Desulfurization of High-Sulfur HIsarna Hot Metal

The HIsarna process is one of the emerging low-CO₂ ironmaking processes that could help the steel industry in achieving their carbon footprint goals. HIsarna hot metal contains 3–4 times more sulfur than hot metal from blast furnaces (BFs). Therefore, a literature study, a thermodynamic analysis, and plant data analysis from Tata...

Effect of graphite on hot metal desulphurisation

During the magnesium-lime co-injection process for hot metal desulphurisation, graphite can precipitate as a result of carbon oversaturation. The formed graphite is known to form a layer between the slag and the hot metal. This potentially blocks the sulphides, that are formed during the desulphurisation process, to reach the slag phase thus...

The hampering effect of precipitated carbon on hot metal desulfurization with magnesium

Carbon may precipitate during the hot metal desulfurization (HMD) process as a result of carbon oversaturation because of temperature decrease. The precipitated carbon flakes form a layer between hot metal and slag. It is postulated that this carbon layer hampers desulfurization with magnesium by preventing MgS particles from reaching the...

Effect of KAlF4 on the efficiency of hot metal desulphurisation with magnesium

At the hot metal desulphurisation (HMD) stations of Tata Steel’s BOS plant in Port Talbot (UK), KAlF4 is injected together with magnesium in order to increase the fluidity of the slag and thus to decrease the iron loss. Although KAlF4 is successfully contributing to a lower iron loss during HMD, it also has a negative effect on the...