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This study explores a model (MIKADO) to analyse scenarios for the reduction of the environmental impact of an aluminium die casting plant. Our model calculates the potential to reduce emissions, and the costs associated with implementation of reduction options. In an earlier paper [Neto, B., Kroeze, C., Hordijk, L., Costa, C., 2008. Modelling the environmental impact of an aluminium pressure die casting company and options for control. Environmental Modelling & Software 23 (2) 147-168] we included the model description and explored the model by applying it to a plant in which no reduction options are assumed to be implemented (so-called zero case, reflecting the current practice in the plant). Here, we perform a systematic analysis of reduction options. We analysed seven types of reduction strategies, assuming the simultaneous implementation of different reduction options. These strategies are analysed with respect to their potential to reduce emissions, environmental impact and costs associated with the implementation of options. These strategies were found to differ largely in their potential to reduce the environmental impact of the plant (10-87%), as well as in the costs associated with the implementation of options (-268 to +277 k€/year). We were able to define 11 strategies, reducing the overall environmental impact by more than 50%. Of these, two have net negative costs, indicating that the company may in fact earn money through their implementation. © 2008 Elsevier Ltd. All rights reserved.

This paper (the second in a series of three) compares incineration options for hazardous waste with LCA. Provided that acceptance criteria are met with regard to metals, PAHs and chlorine, Dutch Municipal Solid Waste Incinerators (MSWIs) appeared to be preferable above rotary kilns since they have a better energy recovery and - unlike rotary kilns - produce reusable slags. The position of the cement kiln relative to the MSWI and rotary kiln depends on the allocation method chosen. System enlargement, which may be most highly defensible, tends to give cement kilns the advantage. Yet, two key concerns which are unsolvable by LCA make final conclusions impossible. First, an input of highly contaminated waste leads to an enrichment of cement with metals. Long-term consequences are not known, so the incineration of waste with a high metal content will inevitably be controversial. Second, no convincing proof was found that cement kilns would not produce additional hazardous process emissions (e.g. dioxins) when using waste instead of fuel. The precautionary principle demands that such proof be provided before cement kilns can be considered for the incineration of waste with a composition other than their regular fuel.

The Port of Rotterdam is expanding to meet the growing demand to accommodate large cargo vessels. The construction of Maasvlakte 2 (MV2) started in September 2008. One of the licensing conditions is the monitoring of the underwater sound produced during its construction, with an emphasis on the establishment of acoustic source levels of the trailing suction hopper dredgers (TSHDs) during their various activities: dredging, transport and discharge of sediment. TNO (Netherlands Organisation for Applied Scientific Research) Sonar and Acoustics carried out measurement and analysis activities for this monitoring. During an initial measurement campaign in September 2008, background measurements were performed in the absence of dredging. Source level and background sound measurements were made in the dredging area while MV2 dredging activities were underway in September 2009. In a final phase of the study, possible effects of underwater sound on marine fauna were considered for scenarios with and without dredgers. In this article, the principal results of the research are described and discussed in the context of the effects predicted in the Environmental Impact Assessment.

The European Union requires member states to achieve or maintain good environmental status for their marine territorial waters and explicitly mentions potentially adverse effects of underwater sound. In this study, we focused on producing maps of underwater sound from various natural and anthropogenic origins in the Dutch North Sea. The source properties and sound propagation are simulated by mathematical methods. These maps could be used to assess and predict largescale effects on behavior and distribution of underwater marine life and therefore become a valuable tool in assessing and managing the impact of underwater sound on marine life. © Springer Science+Business Media New York 2016.

In agricultural areas where greenhouses and dwellings are intermixed, the general population as well as the professional applicators may be exposed to pesticides. In a field study on Crete, exposure to methyl bromide during soil fumigation was assessed. Exposure of applicators (both contractors and farmers) were measured with personal air sampling equipment. Environmental monitoring inside and outside greenhouses combined with meteo data formed the basis for calculating the exposure of the general population with a computer aided dispersion model. Exposure of contractors exceeded the TLV value. The safe limit for the general population living close to a fumigated greenhouse is also exceeded.

