Self-healing concrete using encapsulated healing agent has shown great potential in enhancing concrete durability. However, the capsules are expensive to make and can lower the mechanical properties of concrete. In this study, a new type of manufactured aggregate that employs waste-derived fly ash cenosphere as a carrier of healing agent (SH-CS) was designed and produced. The effect of SH-CS incorporation on hydration, engineering properties and self-healing efficiency of cement mortar was systematically evaluated, with a special focus on self-healing mechanism through the analysis of the mineral composition of the healing product. The results indicate that the prepared SH-CS has good stability in and compatibility with cement mortar. The addition of SH-CS has small influence on the fresh properties of cement mortar and less negative effect on compressive strength at the hardened stage compared to the existing study. By replacing 3 wt.% of fine aggregate with SH-CS, up to 71% of the crack opening area of mortar specimens with a crack width of about 0.3 mm was self-healed after 28 days of water exposure. The self-healing behaviour of SH-CS led to a maximal 41% drop in water adsorption and contributed to the recovery of flexural strength. The healing products precipitated on the fracture surface were mainly composed of amorphous C-S-H and Calcite. It can be estimated that incorporating SH-CS in concrete would result in only a moderate (∼29%) rise in cost for C40 concrete.

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The particle size distribution (PSD) has a significant influence on the fresh and final properties of cement and its derived products. In this paper, CSA cements with three different mean diameters (D₅₀), ranging from 6.04 to 26.62 μm were prepared by milling. The pre-hydration behavior was quantitatively analyzed, including the degree of pre-hydration, the dynamic change of mineral assemblage and the morphology of the prepared CSA cement exposed to 57%, 75% and 97% relative humidities (RHs) for up to 90 days. Hydration kinetics, porosity, and compressive strength of the cement paste made with fresh and pre-hydrated CSA cement with different PSD were also characterized. The results show that pre-hydration of CSA cement at RH higher than 75% has detrimental effects on the hydraulic activity and strength gain of CSA cement. However, coarser CSA cement (D₅₀ = 26.62 μm) does not only show better resistance to pre-hydration, but also higher compressive strength and lower porosity.

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In this research, the effects of natural seawater (SW) on the properties of alkali-activated slag/fly ash (AASF) are studied. AASF prepared with deionized water is set as the reference mixture. The results showed that the use of natural SW resulted in a prolonged setting time and lower heat release, but no obvious impact on the flowability of AASF specimens. The long-term compressive strength became higher when SW was used, whereas the corresponding flexural strength and fractural toughness turned lower. The use of SW induced the formation of new products that were not identified in the reference mixture, such as Cl–hydrocalumite and gypsum. In addition, it is evidenced that the dissolution of fly ash (FA) particles was significantly delayed with the incorporation of SW. All these results were related to the various ions introduced by the natural SW and their interactions with the alkaline activator as well as the precipitation of salts on slag and FA surfaces or in the matrix.

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One-part alkali-activated slag (AAS) binders are more promising in large-scale constructions because one-part mixing procedure is safer and easier to handle compared to normal two-part method. Thus, this study aims at investigating different properties of one-part AAS binders and control samples prepared using the two-part method. Experimental results of the former suggested the hardening time was greatly extended, but the workability showed little difference. Besides, compared to the control, one-part AAS binders had similar early compressive strength (within 7 days) and flexural strength in all tested curing stages but lower later compressive strength (from 28 days). The characterisation of the porous structures suggests that there were fewer C-A-S-H gels for one-part binders evidenced by less volume of mesopores but with larger amount of bigger pores. In addition, mineralogical and microstructural analyses imply that there was no hydrotalcite formed in the one-part AAS binders. Moreover, one-part AAS binders are more susceptible to efflorescence, presumably further affecting their surface and long-term durability.@en

The use of CSA cement in practice has been hindered by its unstable performance and short shelf-life caused by the prehydration of CSA clinker. In this study, the effect of ambient humidity on the prehydration rate and process of CSA clinker was investigated. The prehydration degree, ageing progress, and the dynamic change of mineral composition of CSA clinker exposed to five different relative humidities (ranging from 23% to 98%) for up to 180 days were studied. Experiments revealed that the ambient humidity of 60% RH can be considered a threshold value for storage of CSA clinker. Exposure of CSA clinker to RH higher than 60% will not only result in a significant decrease of hydraulic reactivity, but also in agglomeration of the clinker. Although the exposure of CSA clinker to RH lower than 60% has little effect on the hydraulic reactivity, the main hydration peak was found to be slightly delayed with the increase of RH.

