Print Email Facebook Twitter The second-order magnetic phase transition and magnetocaloric effect in all-d-metal NiCoMnTi-based Heusler alloys Title The second-order magnetic phase transition and magnetocaloric effect in all-d-metal NiCoMnTi-based Heusler alloys Author Zhang, F. (TU Delft RST/Fundamental Aspects of Materials and Energy) Westra, Kevin (Student TU Delft) Shen, Q. (TU Delft RST/Fundamental Aspects of Materials and Energy) Batashev, I. (TU Delft RST/Fundamental Aspects of Materials and Energy) Kiecana, A. (TU Delft RST/Fundamental Aspects of Materials and Energy) van Dijk, N.H. (TU Delft RST/Fundamental Aspects of Materials and Energy) Brück, E.H. (TU Delft RST/Fundamental Aspects of Materials and Energy) Date 2022 Abstract The novel all-d-metal Ni(Co)MnTi based magnetic Heusler alloys provide an adjustable giant magnetocaloric effect and good mechanical properties. We report that the second-order magnetic phase transition can be tailored in this all-d-metal NiCoMnTi based Heusler system by optimizing the Mn/Ti ratio, resulting in a reversible ferromagnetic-to-paramagnetic magnetic transition. A candidate material Ni33Co17Mn30Ti20 with a magnetic entropy change ∆Sm of 2.3 Jkg−1K−1 for a magnetic field change of 0–5 T, has been identified. The TC and saturation magnetization MS can be controlled by adjusting the Ni/Co concentration and doping non-magnetic Cu atoms. The compositional maps of TC and MS have been established. Density functional theory (DFT) calculations reveal a direct correlation between the magnetic moments and the Co content. By combining XRD, SQUID, SEM and DFT calculations, the (micro)structural and magnetocaloric properties have been investigated systematically. This study provides a detailed insight in the magnetic phase transition for this all-d-metal Ni(Co)MnTi-based Heusler alloy system. Subject All-d-metalHeusler alloysMagnetocaloric effectNi(Co)MnTiSOMT To reference this document use: http://resolver.tudelft.nl/uuid:311fbf95-9d5c-4076-adb7-83b78d833cd0 DOI https://doi.org/10.1016/j.jallcom.2022.164337 ISSN 0925-8388 Source Journal of Alloys and Compounds, 906 Part of collection Institutional Repository Document type journal article Rights © 2022 F. Zhang, Kevin Westra, Q. Shen, I. Batashev, A. Kiecana, N.H. van Dijk, E.H. Brück Files PDF 1_s2.0_S0925838822007289_main.pdf 6.85 MB Close viewer /islandora/object/uuid:311fbf95-9d5c-4076-adb7-83b78d833cd0/datastream/OBJ/view