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Perrin, M.L. (author), Galán García, E. (author), Eelkema, R. (author), Thijssen, J.M. (author), Grozema, F.C. (author), van der Zant, H.S.J. (author)In the pursuit of down-sizing electronic components, the ultimate limit is the use of single molecules as functional devices. The first theoretical proposal of such a device, predicted more than four decades ago, is the seminal Aviram–Ratner rectifier that exploits the orbital structure of the molecule. The experimental realization of single...journal article 2016
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Gorczak, N. (author), Renaud, N. (author), Galan, E. (author), Eelkema, R. (author), Siebbeles, L.D.A. (author), Grozema, F.C. (author)Quantum interference is a well-known phenomenon that dictates charge transport properties of single molecule junctions. However, reports on quantum interference in donor-bridge-acceptor molecules are scarce. This might be due to the difficulties in meeting the conditions for the presence of quantum interference in a donor-bridge-acceptor system....journal article 2016
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Galán, E. (author), Perrin, M.L. (author), Lutz, M. (author), Van der Zant, H.S.J. (author), Grozema, F.C. (author), Eelkema, R. (author)We have described the synthesis of novel biphenylethane-based wires for molecular electronics. Exceptional single-molecule diode behavior was predicted for unsymmetrically substituted biphenylethane derivatives, synthesized here using the so far unexplored unsymmetrically substituted 1,2-bis(4-bromophenyl)ethanes as key intermediates, which were...journal article 2016
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Gorczak, N. (author), Renaud, N. (author), Tarkuç, S. (author), Houtepen, A.J. (author), Eelkema, R. (author), Siebbeles, L.D.A. (author), Grozema, F.A. (author)Destructive quantum interference has been shown to strongly reduce charge tunneling rates across molecular bridges. The current consensus is that destructive quantum interference occurs in cross-conjugated molecules, while linearly conjugated molecules exhibit constructive interference. Our experimental results on photoinduced charge transfer in...journal article 2015