Bridging intermittency: with iron electrodes

We have to overcome the intermittent nature of renewables to master the energy transition. Harvesting renewable electricity is only part of the solution. Energy storage is another part and the main challenge of our time. Only with efficient storage solutions can big industries switch to renewables.<br/>Electricity storage is most efficient with...

Hydrogen Storage on Porous Carbon Adsorbents: Rediscovery by Nature-Derived Algorithms in Random Forest Machine Learning Model

Porous carbons as solid adsorbent materials possess effective porosity characteristics that are the most important factors for gas storage. The chemical activating routes facilitate hydrogen storage by adsorbing on the high surface area and microporous features of porous carbon-based adsorbents. The present research proposed to predict H<sub...

Reversible Hydrogen Storage in Metal-Decorated Honeycomb Borophene Oxide

Two-dimensional (2D) boron-based materials are receiving much attention as H2 storage media due to the low atomic mass of boron and the stability of decorating alkali metals on the surface, which enhance interactions with H2. This work investigates the suitability of Li, Na, and K decorations on 2D honeycomb borophene oxide (B2O) for H2...

Fuel Cell Electric Vehicle as a Power Plant: Techno-Economic Scenario Analysis of a Renewable Integrated Transportation and Energy System for Smart Cities in Two Climates

Renewable, reliable, and affordable future power, heat, and transportation systems require efficient and versatile energy storage and distribution systems. If solar and wind electricity are the only renewable energy sources, what role can hydrogen and fuel cell electric vehicles (FCEVs) have in providing year-round 100% renewable, reliable, and...

Exploring the profit potential of energy storage in a car park using electrolysis, hydrogen storage and fuel cell electric vehicles

The Car Park as Power Plant (CPPP) is a main business concept related to a future integrated sustainable mobility and energy system in which hydrogen is a key energy carrier. In order to investigate the uncertain profitability of the CPPP concept, an optimisation model has been developed of a CPPP system that includes an electrolyser, a hydrogen...

Thermodynamic System Studies for a Natural Gas Combined Cycle (NGCC) Plant with CO2 Capture and Hydrogen Storage with Metal Hydrides

Flexibility in natural gas combined cycle power plants (NGCC) with pre-combustion CO2 capture could be introduced with co-production of hydrogen and subsequent hydrogen storage with metal hydrides (MH). The current work presents a thermodynamic analysis and comparison between steady state ASPEN Plus models of a reference case NGCC plant with no...

Destabilization of magnesium hydride through interface engineering

The aim of this thesis is to study the thermodynamics of hydrogenation of nanoconfined magnesium within a thin film multilayer model system. Magnesium hydride is a potential material for hydrogen storage, which is a key component in a renewable energy system based on hydrogen. In bulk form, magnesium hydride is very stable, which means that...

Hydrogen Storage in Porous Materials and Magnesium Hydrides

In this thesis representatives of two different types of materials for potential hydrogen storage application are presented. Usage of either nanoporous materials or metal hydrides has both operational advantages and disadvantages. A main objective of this thesis is to characterize the hydrogen storage mechanism of selected Metal-Organic...

Micro-fabricated channel with ultra-thin yet ultra-strong windows enables electron microscopy under 4-bar pressure

Transmission electron microscopy (TEM) of (de-)hydrogenation reactions is crucial to characterize efficiency of hydrogen storage materials. The nanoreactor, a micromachined channel with 15-nm-thick windows, effectively confines the gas flow to an electron-transparent chamber during TEM of reactions. Realistic experiments require very high...

Testing facility for hydrogen storage materials designed to simulate application based conditions

For the daily use of hydrogen storage materials, not only their intrinsic storage properties are important, but also equally important is the performance under practical conditions. Besides the techniques already available for the fundamental characterization of storage materials, there is a growing need to test storage materials under...

Thermal stability of gas phase magnesium nanoparticles

In this work we present a unique transmission electron microscopy study of the thermal stability of gas phase synthesized Mg nanoparticles, which have attracted strong interest as high capacity hydrogen storage materials. Indeed, Mg nanoparticles with a MgO shell ( ? 3?nm thick) annealed at 300?°C show evaporation, void formation, and void...

Lightweight sodium alanate thin films grown by reactive sputtering

We report the preparation of sodium alanate, a promising hydrogen storage material, in a thin film form using cosputtering in a reactive atmosphere of atomic hydrogen. We study the phase formation and distribution, and the hydrogen desorption, with a combination of optical and infrared transmission spectroscopy. We show that the hydrogen...

Hydrogen Storage in Nanostructured Light Metal Hydrides

The global energy issues can be solved by the abundantly available hydrogen on earth. Light metals are a compact and safe medium for storing hydrogen. This makes them attractive for vehicular use. Unfortunately, hydrogen uptake and release is slow in light metals at practical temperature and pressure conditions. Catalysts are known to accelerate...

Ca(AlH4)2, CaAlH5, and CaH2+6LiBH4: Calculated dehydrogenation enthalpy, including zero point energy, and the structure of the phonon spectra

The dehydrogenation enthalpies of Ca(AlH4)2, CaAlH5, and CaH2+6LiBH4 have been calculated using density functional theory calculations at the generalized gradient approximation level. Harmonic phonon zero point energy (ZPE) corrections have been included using Parlinski’s direct method. The dehydrogenation of Ca(AlH4)2 is exothermic, indicating...

Towards a hydrogen-driven society? Calculations and neutron scattering on potential hydrogen storage materials

For sustainable development, the resources of the earth need to be maintained and carbon dioxide emission should be avoided. In particular, we need to find an alternative for the use of fossil fuels in vehicles. Since long, hydrogen has been recognised as the fuel of the future because it exhausts only water when used in fuel cells and hardly...