Gelatine adhesives aka ‘animal glues’ are water-soluble biopolymers used in historic objects such as wooden cabinets and panel paintings since ancient times. This paper investigates the correlations between microstructural features, namely triple helices, and macroscopic properties of four different types of gelatine adhesives, prevalently used in conservation practices, irrespective of the animal origin. These adhesives include bovine bone, bovine skin, rabbit skin, and fish glues. Thin adhesive films were produced via solution casting methods in controlled climate conditions and their thermal and mechanical properties, and moisture sensitivity were investigated. XRD as a non-destructive characterisation method demonstrated good agreement with DSC in the quantification of gelatine adhesive (animal glue) triple helix content irrespective of the animal origin. Linear correlations between triple helices and gel (Bloom) strength and tensile strain energy to failure (toughness) were found for all adhesive types. Dynamic vapour sorption experiments demonstrated that lower triple helix content is correlated with higher moisture sensitivity of the adhesives. Moreover, the effect of environmental RH on the thermal behaviour of adhesives was investigated by DSC. The results demonstrated that the increase in environmental RH causes a reduction in the adhesives' glass transition and denaturation temperatures whilst triple helix content did not alter. Bovine bone glue with the lowest triple helix content showed the least toughness and highest moisture sensitivity, whilst fish glue with the highest triple helix content was identified as the most flexible glue.

Adhesive joints are frequently exposed to cyclic ageing conditions during their service life, which can have a substantial impact on the mechanical properties of both the adhesive and the substrates. The safe life philosophy, commonly employed in the design of bonded joints, underscores the importance of obtaining an accurate estimate of the adhesive's durability. Therefore, it is essential to enhance the predictive capabilities of the adhesive's mechanical behavior under cyclic ageing conditions. This research aims to expand the use of quasi-static cohesive zone modelling (CZM) for damage and fracture analysis of dissimilar adhesive joints subjected to cyclic ageing environments. The first step involved measuring the mechanical properties of the adhesive through tensile tests on unaged and cyclically aged dogbone specimens, considering their moisture content and ageing cycles. Based on the results, a degradable CZM was developed. To validate the numerical model, dissimilar double cantilever beam specimens (DCBs) of glass fibre reinforced polymer (GFRP) and aluminium were manufactured and tested before and after ageing. The load-displacement curves of the bi-materials bonded joints were successfully predicted using the developed model where the properties of the material are defined as a function of the moisture uptake and ageing cycles at each material element. The obtained results showed that after 4 ageing cycles, the maximum load of DCB specimens decrease considerably.

In some industrial applications, adhesive joints are cyclically exposed to a moist environment, where cyclic moisture absorption and desorption can significantly alter the fracture energy of the bonded joints. Most previous studies are based on monotonic aging conditions, while the performance of bonded joints under cyclic aging is not well explored The aim of the current study is to investigate the effect of cyclic aging on mode I fracture energy of dissimilar DCB (double cantilever beam) adhesive joints. Accordingly, bulk adhesive plates were manufactured and exposed to 4 aging cycles. After the aging process, at different exposure times, the aged adhesive plates were used to bond dissimilar Al/GFRP substrates using a secondary adhesive. Then the prepared DCBs were tested and subsequently the mode I fracture energy of the adhesive was determined. Meanwhile, using gravimetrical tests and numerical simulation, moisture diffusion of the adhesive layer in different exposure times was analysed. Using experimental and numerical results, the variation of fracture energy as a function of moisture uptake was studied. In addition, glass transition temperature (T_g) and chemical bonding of the aged adhesive were analysed in different aging cycles. The results showed that by increasing the number of aging cycles, the reduction rate of mode I fracture energy between the aging cycles decreases.

The aim of this study is to investigate the effect of the adherend material on the mode I fracture behaviour of bi-material composite bonded joints. Both single-material (steel-steel and composite-composite) and bi-material (steel-composite) joints bonded with a structural epoxy adhesive are studied. Additionally, two adhesive bondline thicknesses are considered: 0.4 mm (thin bondline) and 10.1 mm (thick bondline). The Penado-Kanninen reduction scheme is applied to evaluate the mode I strain energy release rate. The results show that the mode I fracture energy, G_Ic, is independent of the adherend type and joint configuration (single or bi-material). G_Ic shows average values between 0.60 and 0.72 N/mm for thin bondlines and 0.90–1.10 N/mm for thick bondlines. For thin bondlines, the failure is cohesive and the similar degree of constraint that is imposed to the adhesive by the high-modulus (i.e., steel) and/or relatively thick (i.e., composite) adherends results in similar values of G_Ic for both single- and bi-material joint types. For thick bondlines, the crack grows closer to one of the adhesive-adherend interfaces, but still within the adhesive. The results show that the adhesive could deform similarly, although the crack has been constrained on one side by different types of adherends, either a steel or composite.

