Print Email Facebook Twitter Control of interpenetration of copper-based MOFs on supported surfaces by electrochemical synthesis Title Control of interpenetration of copper-based MOFs on supported surfaces by electrochemical synthesis Author Sachdeva, S. Pustovarenko, A. Sudhölter, E.J.R. Kapteijn, F. De Smet, L.C.P.M. Gascon, J. Faculty Applied Sciences Department Chemical Engineering Date 2016-01-11 Abstract A study of a copper-based metal–organic framework (MOF) synthesized by an electrochemical route is presented. Morphological and adsorption properties of the MOF synthesized as bulk powder and on supported copper surfaces were investigated. Differences in these properties and structural refinement studies indicate that when 4,4?,4??-s-triazine-2,4,6-triyl-tribenzoic acid (H3TATB) is used as linker interpenetration can be prevented when the structure is grown on a surface. Subject Gold for GoldOpen Access To reference this document use: http://resolver.tudelft.nl/uuid:276944aa-369a-4a4e-bf0b-27b9aba7e6ee DOI https://doi.org/10.1039/C5CE02462E Publisher RSC Publishing ISSN 1466-8033 Source CrystEngComm, 2016, Advance Article Part of collection Institutional Repository Document type journal article Rights (c) 2016 RSC Files PDF c5ce02462e.pdf 1.71 MB Close viewer /islandora/object/uuid:276944aa-369a-4a4e-bf0b-27b9aba7e6ee/datastream/OBJ/view