Nutrients release and melanoidins formation during thermal hydrolysis of waste activated sludge and implications in downstream processes

This thesis research investigated the dynamics of nutrient release and the formation of melanoidins during thermal hydrolysis processes (THP) of waste activated sludge (WAS) preceding mesophilic anaerobic digestion (AD). In Chapter 2, a fractionation of THP-sludge allowed for researching the distribution of nutrients and melanoidins over the...

Release of phosphorus through pretreatment of waste activated sludge differs essentially from that of carbon and nitrogen resources: Comparative analysis across four wastewater treatment facilities

The accumulation of phosphorus in activated sludge in wastewater treatment plants (WWTPs) provides potential for phosphorus recovery from sewage. This study delves into the potential for releasing phosphorus from waste activated sludge through two distinct treatment methods—thermal hydrolysis and pH adjustment. The investigation was conducted...

Role of the composition of humic substances formed during thermal hydrolysis process on struvite precipitation in reject water from anaerobic digestion

Thermal hydrolysis process (THP) is a widely used pre-treatment method in the anaerobic digestion (AD) of waste municipal sewage sludge. A post AD dewatering step of the digestate produces a liquid stream called reject water. THP increases the concentration of humic substances (HSs) and nutrients in the produced reject water. Struvite...

Effects of thermal hydrolysis process-generated melanoidins on partial nitritation/anammox in full-scale installations treating waste activated sludge

Thermal hydrolysis process (THP) is a well-established anaerobic digestion (AD) pre-treatment technology. Despite the THP benefits the pre-treatment increases the concentrations of nutrients and melanoidins in the digestate reject water after dewatering. The increased concentrations of nutrients and melanoidins formed during THP-AD can impact...

Accumulating ammoniacal nitrogen instead of melanoidins determines the anaerobic digestibility of thermally hydrolyzed waste activated sludge

Full-scale thermal hydrolysis processes (THP) showed an increase in nutrients release and formation of melanoidins, which are considered to negatively impact methanogenesis during mesophilic anaerobic digestion (AD). In this research, fractionation of THP-sludge was performed to elucidate the distribution of nutrients and the formed...

Influence of humic substances created in THP on partial nitritation step of PN/A reactors

Anaerobic digestion (AD) is an effective and economical in secondary sludge management. Thermal hydrolysis process (THP) is a reliable pre-treatment method to improve the biodegradability of sludge. Partial nitritation and anammox process (PN/A) is a suitable method used to remove nitrogen in reject water which has a low COD/N ratio. However,...

Recalcitrant compounds from thermally hydrolysed sewage sludge

Thermal hydrolysis (TH) has been widely applied to sewage sludge treatment to improve downstream anaerobic digestion (AD) by enhancing organic solids hydrolysis and subsequent biogas productivity. However, TH also has several drawbacks, including the formation of recalcitrant compounds, which are anaerobically non-biodegradable and even...

Evaluation of a full-scale suspended sludge deammonification technology coupled with an hydrocyclone to treat thermal hydrolysis dewatering liquors

Suspended sludge deammonification technologies are frequently applied for sidestream ammonia removal from dewatering liquors resulting from a thermal hydrolysis anaerobic digestion (THP/AD) process. This study aimed at optimizing the operation, evaluate the performance and stability of a full-scale suspended sludge continuous stirred tank...

Effect of Melanoidins and Metals on Hydrolysis in Anaerobic Digestion

Sludge management has gained importance over the years due to high sludge treatment and disposal cost, stringent disposal laws, and a need to move towards sustainable energy production. Anaerobic Digestion (AD) of waste activated sludge (WAS) is a favoured sludge stabilisation technique due to its low energy footprint. Hydrolysis – the first...

Effects of thermal hydrolysis process (THP) on struvite crystallisation from reject water of anaerobically digested sludge

Various technologies have been implemented in wastewater treatment plants (WWTPs) to generate clean effluent with minimised impacts on the environment. Thermal hydrolysis process (THP) and struvite crystallisation reactors are two examples of these technologies. THP generates humic-like substances, known as melanoidins, that are presumed to...

Ammonia removal from thermal hydrolysis dewatering liquors via three different deammonification technologies

The benefits of deammonification to remove nitrogen from sidestreams, i.e., sludge dewatering liquors, in municipal wastewater treatment plants are well accepted. The ammonia removal from dewatering liquors originated from thermal hydrolysis/anaerobic digestion (THP/AD) are deemed challenging. Many different commercial technologies have been...

Treatment of sidestream dewatering liquors from thermally hydrolised and anaerobically digested biosolids

A long term operation (22 months) of the sidestream treatment plant at the water and resource recovery facility at the Tilburg sewage works in The Netherlands is presented. This plant treats dewatering reject liquor from thermally hydrolysed (THP) and mesophillic anaerobically digested (MAD) biosolids. The sidestream plant is comprised of a...

Evaluation of compounds generated in the thermal hydrolysis process on microbial activities in partial nitritation/anammox process

Anaerobic digestion (AD) is a traditional technique to treat sewage sludge and produce biogas. Thermal hydrolysis process (THP) is a feasible pretreatment for AD by improving the biodegrdability of organic compounds. Partial nitritation/anammox (PN/A) process could be applied in side-stream for treating the reject water from AD since the reject...