The use of green H2 and sustainable carburization to Fe3C for the direct reduction of iron ore pellets

Steel manufacturing is a carbon intensive process, that is responsible for approximately 7% of the total global CO2 emissions. Therefore, TATA Steel IJmuiden aims to lower its carbon emissions. One way to bring down emissions, is to replace the existing blast furnace (BF) CO reduction process with the H2-based direct reduction of iron ore (DRI)....

Microstructures in a carburized steel after isothermal pearlitic treatment

The influence of carbon concentration variations on pearlite formation (20 h at 600 °C) in a case-carburized steel is investigated. The resultant microstructure shows three distinct regions: carburized case, a transition region, and the original core. The microstructural transition from the case to the core regions is observed to be...

Isotopic Exchange Study on the Kinetics of Fe Carburization and the Mechanism of the Fischer-Tropsch Reaction

The kinetics of the transformation of metallic Fe to the active Fe carbide phase at the start of the Fischer-Tropsch (FT) reaction were studied. The diffusion rates of C atoms going in or out of the lattice were determined using 13C-labeled synthesis gas in combination with measurements of the transient 12C and 13C contents in the carbide by...

Influence of chemical segregation on bainitic microstructures in a carburized bearing steel

Bainite to austenite reversal is one of the grain refinement techniques employed in carburized steels. However, chemical segregation influences the homogeneity of the bainitic structure, which is seminal to exploit the advantages associated with austenite reversal. It is therefore important to understand the influence of chemical segregation...

The role of H₂ in Fe carburization by CO in Fischer-Tropsch catalysts

The formation of Fe-carbide phases is relevant to the synthesis of Fischer-Tropsch synthesis catalysts. We investigated the carburization of Raney Fe as a model catalyst using spectroscopic and temperature-programmed techniques. IR spectroscopy shows that CO dissociation already occurs at −150 °C, while C diffusion into metallic Fe requires...

Investigating the material characteristics and fatigue life of 18CrNiMo7-6 carburized steel pinions affected with grinding-induced burns

Carburized steel grades are widely used in applications where high hardness at the surface is required in combination with good core toughness as well as high fatigue resistance. The process of carburizing lower to medium carbon steel can generally provide this combination of properties and has been practised for several decades. Such steel is...

Gear Repair using Laser Metal Deposition

The urge for more sustainable and cost-efficient repair methods for damaged parts is growing every day. On the other hand, laser metal deposition (LMD) is gaining momentum. This flexible technique, where material is added in a layer-by-layer fashion with a minimal heat input offers solutions for a wide range of production and repair purposes....

High-temperature Fischer-Tropsch synthesis over FeTi mixed oxide model catalysts: Tailoring activity and stability by varying the Ti/Fe ratio

tA series of Fe-Ti mixed oxide model catalysts containing different Ti/Fe ratios were synthesized andapplied as catalysts for the High Temperature Fischer-Tropsch reaction (HTFTS). XRD, H2-TPR and in situMössbauer and XAFS spectroscopy were applied to evaluate the role of Ti on the physical and chemicalproperties of Fe within the mixed metal...