn, F. (author), Gascon Sabate, J. (author)
To secure future supply of aromatics, methane is a commercially interesting alternative feedstock. Direct conversion of methane into aromatics combines the challenge of activating one of the strongest C-H bonds in all hydrocarbons with the selective aromatization over zeolites. To address these challenges, smart catalyst and process design...
journal article 2018
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Vollmer, I. (author), van der Linden, B. (author), Ould-Chikh, Samy (author), Aguilar-Tapia, Antonio (author), Yarulina, I. (author), Abou-Hamad, Edy (author), Sneider, Yuri G. (author), Olivos Suarez, A.I. (author), Hazemann, Jean-Louis (author), Kapteijn, F. (author), Gascon Sabate, J. (author)
The mechanism of methane activation on Mo/HZSM-5 is not yet fully understood, despite the great interest in methane dehydroaromatization (MDA) to replace aromatics production in oil refineries. It is difficult to assess the exact nature of the active site due to fast coking. By pre-carburizing Mo/HZSM-5 with carbon monoxide (CO), the MDA active...
journal article 2018
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de Lange, M.F. (author), Kapteijn, F. (author), Moultos, O. (author), Vlugt, T.J.H. (author)
A computational screening of 2930 experimentally synthesized metal-organic frameworks (MOFs) is carried out to find the best-performing structures for adsorption-driven cooling (AC) applications with methanol and ethanol as working fluids. The screening methodology consists of four subsequent screening steps for each adsorbate. At the end of...
journal article 2018
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Vollmer, I. (author), Li, G. (author), Yarulina, I. (author), Kosinov, N. (author), Hensen, Emiel J M (author), Houben, Klaartje (author), Mance, Deni (author), Baldus, Marc (author), Gascon Sabate, J. (author), Kapteijn, F. (author)
Although the local geometry of Mo in Mo/HZSM-5 has been characterized before, we present a systematic way to manipulate the configuration of Mo and link it to its catalytic properties. The location and geometry of cationic Mo-complexes, the precursor of the active metal site for methane dehydroaromatization, are altered by directing the way...
journal article 2018
Searched for: author:"Kapteijn, F."
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