Searched for: subject%3A%22covalent%255C+triazine%255C+framework%22
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Corral-Pérez, Juan José (author), Billings, Amelia (author), Stoian, Dragos (author), Urakawa, A. (author)
Continuous synthesis of formic acid and methyl formate via CO<sub>2</sub> hydrogenation is demonstrated using a molecular iridium complex stably immobilized on a solid covalent triazine framework (CTF) under high-pressure conditions. Compared to formic acid synthesis, methyl formate synthesis is advantageous to enhance the selectivity and...
journal article 2019
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Bavykina, A.V. (author), Olivos Suarez, A.I. (author), Osadchii, D. (author), Valecha, R.R. (author), Franz, R.P.M. (author), Makkee, M. (author), Kapteijn, F. (author), Gascon, Jorge (author)
A quasi chemical vapor deposition method for the manufacture of well-defined covalent triazine framework (CTF) coatings on cordierite monoliths is reported. The resulting supported porous organic polymer is an excellent support for the immobilization of two different homogeneous catalysts: (1) an Ir<sup>III</sup>Cp∗-based catalyst for the...
journal article 2017
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Bavykina, A.V. (author), Rozhko, E. (author), Goesten, M.G. (author), Wezendonk, T.A. (author), Seoane, Beatriz (author), Kapteijn, F. (author), Makkee, M. (author), Gascon, Jorge (author)
A facile one-step method to shape covalent triazine frameworks (CTFs) for catalytic applications is reported. Phase inversion of the CTF powder by using a polyimide as a binder in a microfluidic device results in the formation of composite spheres with accessible CTF porosity and a high mechanical and thermal stability. The fabricated spheres...
journal article 2016