Background, aim and scope: The environmental impact of building products made from heavy metals has been a topic of discussion for some years. This was fuelled by results of life cycle assessments (LCAs), where the emission of heavy metals strongly effected the results. An issue was that the characterisation factors of the Centre for Environmental Studies (CML) 2000 life cycle impact assessment (LCIA) methodology put too much emphasis on the impact of metal emissions. We adjusted Zn characterisation factors according to the most recent insights in the ecotoxicity of zinc and applied them in an LCA using zinc gutters and downpipes as an example. Materials and methods: The CML 2000 methodology was used to assess the environmental impact of the zinc products. To adjust the Zn characterisation factors, the uniform system for the evaluation of substances (USES)-LCA model and the biotic ligand model were used. Results and discussion: The first correction was based on updating the effect values for zinc. This resulted in a reduction of the characterisation factors for zinc to 42% of their original values. Additional correcting for the bioavailability of zinc leads to final Zn characterisation factors for the freshwater aquatic ecotoxicity potential (FAETP), the marine aquatic ecotoxicity potential (MAETP) and the terrestrial ecotoxicity potential (TETP) of 25%, 42% and 0.006%, respectively, of the original values. The CML 2000 LCIA methodology is based on the predicted no-effect concentration (PNEC) of a substance. PNEC is not value-free as political considerations are used to decide on it. Using a more robust toxicity measure as the hazardous concentration at which 50% of the species is affected (HC50) will provide value-free results. The production of standard high-grade zinc shows main contributions to six of the ten environmental impact categories. The recycling of zinc at the end of the life cycle shows beneficial effects for these same categories. Despite the reduction of the characterisation factor of Zn, the runoff emissions of Zn are still dominant. Conclusions and recommendations: To improve LCA characterisation factors for ecotoxicity in the CML 2000 methodology, it is recommended to use either the geometric mean of the effect data or the HC50. The HC50 should be based upon the EC50 values from chronic ecotoxicity tests. It is proposed to include the bioavailability of metals in LCA in three steps: (1) separate soluble fraction, (2) separate dissolved fraction and (3) separate bioavailable fraction. The issue of essentiality could not be resolved in this study. However, this could be accounted for by leaving out the fraction of the emission below the maximum permissible admission. © 2010 The Author(s).

This paper presents results of an assessment of the linkages between regional air pollution and climate change in Europe (the AIR-CLIM Project). The main research tool was an integrated modeling framework and the main product was a consistent set of long-term scenarios covering Europe between 1995 and 2100. Scenarios consisted of trends in emissions, acid deposition, nitrogen deposition and climate change. Critical loads and critical levels were used to assess the impacts of deposition to forest soils and a new analogous concept of "critical climate change" was developed to assess the impacts of climate change. Taking into consideration the limitations of the scope and models used in the study, preliminary conclusions were: (1) regional air pollution and climate change may be fairly weakly coupled in the natural environment, i.e. climate change was not found to have a large impact on the sensitivity of forest ecosystems to regional air pollution, nor on the distribution of deposition; nor did regional air pollution (in the form of sulfate aerosols) have a significant impact on climate change in Europe; (2) however, regional air pollution and climate change may be strongly coupled in the "policy" environment. It was estimated that virtually all of Europe at mid-century might be affected by either regional air pollution or climate change, or both, and this will require a strong policy response. Moreover, the indirect effects of climate policies were found to reduce the costs of controlling air pollution emissions by more than 50%, suggesting a strong potential financial linkage between policies to reduce greenhouse gas and air pollution emissions. © 2002 Published by Elsevier Science Ltd.

The underwater sound produced during construction of the Port of Rotterdam harbor extension (Maasvlakte 2) was measured, with emphasis on the contribution of the trailing suction hopper dredgers during their various activities: dredging, transport, and discharge of sediment. Measured source levels of the dredgers, estimated source levels of other shipping, and time-dependent position data from a vessel-tracking system were used as input for a propagation model to generate dynamic sound maps. Various scenarios were studied to assess the risk of possible effects of the sound from dredging activities on marine fauna, specifically on porpoises, seals, and fish. © Springer Science+Business Media New York 2016.

Marine mammals may be negatively affected by anthropogenic noise. Behavioural response studies (BRS) aim to establish a relationship between noise exposure conditions (dose) from a potential stressor and associated behavioural responses of animals. A recent series of BRS have focused on the effects of naval sonar sounds on cetaceans. Here, we review the current state of understanding of naval sonar impact on marine mammals and highlight knowledge gaps and future research priorities. Many marine mammal species exhibit responses to naval sonar sounds. However, responses vary between and within individuals and populations, highlighting the importance of exposure context in modulating dose–response relationships. There is increasing support from both terrestrial and marine systems for the risk-disturbance hypothesis as an explanation for underlying response processes. This proposes that sonar sounds may be perceived by animals as a threat, evoking a response shaped by the underlying species-specific risk of predation and anti-predator strategy. An understanding of responses within both the dose–response and risk-disturbance frameworks may enhance our ability to predict responsiveness for unstudied species and populations. Many observed behavioural responses are energetically costly, but the way that these responses may lead to long-term individual and population-level impacts is poorly understood. Synthesis and applications. Behavioural response studies have greatly improved our understanding of the potential effects of naval sonar on marine mammals. Despite data gaps, we believe a dose-response approach within a risk-disturbance framework will enhance our ability to predict responsiveness for unstudied species and populations. We advocate for (1) regulatory frameworks to utilize peer-reviewed research findings when making predictions of impact, (2) regulatory frameworks to account for the inherent uncertainty in predictions of impact and (3) investment in monitoring programmes that are both directed by recent research and offer opportunities for validation of predictions at the individual and population level. © 2017 The Authors. Journal of Applied Ecology published by John Wiley & Sons Ltd on behalf of British Ecological Society.

