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Inamdar, A.S. (author), van Soestbergen, Michiel (author), Mavinkurve, Amar (author), van Driel, W.D. (author), Zhang, Kouchi (author)Moulding compounds used for encapsulating electronics typically occupy a large portion of package volume and are most exposed to the external environment. Under harsh conditions such as high temperature, humidity, and mechanical vibrations, constituent materials of electronic components degrade, resulting in a change in their thermal, mechanical...conference paper 2023
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Zhao, Guofeng (author), Moulijn, J.A. (author), Kapteijn, F. (author), Dautzenberg, Frits M. (author), Xu, Bin (author), Lu, Yong (author)Heterogeneous catalysis plays a pivotal role in the current chemical and energy vectors production. Notably, to fully utilize the intrinsic activity and selectivity of a catalyst, the chemical reactor has to be designed and operated optimally to achieve enhanced heat/mass transfer, well-defined contact time of reactants, uniform flow pattern,...journal article 2023
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Piergentili, I. (author), Cai, Mao (author), Klemm, B. (author), Xu, B. (author), Luo, Sanzhong (author), Eelkema, R. (author)The redox balance in tumor and diseased cells often leads to the production of reactive oxygen species (ROS). Many ROS-responsive materials based on sulfur oxidation have been reported with the goal of achieving controlled delivery at the tumor. However, these materials often lack responsiveness to low ROS concentrations present in the tumor...journal article 2023
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Inamdar, A.S. (author), Gromala, Przemyslaw Jakub (author), Prisacaru, Alexandru (author), Kabakchiev, Alexander (author), Yang, Yu Hsiang (author), Han, Bongtae (author)Epoxy molding compound (EMC) is widely used for encapsulating automotive electronics. Among all of the components of an electronic package, EMC is most exposed to the atmosphere, and thus undergoes aging. During high-temperature operation, EMC is oxidized, which alters its mechanical properties, and thus can affect the reliability of electronic...book chapter 2022
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Roodenburg, Koos (author)The development in solar cells began with wafer based cells, also called the first generation photovoltaic technology. Most of these wafer based cells were made of crystalline silicon. As a crystalline silicon cell must be relatively thick to absorb most of the incoming energy, the second generation (thin film solar cells) was introduced. In the...master thesis 2021
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Geertzen, Sander Geertzen (author)Drought and subsidence are two out of several water-related urban climate adaptation challenges many cities in the Netherlands currently face. Drought is expected to increase in frequency and extent due to climate change. Therefore, drought is likely to further pressurize (subsiding) urban areas in the coming decades. Although the impact of...master thesis 2021
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Biocatalytic Aromaticity-Breaking Epoxidation of Naphthalene and Nucleophilic Ring-Opening ReactionsZhang, W. (author), Li, Huanhuan (author), Younes, S.H.H. (author), Gómez De Santos, Patricia (author), Tieves, F. (author), Grogan, Gideon (author), Pabst, Martin (author), Alcalde, Miguel (author), Whitwood, Adrian C. (author), Hollmann, F. (author)Aromatic hydroxylation reactions catalyzed by heme-thiolate enzymes proceed via an epoxide intermediate. These aromatic epoxides could be valuable building blocks for organic synthesis giving access to a range of chiral trans-disubstituted cyclohexadiene synthons. Here, we show that naphthalene epoxides generated by fungal peroxygenases can...journal article 2021
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Mahor, Durga (author), Cong, Zhiqi (author), Weissenborn, Martin J. (author), Hollmann, F. (author), Zhang, Wuyuan (author)The oxidation of alkanes into valuable chemical products is a vital reaction in organic synthesis. This reaction, however, is challenging, owing to the inertness of C−H bonds. Transition metal catalysts for C−H functionalization are frequently explored. Despite chemical alternatives, nature has also evolved powerful oxidative enzymes (e. g.,...review 2021
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de Vrijer, T. (author), Ravichandran, Ashwath (author), Bouazzata, Bilal (author), Smets, A.H.M. (author)Low-cost multijunction photovoltaic devices are the next step in the solar energy revolution. Adding a bottom junction with a low bandgap energy material through plasma enhanced chemical vapor deposition (PECVD) processing could potentially provide a low-cost boost in conversion efficiency. A logical candidate for this low bandgap material is...journal article 2021
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Ampurdanés, Jordi (author), Bunea, S. (author), Urakawa, A. (author)Electrolysis-assisted nitrate (NO<sub>3</sub><sup>−</sup>) reduction is a promising approach for its conversion to harmless N<sub>2</sub> from waste, ground, and drinking water due to the possible process simplicity by in-situ generation of H<sub>2</sub>/H/H<sup>+</sup> by water electrolysis and to the flexibility given by tunable redox...journal article 2020
