Effect of polymer architecture on the intrinsic self-healing character of polymers

Intrinsic and extrinsic self-healing strategies can be employed to mitigate the effects of local damage in order to (partially) restore a lost property or functionality and to avoid premature catastrophic failure of the whole system. It is well known that polymer architecture has a crucial influence on mechanical, physical and thermal properties...

Understanding the molecular mechanisms involved in the interfacial self-healing of supramolecular rubbers

Supramolecular rubbers based on 2-aminoethylimidazolidone and fatty acids with epoxy crosslinks have been shown to self-heal via multiple hydrogen bonding sites. In this work, several tools are used to investigate the molecular mechanisms taking place at the interface to understand cohesive healing in these polymers. The quantification of self...

The role of clusters on the healing efficiency of a modified Zn based ionomer

Poly(ethylene-co-methacrylic acid) (EMAA) ionomers have shown healing capabilities in both ballistic and static tests. In previous studies it was shown that the degree of crosslinking (clusters) affects (positively or negatively) the healing under impact tests. Moreover, it has also been reported that the modification of the ionomers by...

The role of clusters on the healing efficiency of a modified Zn based ionomer

Poly(ethylene-co-methacrylic acid) (EMAA) ionomers have shown healing capabilities in both ballistic and static tests. In previous studies it was shown that the degree of crosslinking (clusters) affects (positively or negatively) the healing under impact tests. Moreover, it has also been reported that the modification of the ionomers by...

A study of the temperature dependent healing capabilities of new polymers based on Diels-Alder cycloaddition

Because of its thermal reversibility, the retro-Diels-Alder (RDA) reaction represents an appealing possibility to produce self-healing polymers with well-defined architectures and tunable properties [1]. However, the polymer architecture for which the Diels-Alder (DA) reaction can best be used to contribute to the healing process is still not...

Compartemented fibres: The concept of multiple self-healing in advanced fibre composites

Polymers reinforced with high performance fibres are successfully replacing metal alloys in lightweight aircraft structures. A critical factor in structural design is the resistance of a structure to progressive damage which develops during its service time. The brittle nature of matrix cracking is the main source of composite failure initiating...

A study of the temperature dependent healing capabilities of new polymers based on Diels-Adler cycloaddition

Because of its thermal reversibility, the retro-Diels-Alder (RDA) reaction represents an appealing possibility to produce self-healing polymers with well-defined architectures and tunable properties [1]. However, the polymer architecture for which the Diels-Alder (DA) reaction can best be used to contribute to the healing process is still not...

Self-healing metallopolymers: Detailed investigation of the self-healing properties by scratch testing

In the last decade several intrinsic self-healing materials have been developed in which the healing mechanism was mainly based on the reversibility of a certain structural element. For this purpose, reversible covalent bonds, e.g., based on the Diels-Alder reaction or weaker non-covalent interactions, e.g., hydrogen bonding, ionic interactions...

On the healing mechanism of sol-gel derived hybrid materials containing dynamic di-sulfide bonds

Sol-gel technology is increasingly being used in coatings for corrosion protection and adhesion improvement. So far, the self-healing concept in sol-gel coatings has only been approached from extrinsic healing perspective (i.e. use of nano and micro carriers of corrosion inhibitors) [1]. Despite the benefits of this approach, the damaged area...

Compartemented fibres: The concept of multiple self-healing in advanced fibre composites

Polymers reinforced with high performance fibres are successfully replacing metal alloys in lightweight aircraft structures. A critical factor in structural design is the resistance of a structure to progressive damage which develops during its service time. The brittle nature of matrix cracking is the main source of composite failure initiating...

On the healing mechanism of sol-gel derived hybrid materials containing dynamic di-sulfide bonds

Sol-gel technology is increasingly being used in coatings for corrosion protection and adhesion improvement. So far, the self-healing concept in sol-gel coatings has only been approached from extrinsic healing perspective (i.e. use of nano and micro carriers of corrosion inhibitors) [1]. Despite the benefits of this approach, the damaged area...

Understanding the molecular mechanisms involved in the interfacial self-healing of supramolecular rubbers

Supramolecular rubbers based on 2-aminoethylimidazolidone and fatty acids with epoxy crosslinks have been shown to self-heal via multiple hydrogen bonding sites. In this work, several tools are used to investigate the molecular mechanisms taking place at the interface to understand cohesive healing in these polymers. The quantification of self...

Model based tuning of the release of self healing agents from organic coatings: From Fickian to controlled release kinetics (abstract)

A mechanical model for the self healing response of coatings based on expansive phases (abstract)

Electrochemical healing of MAX phase ceramics (abstract)

A quantitative description of the surface healing of ionomers (abstract)