The Tropospheric Monitoring Instrument (TROPOMI), aboard the Sentinel-5 Precursor (S5P) satellite, launched on 13 October 2017, provides measurements of atmospheric trace gases and of cloud and aerosol properties at an unprecedented spatial resolution of approximately 7 × 3:5 km² (approx. 5:5 × 3:5 km² as of 6 August 2019), achieving near-global coverage in 1 d. The retrieval of nitrogen dioxide (NO₂) concentrations is a three-step procedure: slant column density (SCD) retrieval, separation of the SCD in its stratospheric and tropospheric components, and conversion of these into vertical column densities. This study focusses on the TROPOMI NO₂ SCD retrieval: the retrieval method used, the stability of the SCDs and the SCD uncertainties, and a comparison with the Ozone Monitoring Instrument (OMI) NO₂ SCDs. The statistical uncertainty, based on the spatial variability of the SCDs over a remote Pacific Ocean sector, is 8.63 μmol m^-2 for all pixels (9.45 μmol m^-2 for clear-sky pixels), which is very stable over time and some 30 % less than the long-term average over OMI-QA4ECV data (since the pixel size reduction TROPOMI uncertainties are ~ 8 % larger). The SCD uncertainty reported by the differential optical absorption spectroscopy (DOAS) fit is about 10 % larger than the statistical uncertainty, while for OMI-QA4ECV the DOAS uncertainty is some 20 % larger than its statistical uncertainty. Comparison of the SCDs themselves over the Pacific Ocean, averaged over 1 month, shows that TROPOMI is about 5 % higher than OMI-QA4ECV, which seems to be due mainly to the use of the so-called intensity offset correction in OMI-QA4ECV but not in TROPOMI: turning that correction off means about 5 % higher SCDs. The row-torow variation in the SCDs of TROPOMI, the "stripe amplitude", is 2.15 μmol m, while for OMI-QA4ECV it is a factor of ~ 2 (~ 5) larger in 2005 (2018); still, a so-called stripe correction of this non-physical across-track variation is useful for TROPOMI data. In short, TROPOMI shows a superior performance compared with OMI-QA4ECV and operates as anticipated from instrument specifications. The TROPOMI data used in this study cover 30 April 2018 up to 31 January 2020.

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Societal dependence on, and commercial and scientific exploitation of Earth-Oriented remote sensing from satellites is growing at an exponential rate. The comprehensive EU Copernicus programme provides a major contribution to the global effort, but even so, to achieve the necessary global and temporal coverage requires synergistic cooperation and associated interoperability of the Worlds sensors. For a user to exploit Earth Observation (EO) data there must exist confidence in data characteristics, quality and reliable delivery. Although long-term data records for climate may be the most demanding in nature, generation of analysis-ready operational data sets for applications, as diverse as food security to pollution monitoring, all require the user to have some quantitative level of confidence in the data and derived information. A long-term Calibration/Validation (Cal/Val) vision necessitates clear ownership and long-term funding. Delineating the roles of the European Commission (EC), space agencies and member states in long-term Cal/Val would provide clarity. It is clear that the space agencies have the responsibility to meet the mission requirement of their spaceborne instruments but long-term validation is often entrusted to interested parties bringing their own resources to the task. Furthermore, there is a critical need for Fiducial Reference Measurements (FRMs), acquired in operational mode, and comprehensive in coverage both spatially and temporally, to assure that the satellite product accuracies are met. This paper discusses the current status, gaps and challenges regarding long-term Cal/Val of EO satellites and recommends the creation of a European coordinating entity for satellite product calibration and validation. The proposed entity would be an integrative organization coordinating the European Cal/Val activities in partnership with the member states and the space agencies and working together with existing data providers to secure access to satellite and in-situ data of traceable FRM standards.

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TROPOspheric Monitoring Instrument (TROPOMI), on-board the Sentinel-5 Precurser satellite, is a nadir-viewing spectrometer measuring reflected sunlight in the ultraviolet, visible, near-infrared, and shortwave infrared. From these spectra several important air quality and climate-related atmospheric constituents are retrieved, including nitrogen dioxide (NO2) at unprecedented spatial resolution from a satellite platform. We present the first retrievals of TROPOMI NO2 over the Canadian Oil Sands, contrasting them with observations from the Ozone Monitoring Instrument satellite instrument, and demonstrate TROPOMI's ability to resolve individual plumes and highlight its potential for deriving emissions from individual mining facilities. Further, the first TROPOMI NO2 validation is presented, consisting of aircraft and surface in situ NO2 observations, and ground-based remote-sensing measurements between March and May 2018. Our comparisons show that the TROPOMI NO2 vertical column densities are highly correlated with the aircraft and surface in situ NO2 observations, and the ground-based remote-sensing measurements with a low bias (15–30 %); this bias can be reduced by improved air mass factors.@en

