Searched for: subject%3A%22M%25C3%25B6ssbauer%255C%2Bspectroscopy%22
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Belloni, C. (author)This thesis focuses on recycling resources while preserving water quality and availability. This concept is at the basis of a healthy and sustainable society yet works needs to be done. Water scarcity will be a growing challenge that humanity will have to face in the coming years, due to poor resource management and the climate change crisis....doctoral thesis 2023
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Ariëns, M.I. (author)Hydrogen gas is an essential reagent in numerous industrial processes including ammonia synthesis. Ammonia is a key intermediate in the synthesis of nitrogen-based fertilisers, e.g. nitrates and urea. According to recent estimates (2008), approximately half of the world population is fed by nitrogen-based fertilisers of synthetic origin....doctoral thesis 2023
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van Koppen, L.M. (author), Dugulan, A.I. (author), Leendert Bezemer, G. (author), Hensen, Emiel J.M. (author)The study of titania-supported cobalt nanoparticles is relevant for industrial Fischer-Tropsch synthesis (FTS). Herein, we report about various deactivation pathways of cobalt supported on P25 titania (cobalt loading 2–8 wt%) under simulated high conversion conditions using in situ Mössbauer spectroscopy. A fraction of metallic cobalt was...journal article 2023
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Shen, Q. (author), Zhang, F. (author), Dugulan, A.I. (author), van Dijk, N.H. (author), Brück, E.H. (author)In this work, the magnetocaloric effect and negative thermal expansion in melt-spun Fe<sub>2</sub>Hf<sub>0.83</sub>Ta<sub>0.17</sub> Laves phase alloys were studied. Compared to arc-melted alloys, which undergo a first-order magnetoelastic transition from the ferromagnetic to the antiferromagnetic phase, melt-spun alloys exhibit a second...journal article 2023
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van Koppen, L.M. (author), Dugulan, A.I. (author), Hensen, Emiel J.M. (author), Bezemer, G. Leendert (author)The commercial application of cobalt-based Fischer-Tropsch synthesis (FTS) suffers from catalyst deactivation. One of the main deactivation mechanisms under industrial conditions is sintering. In this work, we explored the role of manganese oxide as a structural promoter against sintering in a carbon nanofiber supported cobalt model catalyst....journal article 2022
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Kiecana, A. (author), Batashev, I. (author), Dugulan, A.I. (author), Kwakernaak, C. (author), Pieter, L. (author), Zhang, F. (author), van Dijk, N.H. (author), Brück, E.H. (author)The effect of Co and Ni doping on the structure, magnetic and magnetocaloric properties of Fe-rich (Mn,Fe)<sub>2</sub>(P,Si) compounds was studied. With increasing Co and Ni content, both the Curie temperature (T<sub>c</sub>) and the thermal hysteresis (ΔT<sub>hys</sub>) decreased, whereas the hexagonal P-62 m crystal structure was maintained...journal article 2022
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Ariëns, M.I. (author), Van De Water, L. G.A. (author), Dugulan, A.I. (author), Brück, E.H. (author), Hensen, E. J.M. (author)A set of doped iron oxides (chromium, aluminum, gallium, indium, manganese, zinc, niobium) were prepared by a one-step coprecipitation/calcination approach evaluated for their WGS activity under industrially relevant conditions and characterized in detail. The WGS activity after ageing the doped catalyst for 4 days at 25 bar follows the order...journal article 2022
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Prot, T.J.F. (author), Pannekoek, W. (author), Belloni, C. (author), Dugulan, A.I. (author), Hendrikx, R.W.A. (author), Korving, L. (author), van Loosdrecht, Mark C.M. (author)It was recently discovered that vivianite (Fe<sub>3</sub>(PO<sub>4</sub>)<sub>2</sub>.8H<sub>2</sub>O) could be magnetically extracted from digested activated sludge which opened a new route for phosphorus recovery (Wijdeveld et al. 2022). While its formation in digested sludge is regularly reported, it is not yet studied for fresh,...journal article 2022
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Gonugunta, P. (author), Dugulan, A.I. (author), Bezemer, G. Leendert (author), Brück, E.H. (author)Operando spectroscopic techniques (Diffusive Reflective Infrared Fourier-Transform and Mössbauer emission spectroscopy) were combined to investigate the role of oxygenates deposition on deactivation of cobalt on titania Fischer-Tropsch catalysts at high pressure. Clear formation of carboxylates was seen for catalysts prepared via both...journal article 2021
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Ariëns, M.I. (author), Chlan, V. (author), Novák, P. (author), van de Water, L. G.A. (author), Dugulan, A.I. (author), Brück, E.H. (author), Hensen, E. J.M. (author)Chromium promotion of iron oxide based water-gas shift (WGS) catalysts prepared via co-precipitation/calcination was investigated. Mössbauer spectroscopy and XRD evidence that chromium is incorporated in the calcined hematite (α-Fe<sub>2</sub>O<sub>3</sub>) precursor irrespective of the doping level (0−12 wt.%). CO-TPR shows chromium delays...journal article 2021