This paper presents a new process for obtaining eco-epoxide adhesives synthesized from bio-renewable raw material (tannic acid-TA) and used for bonding lightweight materials (aluminum (Al) and carbon fiber reinforced polymer (CFRP). Two synthesized bio-epoxy components based on TA, (A) glycidyl ether and (B) glycidyl phosphate ester of TA, were used as a replacement for the toxic epoxy component based on Bisphenol A. The effect of eco-epoxy components on the interface adhesion was measured by the determination of adhesion parameter b, which was compared to the reference epoxy (REF). The increase of adhesion parameter b was 77.5% for A and 151.5% for B. The adhesion of both eco-adhesives was tested using the bell peel test (BPT) with the Al and CFRP adherends. When compared to REF, the average peel load for B was 17.6% (39.3%) and 58.3% (176.9%) higher for the Al and CFRP adherends, respectively. Complete adhesion failure of REF reflected the weak adhesion to both Al and CFRP, which was improved by the addition of eco-epoxy components A and B showing the presence of cohesive failure. The microhardness testing method of interface adhesion was proven to be a fast and reliable testing method, providing a qualitative indication in adhesive selection.

Gelatins are proteinaceous natural materials that are widely used in areas such as conservation and restoration of artifacts as adhesives and consolidants, in pharmaceutics as drug delivery carriers, and in the food industry as structurants. Herein, type A porcine gelatin adhesive films are prepared via solution casting method and their physical and mechanical properties are investigated using X-ray diffraction (XRD), differential scanning calorimetry, contact angle measurement, dynamic mechanical analysis, and uniaxial tensile tests. The results demonstrate a linear correlation between microstructure of gelatin films in terms of their triple-helix content and their macroscopic mechanical properties such as tensile strength and gel (Bloom) strength. Moreover, the findings of this study can help the scientists, in, e.g., art conservation and restoration, to predict the mechanical performance of these adhesives by performing a less material demanding and nondestructive physical measurement such as XRD.

The fracture behaviour of joints bonded with a structural epoxy adhesive and bond line thicknesses of 0.1–4.5 mm has been studied. However, limited research is found on similar joints with thicker bond lines, which are relevant for maritime applications. Therefore, the effect of the adhesive bond line thickness, varying from 0.4 to 10.1 mm, on the mode I fracture behaviour of steel to steel joints bonded with a structural epoxy adhesive was investigated in this study. An experimental test campaign of double-cantilever beam (DCB) specimens was carried out in laboratory conditions. Five bond line thicknesses were studied: 0.4, 1.1, 2.6, 4.1 and 10.1 mm. Analytical predictions of the experimental load-displacement curves were performed based on the Simple Beam Theory (SBT), the Compliance Calibration Method (CCM) and the Penado-Kanninen (P-K) model. The P-K model was used to determine the mode I strain energy release rate (SERR). The average mode I SERR, G _Iav., presented similar values for the specimens with adhesive bond line thicknesses of 0.4, 1.1 and 2.6 mm (G _{I av.}=0.71, 0.61, 0.63 N/mm, respectively). However, it increased by approximately 63% for 4.1 mm (G _{I av.}=1.16 N/mm) and decreased by about 10% (in comparison with 4.1 mm) for the 10.1 mm (G _{I av.}=1.04 N/mm). The trend of the G _Iav. in relation to the bond line thickness is explained by the combination of three factors: the crack path location, the failure surfaces features and the stress field ahead of the crack tip.

The impact of UV/ozone treatment on the wettability and adhesion of ethylene propylene diene methylene (EPDM) rubber, polyvinyl chloride (PVC), and acrylonitrile butadiene styrene (ABS) was investigated using contact angle measurements, OWRK surface free energy model, standardized adhesion tests, and spectroscopic and microscopic observations. It is found that UV/ozone treatment enhances the wettability of the examined polymers. Also, it considerably improved the adhesion strength of PVC and ABS samples, and shifted their failure modes from adhesive to cohesive. FTIR-ATR characterization showed insignificant changes in the chemical structures of the studied materials. However, SEM observation showed newly-created wrinkles and micro-holes on treated PVC surfaces, and micropores on ABS surfaces. These UV-induced morphological changes on PVC and ABS surfaces increased the surface area which can promote the mechanical interlocking with the adhesive. This explains the improvement of their adhesion strength. Implications of the current study for the processing of strongly bonded polymeric joints are discussed.

The curing behaviour and the mechanical behaviour of susceptor-assisted induction-cured adhesively bonded joints has been investigated. Induction Heating (IH) was established by mixing Iron particles into a two component epoxy paste adhesive. The effect of different process parameters, such as particle content, coupling distance and coil current, on the IH curing process was evaluated by experimental tests and simulation of the induction heating process in COMSOL multiphysics. The process simulation showed that hysteresis losses has a major contribution for the heat generation of IH using Iron particles. Differential scanning calorimetry (DSC) analysis was used to assess the effect of susceptor particles on the cure behaviour of the adhesive. The results showed that the Iron particles do not interfere with the curing process of the epoxy adhesive in scope. The mechanical performance was evaluated through Single Lap-Shear (SLS) testing at different volume-percentages of Iron particles in combination with glass fibre reinforced plastic (GFRP) adherends. Induction-cured SLS samples were compared with conventional oven-cured SLS samples. In the oven cured samples, the addition of Iron particles resulted in a decrease in the lap-shear strength of 15% to 20%, even for a volume-percentage as low as 0.5%. An additional increase in particle content up to 7.5 v% did not show any additional reduction in the lap-shear strength. Furthermore, results show that when curing the adhesive layer from the inside, as in the susceptor-assisted induction heating, the lap-shear strength is 6% higher than in oven-cured samples (curing the adhesive layer from the outside).