Satellite retrieval of vertical column densities (VCDs) of tropospheric nitrogen dioxide (NO₂) is critical for NO_x pollution and impact evaluation. For regions with high aerosol loadings, the retrieval accuracy is greatly affected by whether aerosol optical effects are treated implicitly (as additional effective clouds) or explicitly, among other factors. Our previous POMINO algorithm explicitly accounts for aerosol effects to improve the retrieval, especially in polluted situations over China, by using aerosol information from GEOS-Chem simulations with further monthly constraints by MODIS/Aqua aerosol optical depth (AOD) data. Here we present a major algorithm update, POMINO v1.1, by constructing a monthly climatological dataset of aerosol extinction profiles, based on level 2 CALIOP/CALIPSO data over 2007-2015, to better constrain the modeled aerosol vertical profiles. We find that GEOS-Chem captures the month-to-month variation in CALIOP aerosol layer height (ALH) but with a systematic underestimate by about 300-600 m (season and location dependent), due to a too strong negative vertical gradient of extinction above 1 km. Correcting the model aerosol extinction profiles results in small changes in retrieved cloud fraction, increases in cloud-top pressure (within 2 %-6 % in most cases), and increases in tropospheric NO₂ VCD by 4 %-16 % over China on a monthly basis in 2012. The improved NO₂ VCDs (in POMINO v1.1) are more consistent with independent ground-based MAX-DOAS observations (R²=0.80, NMB =-3.4 %, for 162 pixels in 49 days) than POMINO (R²=0.80, NMB =-9.6 %), DOMINO v2 (R²=0.68, NMB =-2.1 %), and QA4ECV (R²=0.75, NMB =-22.0 %) are. Especially on haze days, R² reaches 0.76 for POMINO v1.1, much higher than that for POMINO (0.68), DOMINO v2 (0.38), and QA4ECV (0.34). Furthermore, the increase in cloud pressure likely reveals a more realistic vertical relationship between cloud and aerosol layers, with aerosols situated above the clouds in certain months span id=page2 instead of always below the clouds. The POMINO v1.1 algorithm is a core step towards our next public release of the data product (POMINO v2), and it will also be applied to the recently launched S5P-TROPOMI sensor.

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This overview paper highlights the successes of the Ozone Monitoring Instrument (OMI) on board the Aura satellite spanning a period of nearly 14 years. Data from OMI has been used in a wide range of applications and research resulting in many new findings. Due to its unprecedented spatial resolution, in combination with daily global coverage, OMI plays a unique role in measuring trace gases important for the ozone layer, air quality, and climate change. With the operational very fast delivery (VFD; direct readout) and near real-time (NRT) availability of the data, OMI also plays an important role in the development of operational services in the atmospheric chemistry domain.

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The Ozone Monitoring Instrument (OMI) onboard NASA's Aura satellite has been providing global observations of the ozone layer and key atmospheric pollutant gases, such as nitrogen dioxide (NO2) and sulfur dioxide (SO2), since October 2004. The data products from the same instrument provide consistent spatial and temporal coverage and permit the study of anthropogenic and natural emissions on local-to-global scales. In this paper, we examine changes in SO2 and NO2 over some of the world's most polluted industrialized regions during the first decade of OMI observations. In terms of regional pollution changes, we see both upward and downward trends, sometimes in opposite directions for NO2 and SO2, for different study areas. The trends are, for the most part, associated with economic and/or technological changes in energy use, as well as regional regulatory policies. Over the eastern US, both NO2 and SO2 levels decreased dramatically from 2005 to 2015, by more than 40 and 80ĝ€%, respectively, as a result of both technological improvements and stricter regulations of emissions. OMI confirmed large reductions in SO2 over eastern Europe's largest coal-fired power plants after installation of flue gas desulfurization devices. The North China Plain has the world's most severe SO2 pollution, but a decreasing trend has been observed since 2011, with about a 50ĝ€% reduction in 2012–2015, due to an economic slowdown and government efforts to restrain emissions from the power and industrial sectors. In contrast, India's SO2 and NO2 levels from coal power plants and smelters are growing at a fast pace, increasing by more than 100 and 50ĝ€%, respectively, from 2005 to 2015. Several SO2 hot spots observed over the Persian Gulf are probably related to oil and gas operations and indicate a possible underestimation of emissions from these sources in bottom-up emission inventories. Overall, OMI observations have proved valuable in documenting rapid changes in air quality over different parts of the world during last decade. The baseline established during the first 11 years of OMI is indispensable for the interpretation of air quality measurements from current and future satellite atmospheric composition missions.

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Land use regression (LUR) modelling has increasingly been applied to model fine scale spatial variation of outdoor air pollutants including nitrogen dioxide (NO₂). Satellite observations of tropospheric NO₂ improved LUR model in very large study areas, including Canada, United States and Australia. The aim of our study was to assess the value of satellite observations of NO₂ in modelling the spatial variation of annual average NO₂ concentrations in a small densely populated country. We used surface level annual average NO₂ concentration and geographic information system data from 144 monitoring sites spread over the Netherlands: 26 regional background, 78 urban background and 40 traffic sites for developing land use regression models. For the 144 monitoring sites we obtained the annual average tropospheric NO₂ concentration for 2007 from the Ozone Monitoring Instrument (OMI) satellite sensor. These OMI data reflect a spatial scale of about 10×10km. We calculated the correlation between satellite and surface level NO₂ concentrations for all sites and for background sites only. We next evaluated whether adding satellite observations improved land use regression models.Annual average satellite observations of tropospheric NO₂ correlated well spatially with annual average urban plus regional background (R=0.74, n=104 sites) and especially regional background NO₂ concentrations (R=0.88, n=26). The correlation was moderate for all sites, including traffic locations (R=0.51, n=144). A LUR model including satellite NO₂ observations performed better (overall R²=0.84) than LUR models including geographical coordinates or indicator variables (overall R² 65-74%) in modeling concentrations at the 104 background sites across the Netherlands.Satellite NO₂ observations agreed well with measured surface concentrations at background locations and improved land use regression models, even in a small densely populated country.

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