Advanced biofuels from thermochemical liquefaction, such as pyrolysis (PY) and Hydrothermal liquefaction (HTL), of olive residues in the Andalusian region of Spain (specifically in the province of Jaen) can potentially play a crucial role in the reduction of greenhouse gas (GHG) emissions in the maritime sector. In this study, an attributional life-cycle assessment (ALCA) was performed to estimate and compare the GHG emissions for producing marine biofuels via pyrolysis and HTL from olive pomace (COP) and pruning biomass (OTPB), to provide 1 megajoule (MJ) of marine biofuel, as a functional unit. For convenience, the different technology-feedstock combination scenarios are represented as scenario 1 (PY_COP), scenario 2 (PY_OTPB), scenario 3 (HTL_COP), and scenario 4 (HTL_OTPB). The life-cycle GHG emissions of the biofuels were 42.0, 44.1, 22.1, and 32.1 g CO₂-eq/MJ for PY_COP, PY_OTPB, HTL_COP and HTL_OTPB scenarios, respectively, corresponding to 47–73% GHG emissions reduction compared with petroleum fuels. The scenarios were also evaluated based on other impact categories such as Sulphur dioxide in the air, Nitrogen oxides in the air, Particulates in the air, and Non-methane volatile organic compounds (NMVOCs) in the air. The scenarios reduced the SO₂ emissions, Nitrogen emissions, NVMOCs, and particulates in the air by at least 50%, 90%, 20%, and 25% respectively in comparison to fossil fuels. A contribution analysis revealed that olive cultivation and upgrading as hot spots for emission in pyrolysis-based systems. Likewise, HTL conversion and upgrading steps were emitting more emissions for an HTL-based system. Therefore, marine biofuel obtained through the thermochemical conversion of olive residues has better environmental performance on a life cycle basis, with a preference for HTL based system over pyrolysis.