SEM-EDX hyperspectral data analysis for the study of soil aggregates

Scanning electron microscopy coupled with microanalysis (SEM-EDX) is an important analytical tool for the morphological and chemical characterization of different types of materials. In many applications, SEM-EDX elemental maps are usually used and processed as images, thus flattening and reducing the spectroscopic information contained in...

The role of the micron-scale in reactive transport processes

Quantitative predictions for durability issues are necessary to adapt the formulations of cement blends with novel supplementary cementitious materials. These predictions are usually carried out with reactive transport models which are solved at the macroscopic scale. Upscaling laws are necessary to ensure that effective transport properties...

Ceramic-faience hybrids were used to recycle bronze in North-Western European Iron Age egg-shaped crucibles

We investigated the characteristics of a group of 13 Middle Iron Age egg-shaped crucibles and crucible fragments from Tilburg (The Netherlands). We used a combination of optical and chemical analyses, including hand-held XRF, microCT scanning and 3-D printing polarizing light microscopy and SEM-EDX. The chemical analyses confirmed that the...

The role of smalt in complex pigment mixtures in Rembrandt’s Homer 1663: combining MA-XRF imaging, microanalysis, paint reconstructions and OCT

As part of the NWO Science4Arts REVISRembrandt project (2012–2018), novel chemical imaging techniques were developed and applied to the study of Rembrandt’s late experimental painting technique (1651–1669). One of the unique features in his late paintings is his abundant use of smalt: a blue cobalt glass pigment that he often combined with...

Simulation of self-healing of dolomitic lime mortar

In the present research a test procedure was set up to reproduce self-healing on lime-based (both pure calcium and magnesium-calcium) mortar specimens in laboratory. After few months testing, during which the specimens were subjected to wet-dry cycles, thin sections of the specimens were prepared and observed by Polarization and Fluorescence...