Competitive and Cooperative CO₂-H₂O Adsorption through Humidity Control in a Polyimide Covalent Organic Framework

In order to capture and separate CO2 from the air or flue gas streams through nanoporous adsorbents, the influence of the humidity in these streams has to be taken into account as it hampers the capture process in two main ways: (1) water preferentially binds to CO2 adsorption sites and lowers the overall capacity, and (2) water causes...

Impact of flow-induced disturbances during synthesis on the photophysical properties of naphthalene diimide covalent organic frameworks

Flow-induced disturbances were applied during the synthesis of a naphthalene diimide covalent organic framework (NDI-COF), which resulted in different COF polymer networks. We discovered that a high intensity of stirring resulted in more aggregated structures on both the micro- and nano-length scale. Subsequently, these structures absorbed...

Synthesis and Structure-Property Relationships of Polyimide Covalent Organic Frameworks for Carbon Dioxide Capture and (Aqueous) Sodium-Ion Batteries

Covalent organic frameworks (COFs) are an emerging material family having several potential applications. Their porous framework and redox-active centers enable gas/ion adsorption, allowing them to function as safe, cheap, and tunable electrode materials in next-generation batteries, as well as CO2 adsorption materials for carbon-capture...