Plasmonic CO₂ methanation using γ-Al₂O₃-supported Ru nanorods was carried out under continuous-flow conditions without conventional heating, using mildly concentrated sunlight as the sole and sustainable energy source (AM 1.5, irradiance 5.5–14.4 kW·m⁻² = 5.5–14.4 suns). Under 12.5 suns, a CO₂ conversion exceeding 97% was achieved with complete selectivity towards CH₄ and a stable production rate (261.9 mmol·g^{−1 Ru·h−1}) for at least 12 h. The CH₄ production rate showed an exponential increase with increasing light intensity, suggesting that the process was mainly promoted by photothermal heating. This was confirmed by the apparent activation energy of 64.3 kJ·mol⁻¹, which is very similar to the activation energy obtained for reference experiments in dark (67.3 kJ·mol⁻¹). The flow rate influence was studied under 14.4 suns, achieving a CH₄ production plateau of 264 µmol min⁻¹ (792 mmol·g^{−1 Ru·h−1}) with a constant catalyst bed temperature of approximately 204^◦C.

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Distinguishing between photothermal and non-thermal contributions is essential in plasmon catalysis. Use of a tailored optical temperature sensor based on fiber Bragg gratings enabled us to obtain an accurate temperature map of an illuminated plasmonic catalyst bed with high spatiotemporal resolution. Its importance for quantification of the photothermal and non-thermal contributions to plasmon catalysis is demonstrated using a Ru/Al₂O₃ catalyst. Upon illumination with LEDs, we measured temperature differences exceeding 50 °C in the top 0.5 mm of the catalyst bed. Furthermore, we discovered differences between the surface temperature and the temperature obtained via conventional thermocouple measurements underneath the catalyst bed exceeding 200 °C at 2.6 W cm⁻² light intensity. This demonstrates that accurate multi-point temperature measurements are a prerequisite for a correct interpretation of catalysis results of light-powered chemical reactions obtained with plasmonic catalysts.

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Sunlight-powered reduction of CO₂ to fuels and chemicals is a promising strategy to close the carbon loop and facilitate the energy transition. In this research, we demonstrate that Au nanoparticles supported on TiO₂ are an efficient plasmonic catalyst for the sunlight-powered reverse water-gas shift (rWGS) reaction. A maximum CO production rate of 429 mmol ⋅ g_Au⁻¹ ⋅ h⁻¹ with a selectivity of 98 % and an apparent quantum efficiency of 4.7 % were achieved using mildly concentrated sunlight (1.44 W ⋅ cm⁻² equals 14.4 sun). The CO production rate showed an exponential increase with increasing light intensity, suggesting that the process is mainly promoted by a photothermal effect. Thermal reference experiments with the same catalysts promoted CH₄ formation, dropping the CO selectivity to 70 %. Thus, mildly concentrated sunlight can efficiently and selectively enhance the promotion of the rWGS reaction without using external heating.

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Water-soluble polyacrylamides have often been used to modify flow response in various water-based technologies and industrial processes, including paints, water treatment, paper manufacturing, and chemical enhanced oil recovery. Polymers are susceptible to degradation at combined high salinity and elevated temperature conditions which limits their overall performance. Hybrid mixtures of hydrophobically modified polyacrylamide (HMPAM) with hydrophobically modified silica nanoparticles (NPs) emerged as a promising strategy for achieving enhanced stability and high viscosity in brines having a high total dissolved solids (TDS) content and high hardness at elevated temperatures (>20 wt% TDS, including >1.5 wt% divalent cations at T > 70 °C). The rheological response of the hybrids at various concentrations of HMPAM and NPs was examined to investigate the synergic effects. Hybridization of HMPAM with NPs led to a higher viscosity at high salinity and elevated temperature. The viscosity improvement was more pronounced when the concentration of HMPAM was in the semi-dilute regime and concentration of NPs was higher than a critical threshold where the viscosity increased roughly by a factor of 1.5. Here we present the mechanisms of improved viscosity behaviour. The rheological data suggest the role of NPs in the bridging between HMPAM molecules, which in turn increases the hydrodynamic radius and consequently the viscosity of the hybrids.@en

Both in design and production of nanoparticles and nanocomposites it is of vital importance to have information about their size and concentration. During the formation of nanoparticles, real-time monitoring of particle size and concentration during bottom-up synthesis in liquids allows for a detailed study of nucleation and growth. This provides valuable insights into the formation of nanoparticles that can be used for process optimization and scale up. In the production of nanoparticles, real-time monitoring enables intervention to minimize the number of off-spec batches. In this paper we will qualify an ultrasound nanoparticle sizer (UNPS) as a real-time monitor for the growth of nanoparticles (or sub-micro particles) in the 100 nm-1 μm range. Nanoparticles affect the speed and attenuation of ultrasonic waves in the dispersion. The size of the change depends, amongst other things, on the size and concentration of the nanoparticles. This dependency is used in the UNPS method. The qualification of the UNPS was undertaken in two successful experiments. The first experiment consisted of static measurements on commercially available silica particles, and the second experiment was real-time monitoring of the size and concentration during the growth of silica nanoparticles in Stöber synthesis in a water-alcohol mixture starting from the molecular precursor tetraethyl orthosilicate. The results of the UNPS were verified by measurements of a dynamic light scattering device and a transmission electron microscope.

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