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A cementitious system embedded in microcapsules can achieve self-healing, and the fracture and triggering behavior of microcapsules is with great importance. In this study, the crack behavior of the concrete-microcapsule system was simulated by a three-dimensional lattice model. Based on the results of the fracture energy test on concrete beams and the nanoindentation test on microcapsules, the local mechanical properties of the lattice elements were determined. The aim of this paper is to set up a three-dimensional lattice model to study the trigger mechanism of the microcapsule-interface-concrete zone.@en

External sulfate attack is a progressive degradation process that may cause expansion, cracking, loss of binder cohesion and increased permeability in cementitious materials. Crystallization pressure theory has often been referred to as the most likely mechanism. However, thus far the stress causing the expansion has not been quantified. In this study, small cement paste pipes with a wall thickness of 2.5 mm were prepared and immersed in sodium sulfate solutions with SO₄²⁻ ion concentrations of 1.5 g/L and 30 g/L. Three types of longitudinal restraints were applied on the specimens before exposure, which were created by a spring, a thin or a thicker stainless steel bar that was centered in the hollow specimens in order to facilitate the non-, low- or high-restraint condition. The free expansion, restrained expansion and generated stress were quantified. The pore size distribution, sulfur distribution and crack pattern were periodically analyzed during the sulfate immersion tests up to 420 days. The generated stresses were found to be as high as 13.1 MPa in high sulfate solution and 8.3 MPa in low sulfate solution under high-restraint condition after 420-day immersion. For the unrestrained specimens immersed in low sulfate solution, an almost uniform sulfur distribution along the diffusion direction was found at 189-day immersion. However, for the unrestrained specimens immersed in high sulfate solution, a layer or several layers of mainly gypsum were formed subparallel to the exposed surface from 133-day immersion.

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A 2D lattice model was constructed to simulate crack process of in shell-interlayer-cement paste zone. The simulated tensile strength was validated by an experimental uniaxial tensile test and used as the input for a 3D lattice model, which was constructed to perform mechanical analysis based on a series of 2D X-ray microtomography images. The fracture behaviour of the 3D lattice model with assigned mechanical properties gave a similar crack pattern and tensile strength as the real structure. This study is expected to provide a feasible approach for investigating the fracture and trigger behaviour miccrocapsules embedded in a self-healing cementitious system.

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At present several methods are available to predict the durability of reinforced concrete structures. In most cases, one dominant deterioration process such as carbonation or chloride penetration is taken into consideration. Experimental results as well as observations in practice show that this is not a realistic and certainly not a conservative approach. In order to test more realistically, RILEM TC 246-TDC, founded in 2011, has developed a method to determine the durability of concrete exposed to the combined action of chloride penetration and mechanical load. In this report, a test method is presented which allows determination of realistic diffusion coefficients for chloride ions in concrete under compressive or tensile stress. Comparative test results from five different laboratories showed that the combination of mechanical and environmental loads may be much more severe than a single environmental load without mechanical loading. Modelling and probabilistic analysis also showed that the obvious synergetic effects cannot be neglected in realistic service life prediction.

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Water ingress into cracked concrete structures is a serious problem, as it can cause leakage and reinforcement corrosion and thus reduce functionality and safety of the structures. In this study, the application of water-swelling rubber particles for providing the cracked concrete a self-sealing function was developed. The feasibility of applying water-swelling rubber particles and the influence of incorporating water-swelling rubber particles on the mechanical properties of concrete was investigated. The self-sealing efficiency of water-swelling rubber particles with different content and particle size was quantified through a permeability test. The sealing effect of the water swelling rubber particles was monitored by X-ray computed tomography. The experimental results show that, by using 6% of these water swelling rubber particles as a replacement of aggregates in concrete, up to 64% and 61% decrease of water permeability was realized for 0.7 mm and 1.0 mm cracks. Furthermore, when the concrete cracks, the water swelling rubber particles can act as a crack bridging filler, preventing the crack from fully separating the specimens in two pieces.

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Self-healing cementitious materials containing a microencapsulated healing agent are appealing due to their great application potential in improving the serviceability and durability of concrete structures. In this study, poly(phenol-formaldehyde) (PF) microcapsules that aim to provide a self-healing function for cementitious materials were prepared by an in situ polymerization reaction. Size gradation of the synthesized microcapsules was achieved through a series of sieving processes. The shell thickness and the diameter of single microcapsules was accurately measured under environmental scanning electron microscopy (ESEM). The relationship between the physical properties of the synthesized microcapsules and their micromechanical properties were investigated using nanoindentation. The results of the mechanical tests show that, with the increase of the mean size of microcapsules and the decrease of shell thickness, the mechanical force required to trigger the self-healing function of microcapsules increased correspondingly from 68.5 ± 41.6 mN to 198.5 ± 31.6 mN, featuring a multi-sensitive trigger function. Finally, the rupture behavior and crack surface of cement paste with embedded microcapsules were observed and analyzed using X-ray computed tomography (XCT). The synthesized PF microcapsules may find potential application in self-healing cementitious materials.

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In the semiconductor industry, positioning accuracy and acceleration are critical parameters. To improve the acceleration speed of a motor, this paper proposes the moving-coil maglev planar motor with a concentric winding structure. The coordinate system has been built for the multiple degrees of freedom movement system. The Lorenz force method has been applied to solve its electromagnetic model. The real-time solving of the generalized inverse matrix of factors can realize the decoupling of the winding current. When the maglev height changes, the electromagnetic force and torque decreases exponentially with the increase of the air gap. To decrease the influence on control system performance by the internal model change and the external disturbance, this paper proposes an improved active disturbance rejection control (ADRC) to design the controller. This new controller overcomes the jitter phenomenon due to the turning point for the traditional ADRC, thus it is more suitable for the maglev control system. The comparison between ADRC and the improved ADRC has been conducted, the result of which shows the improved ADRC has greater robustness.@en