"uuid","repository link","title","author","contributor","publication year","abstract","subject topic","language","publication type","publisher","isbn","issn","patent","patent status","bibliographic note","access restriction","embargo date","faculty","department","research group","programme","project","coordinates" "uuid:edbcde5f-0ec6-4683-9fcd-891500d198a8","http://resolver.tudelft.nl/uuid:edbcde5f-0ec6-4683-9fcd-891500d198a8","Metal-Organic-Framework-Mediated Nitrogen-Doped Carbon for CO2 Electrochemical Reduction","Wang, R. (TU Delft ChemE/Catalysis Engineering); Sun, X. (TU Delft ChemE/Catalysis Engineering); Ould-Chikh, Samy (King Abdullah University of Science and Technology); Osadchii, D. (TU Delft ChemE/Catalysis Engineering); Bai, F. (TU Delft ChemE/Catalysis Engineering; TU Delft Applied Sciences); Kapteijn, F. (TU Delft ChemE/Catalysis Engineering); Gascon, Jorge (TU Delft ChemE/Catalysis Engineering; King Abdullah University of Science and Technology)","","2018","A nitrogen-doped carbon was synthesized through the pyrolysis of the well-known metal-organic framework ZIF-8, followed by a subsequent acid treatment, and has been applied as a catalyst in the electrochemical reduction of carbon dioxide. The resulting electrode shows Faradaic efficiencies to carbon monoxide as high as ∼78%, with hydrogen being the only byproduct. The pyrolysis temperature determines the amount and the accessibility of N species in the carbon electrode, in which pyridinic-N and quaternary-N species play key roles in the selective formation of carbon monoxide.","CO electrochemical reduction; electrocatalyst; MOF-mediated synthesis; nitrogen-doped carbon; ZIF-8","en","journal article","","","","","","Accepted Author Manuscript","","2019-05-18","Applied Sciences","","ChemE/Catalysis Engineering","","",""