Comparisons of measured and model-predicted atmospheric copper concentrations show a severe underestimation of the observed concentrations by the models. This underestimation may be (partly) due to underestimated emissions of copper to air. Since the phase out of asbestos brake lining material, the composition of brake lining material has changed and may contain up to ∼15% copper. This makes brake wear from vehicles potentially an important source of atmospheric (particulate) copper concentrations. In this paper, we reassess the copper emissions due to exhaust emissions and brake wear from road transport. Overall, our reassessments result in an estimate of total copper emission to air in UNECE-Europe of 4.0-5.5 ktonnes yr-1, which is substantially higher than the previous estimate of 2.8 ktonnes yr-1. Copper concentrations over Europe are calculated with the LOTOS-EUROS model using the revised emission data as model input. The results show that the revised emission estimates are a major step towards gap closure of predicted versus observed copper concentrations in ambient air. Brake wear emissions may be responsible for 50-75% of the total copper emissions to air for most of Western Europe. The hypothesis that road transport is an important source of copper emissions is tested and confirmed by (1) reviewing available literature data of chemically speciated PM data from road tunnel studies and (2) the gradient observed in copper concentrations from ambient PM monitoring going from rural sites to street stations. The literature review and observational data suggest that the majority of the emitted PM10 brake wear particles is in the PM2.5-10 size range. The results of this study indicate that modification of brake lining composition is an important mitigation option to reduce copper exposure of the population in Western Europe. © 2007 Elsevier Ltd. All rights reserved.

Endotoxin exposure occurs in homes and occupational environments and is known to cause adverse health effects. In order to compare results from different studies and establish standards, airborne endotoxin exposures should be assessed using standardized methods. Although the European Committee for Standardization (CEN) developed guidelines for endotoxin exposure assessment, these leave room for individual interpretation. The influence of methods of sampling, extraction, and analysis has never been investigated in a full experimental design. Thus, we sought to fully elucidate the importance of all facets of endotoxin assessment. Inhalable dust samples collected simultaneously were used to investigate the effects on and interactions with airborne endotoxin concentration in two working environments of filter type (glass fiber or Teflon), transport conditions (with/without desiccant), sample storage (-20 or 4°C), extraction solution (pyrogen-free water [PFW] or PFW plus 0.05% Tween 20), extract storage (-20 or 4°C), and assay solution (PFW or PFW plus 0.05% Tween 20). Four hundred samples were collected and randomly distributed over the 20 combinations of treatments. There were no differences found for transport conditions and storage temperature of extracts. Also, no interactions between study variables existed. Sampling on glass-fiber filters, storage of samples in the freezer, and extraction in PFW plus 0.05% Tween 20 resulted in 1.3-, 1.1-, and 2.1-fold-higher estimated endotoxin concentrations, respectively. Use of PFW plus 0.05% Tween 20 in the assay solution had an additive effect. Thus, this study investigated gaps in the CEN protocol and provides data with which to fully specify a protocol for standardization of endotoxin exposure assessment. Copyright © 2007, American Society for Microbiology. All Rights Reserved.

The vertical allocation of emissions has a major impact on results of Chemistry Transport Models. However, in Europe it is still common to use fixed vertical profiles based on rough estimates to determine the emission height of point sources. This publication introduces a set of new vertical profiles for the use in chemistry transport modeling that were created from hourly gridded emissions calculated by the SMOKE for Europe emission model. SMOKE uses plume rise calculations to determine effective emission heights. Out of more than 40 000 different vertical emission profiles 73 have been chosen by means of hierarchical cluster analysis. These profiles show large differences to those currently used in many emission models. Emissions from combustion processes are released in much lower altitudes while those from production processes are allocated to higher altitudes. The profiles have a high temporal and spatial variability which is not represented by currently used profiles. © 2010 Published by Elsevier Ltd.

In this study two desalination technologies have been compared by means of LCA with the focus on energy supply with a variety of scenarios based on different assumptions. The studied technologies are reverse osmosis and the newly developed technology Memstill where electrical energy demand is reduced by using external thermal energy source and use of chemicals is reduced. The scenarios are chosen to simulate different locations of sea water desalination plants and to demonstrate the impact of energy demand and energy source, chemical use and longer components' life times on the environment. The results show the dominant impact of energy demand on the overall results for all applied environmental impact assessment methods; transports, material and even chemical use are of negligible impact on the total score. The use of waste heat in case of Memstill offers a great opportunity to reduce the negative environmental impacts related to energy use. As the LCA analysis tool the GaBi software has been applied with the Ecoindicator99, CML 2001 and Ecopoints environmental impact assessment methods. © IWA Publishing 2011.