Repository hosted by TU Delft Library

Home · Contact · About · Disclaimer ·
 

Impurity profiling of trinitrotoluene using vacuum-outlet gas chromatography-mass spectrometry

Publication files not online:

Author: Brust, H. · Willemse, S. · Zeng, T. · Asten, A. van · Koeberg, M. · Heijden, A.E.D.M. van der · Bolck, A. · Schoenmakers, P.
Type:article
Date:2014
Publisher: Elsevier
Source:Journal of Chromatography A, 1374, 224-230
Identifier: 520728
doi: doi:10.1016/j.chroma.2014.11.055
Keywords: Chemistry · Explosives · Forensic science · Impurity profiling · TNT · Trinitrotoluene · Vacuum-outlet GC-MS · Explosives · Impurities · Isomers · Mass spectrometry · 2 ,4-dinitrotoluene · 2 ,6-Dinitrotoluene · Forensic science · Impurity profiling · Limits of detection · Selected-ion monitoring (SIM) · TNT · Trinitrotoluene · Gas chromatography · Fluid Mechanics Chemistry & Energetics · EM - Energetic Materials · TS - Technical Sciences

Abstract

In this work, a reliable and robust vacuum-outlet gas chromatography-mass spectrometry (GC-MS) method is introduced for the identification and quantification of impurities in trinitrotoluene (TNT). Vacuum-outlet GC-MS allows for short analysis times the analysis of impurities in TNT was performed in 4. min. This study shows that impurity profiling of TNT can be used to investigate relations between TNT samples encountered in forensic casework. A wide variety of TNT samples were analyzed with the developed method. Dinitrobenzene, dinitrotoluene, trinitrotoluene and amino-dinitrotoluene isomers were detected at very low levels (<1. wt.%) by applying the MS in selected-ion monitoring (SIM) mode. Limits of detection ranged from 6. ng/mL for 2,6-dinitrotoluene to 43. ng/mL for 4-amino-2,6-dinitrotoluene. Major impurities in TNT were 2,4-dinitrotoluene and 2,3,4-trinitrotoluene. Impurity profiles based on seven compounds showed to be useful to TNT samples from different sources. Statistical analysis of these impurity profiles using likelihood ratios demonstrated the potential to investigate whether two questioned TNT samples encountered in forensic casework are from the same source.