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Lai, J. (author), You, X. (author), Dugulan, A.I. (author), Huang, B. (author), Liu, J. (author), Maschek, M. (author), van Eijck, L. (author), van Dijk, N.H. (author), Brück, E.H. (author)The first-order magneto-elastic transition in the Mn–Fe–P–Si alloys can be tailored by vanadium substitution. Alloys with a suitable V substitution provide an excellent magnetocaloric effect with minor hysteresis in low magnetic fields up to 1.2 T. Mössbauer measurements show that the hyperfine field is reduced by V substitution. Neutron...journal article 2020
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Prot, T.J.F. (author), Wijdeveld, W. (author), Eshun, L. Ekua (author), Dugulan, A.I. (author), Goubitz, K. (author), Korving, L. (author), van Loosdrecht, Mark C.M. (author)The recovery of phosphorus from secondary sources like sewage sludge is essential in a world suffering from resources depletion. Recent studies have demonstrated that phosphorus can be magnetically recovered as vivianite (Fe(II)<sub>3</sub>(PO<sub>4</sub>)<sub>2</sub>∗8H<sub>2</sub>O) from the digested sludge (DS) of Waste Water Treatment...journal article 2020
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Prot, T.J.F. (author), Nguyen, V. H. (author), Wilfert, P.K. (author), Dugulan, A.I. (author), Goubitz, K. (author), de Ridder, D.J. (author), Korving, L. (author), Rem, P.C. (author), Bouderbala, A. (author), Witkamp, G.J. (author), van Loosdrecht, Mark C.M. (author)To prevent eutrophication of surface water, phosphate needs to be removed from sewage. Iron (Fe) dosing is commonly used to achieve this goal either as the main strategy or in support of biological removal. Vivianite (Fe(II) <sub>3</sub> (PO <sub>4</sub> ) <sub>2</sub> * 8H <sub>2</sub> O) plays a crucial role in capturing the phosphate, and...journal article 2019
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Darwiche, Ali (author), Fehse, M. (author), Mahmoud, Abdelfattah (author), La Fontaine, Camille (author), Fraisse, Bernard (author), Hermann, Raphael P. (author), Doublet, Marie Liesse (author), Monconduit, Laure (author), Sougrati, Moulay T. (author)In this study, we want to highlight the assets and restrictions of X-ray absorption spectroscopy (XAS) and Mössbauer spectroscopy for investigating the mechanism of the electrochemical reaction of antimony electrode materials vs. Na. For this, operando XAS was carried out during the first one and a half cycles, and the whole set of measured...journal article 2018
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Wilfert, P.K. (author), Mandalidis, A. (author), Dugulan, A.I. (author), Goubitz, K. (author), Korving, L. (author), Temmink, H. (author), Witkamp, G.J. (author), van Loosdrecht, Mark C.M. (author)Iron is an important element for modern sewage treatment, inter alia to remove phosphorus from sewage. However, phosphorus recovery from iron phosphorus containing sewage sludge, without incineration, is not yet economical. We believe, increasing the knowledge about iron-phosphorus speciation in sewage sludge can help to identify new routes...journal article 2016
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Miao, X.F. (author)Mn-Fe-P-Si compounds are, to date, the most promising materials for refrigeration and energy conversion applications due to the combination of giant magnetocaloric effect (GMCE) and low material cost. The nature of magneto-elastic transition was studied on both length- and time-scales using neutron diffraction, muSR and Mӧssbauer spectroscopy...doctoral thesis 2016
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Smith, A.L. (author), Hen, Amir (author), Magnani, Nicola (author), Sanchez, Jean Pierre (author), Colineau, Eric (author), Griveau, Jean Christophe (author), Raison, Philippe E. (author), Caciuffo, Roberto (author), Konings, R. (author), Cheetham, Anthony K. (author)The physical and chemical properties at low temperatures of hexavalent disodium neptunate α-Na<sub>2</sub>NpO<sub>4</sub> are investigated for the first time in this work using Mössbauer spectroscopy, magnetization, magnetic susceptibility, and heat capacity measurements. The Np(VI) valence state is confirmed by the isomer shift value of the...journal article 2016
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Honarmand Ebrahimi, K. (author)Storage of Fe(III) is a common mechanism by which the cellular machinery controls the availability of Fe(II) and Fe(III) for biosynthesis of iron-containing cofactors of enzymes which are involved in several essential biological processes, including oxidative phosphorylation. The conserved 24-meric iron-storage protein ferritin has been...doctoral thesis 2013
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Taboada, J.B. (author)Steam-treated isomorphously substituted [Fe,Al]MFI zeolite is known to exhibit superior catalytic performance in the direct oxidation of benzene to phenol, using N2O as oxidant (BTOP). However, despite extensive efforts, the nature of the active sites in the [Fe,Al]MFI catalyst for the BTOP reaction is still largely unknown. However, recent...doctoral thesis 2006
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- Mulders, A.M. (author) doctoral thesis 1998
Searched for: subject%3A%22M%25C3%25B6ssbauer%255C%2Bspectroscopy%22
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