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Yoon, Jaeho (author), Kim, Jinhyun (author), Tieves, F. (author), Zhang, W. (author), Alcalde, Miguel (author), Hollmann, F. (author), Park, Chan Beum (author)Peroxygenases have long inspired the selective oxyfunctionalization of various aliphatic and aromatic compounds, because of their broad substrate spectrum and simplicity of catalytic mechanism. This study provides a proof-of-concept of piezobiocatalysis by demonstrating peroxygenase-catalyzed oxyfunctionalization reactions fueled by...journal article 2020
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Zain, N.H.M. (author)Organic soils and peat soils are widely distributed across the world, particularly in the Northern hemisphere in countries like Canada and Russia having 170 and 150 million hectares respectively and in tropical regions such as Indonesia and Malaysia, which contain 26 million and 3 million hectares respectively. Organic soils and peat are...doctoral thesis 2019
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Chen, Ying (author), Zhang, Xun (author), van der Zwaag, S. (author), Sloof, W.G. (author), Xiao, Ping (author)A self‐healing thermal barrier coating (TBC) system is manufactured by air plasma spraying (APS) and tested by thermal cycling. The ceramic topcoat in the self‐healing APS TBC system consists of an yttria stabilised zirconia (YSZ) matrix and contains self‐shielding aluminium containing MoSi2 healing particles dispersed close to the topcoat/bond...journal article 2019
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Tieves, F. (author), Willot, S.J. (author), van Schie, M.M.C.H. (author), Rauch, M.C.R. (author), Younes, S.H.H. (author), Zhang, W. (author), Dong, J. (author), Gomez de Santos, P. (author), Hollmann, F. (author)An increasing number of biocatalytic oxidation reactions rely on H <sub>2</sub> O <sub>2</sub> as a clean oxidant. The poor robustness of most enzymes towards H <sub>2</sub> O <sub>2</sub> , however, necessitates more efficient systems for in situ H <sub>2</sub> O <sub>2</sub> generation. In analogy to the well-known formate dehydrogenase to...journal article 2019
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van Schie, M.M.C.H. (author), Zhang, W. (author), Tieves, F. (author), Choi, Da Som (author), Park, Chan Beum (author), Burek, Bastien O. (author), Bloh, Jonathan Z. (author), Arends, I.W.C.E. (author), Paul, C.E. (author), Alcalde, Miguel (author), Hollmann, F. (author)Peroxygenases are very interesting catalysts for specific oxyfunctionalization chemistry. Instead of relying on complicated electron transport chains, they rely on simple hydrogen peroxide as the stoichiometric oxidant. Their poor robustness against H<sub>2</sub>O<sub>2</sub> can be addressed via in situ generation of H<sub>2</sub>O<sub>2<...journal article 2019
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Dong, J. (author), Fernandez Fueyo, E. (author), Hollmann, F. (author), Paul, C.E. (author), Pesic, M. (author), Schmidt, S. (author), Wang, Yonghua (author), Younes, S.H.H. (author), Zhang, W. (author)Oxidation chemistry using enzymes is approaching maturity and practical applicability in organic synthesis. Oxidoreductases (enzymes catalysing redox reactions) enable chemists to perform highly selective and efficient transformations ranging from simple alcohol oxidations to stereoselective halogenations of non‐activated C−H bonds. For many of...journal article 2018
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Zhang, W. (author), Gacs, Jenő (author), Arends, I.W.C.E. (author), Hollmann, F. (author)The aerobic organocatalytic oxidation of alcohols was achieved by using water-soluble sodium anthraquinone sulfonate. Under visible-light activation, this catalyst mediated the aerobic oxidation of alcohols to aldehydes and ketones. The photo-oxyfunctionalization of alkanes was also possible under these conditions.journal article 2017
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Stikkelman, J. (author)MAX-phase materials, a class of ternary carbides and nitrides that combine favorable properties of metals (conductivity and toughness) and ceramics (high temperature strength) have been shown to autonomously heal micro-cracks by high temperature oxidation. The investigation of Ta and Al containing MAX phases (Ta2AlC & Ta4AlC3) could render self...master thesis 2016
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Fernandez Fueyo, E. (author), Younes, S.H.H. (author), Van Rootselaar, Stefan (author), Aben, René W M (author), Renirie, R. (author), Wever, Ron (author), Holtmann, Dirk (author), Rutjes, Floris P J T (author), Hollmann, F. (author)A catalytic, enzyme-initiated (aza-) Achmatowicz reaction is presented. The involvement of a robust vanadium-dependent peroxidase from Curvularia inaequalis allows the simple use of H<sub>2</sub>O<sub>2</sub> and catalytic amounts of bromide.journal article 2016
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Skupien, E. (author), Berger, R.J. (author), Santos, V.P. (author), Gascon, J. (author), Makkee, M. (author), Kreutzer, M.T. (author), Kooyman, P.J. (author), Moulijn, J.A. (author), Kapteijn, F. (author)Benzyl alcohol oxidation was carried out in toluene as solvent, in the presence of the potentially inhibiting oxidation products benzaldehyde and benzoic acid. Benzoic acid, or a product of benzoic acid, is identified to be the inhibiting species. The presence of a basic potassium salt (K2CO3 or KF) suppresses this inhibition, but promotes the...journal article 2014