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Gorczak, N. (author), Renaud, N. (author), Galan, E. (author), Eelkema, R. (author), Siebbeles, L.D.A. (author), Grozema, F.C. (author)
Quantum interference is a well-known phenomenon that dictates charge transport properties of single molecule junctions. However, reports on quantum interference in donor-bridge-acceptor molecules are scarce. This might be due to the difficulties in meeting the conditions for the presence of quantum interference in a donor-bridge-acceptor system....
journal article 2016
document
Gorczak, N. (author), Renaud, N. (author), Tarkuç, S. (author), Houtepen, A.J. (author), Eelkema, R. (author), Siebbeles, L.D.A. (author), Grozema, F.A. (author)
Destructive quantum interference has been shown to strongly reduce charge tunneling rates across molecular bridges. The current consensus is that destructive quantum interference occurs in cross-conjugated molecules, while linearly conjugated molecules exhibit constructive interference. Our experimental results on photoinduced charge transfer in...
journal article 2015
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Günba?, D.D. (author), Xue, C. (author), Patwardhan, S. (author), Fravventura, M.C. (author), Zhang, H. (author), Jager, W.F. (author), Sudhölter, E.J.R. (author), Laurens, D.A. (author), Siebbeles, L.D.A. (author), Savenije, T.J. (author), Jin, S. (author), Grozema, F.C. (author)
In this communication we report on the synthesis and charge mobility of highly soluble perylenebisimid derivatives.We show that introduction of alkylester side chains results in compounds combining a high solubility with charge mobilities up to 0.22 cm2 V_1 s_1. These materials are therefore interesting as an electron acceptor for solution...
journal article 2014
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Petrus, M.L. (author), Bouwer, R.K.M. (author), Lafont, U. (author), Murthy, D.H.K. (author), Kist, R.J.P. (author), Böhm, M.L. (author), Olivier, Y. (author), Savenije, T.J. (author), Siebbeles, L.D.A. (author), Greenham, N.C. (author), Dingemans, T.J. (author)
Three conjugated triphenylamine-based poly(azomethine)s were prepared via well-known polycondensation chemistry using cheap and readily available starting materials and the results were contrasted with rrP3HT. Three functionalized diaminetriphenylamines (TPA(X), X ¼ –H, –OMe, –CN) were polymerized in a simple one-step process with 2,3...
journal article 2013
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