Metal containing nanoclusters in zeolites

The molecular-sized void space of the zeolitic micropores is perfect matrices to encapsulate and stabilize multicomponent and multifunctional complexes that can be used as active sites for a wide range of important catalytic transformations. In this article, we discuss and analyze the key developments of the last decade in the catalytic...

In-Site Phenotype of the Settlement Space along China’s Grand Canal Tianjin Section: GIS-sDNA-Based Model Analysis

The settlement space along China’s Grand Canal composes an important part of the Canal heritage, has a close bearing on the production and life of the residents there, nourishes rich culture and wisdom and boasts vital value of conservation and inheritance. Due to China’s rapid urbanization and industrialization, the settlements along the...

Structure-activity relationships in metal organic framework derived mesoporous nitrogen-doped carbon containing atomically dispersed iron sites for CO₂ electrochemical reduction

Mesoporous nitrogen-doped carbon nanoparticles with atomically dispersed iron sites (named mesoNC-Fe) are synthesized via high-temperature pyrolysis of an Fe containing ZIF-8 MOF. Hydrolysis of tetramethyl orthosilicate (TMOS) in the MOF framework prior to pyrolysis plays an essential role in maintaining a high surface area during the...

The Nature and Catalytic Function of Cation Sites in Zeolites: a Computational Perspective

Zeolites have a broad spectrum of applications as robust microporous catalysts for various chemical transformations. The reactivity of zeolite catalysts can be tailored by introducing heteroatoms either into the framework or at the extraframework positions that gives rise to the formation of versatile Brønsted acid, Lewis acid and redox...

Probabilistic Characterization of a Soft Scandinavian Clay Supporting a Light Quay Structure

A full geotechnical risk analysis includes site investigation, model simplification and analysis. The site characterization forms the basis for the choice of the soil parameters used in the subsequent analysis, but the soil data is normally analyzed with crude methods that do not include the effect of the soil variability. A case study is here...