Bifunctionality of Re Supported on TiO₂ in Driving Methanol Formation in Low-Temperature CO₂ Hydrogenation

Low temperature and high pressure are thermodynamically more favorable conditions to achieve high conversion and high methanol selectivity in CO₂ hydrogenation. However, low-temperature activity is generally very poor due to the sluggish kinetics, and thus, designing highly selective catalysts active below 200 °C is a great...

Synthesis and characterization of Ag-ion-exchanged zeolite/TiO2 nanocomposites for antibacterial applications and photocatalytic degradation of antibiotics

This paper investigates the synthesis, antibacterial, and photocatalytic properties of silver ion-exchanged natural zeolite/TiO2 photocatalyst nanocomposite. Zeolite is known to have a porous surface structure, making it an ideal substrate and framework in different nanocomposites. Moreover, natural zeolite has a superior thermal and chemical...

The Role of Vacancies in a Ti₂CT_x MXene-Derived Catalyst for Butane Oxidative Dehydrogenation

MXenes are a new family of 2D carbides or nitrides that have attracted attention due to their layered structure, tunable surface groups and high electrical conductivity. Here, we report for the first time that the Ti₂CT_x MXene catalyses the selective oxidative dehydrogenation of n-butane to butenes and 1,3-butadiene....

3D-Printed Metal–Organic Framework-Derived Composites for Enhanced Photocatalytic Hydrogen Generation

Direct ink writing technique is used to 3D print Ti-metal–organic framework (MOF) NH₂-MIL-125 mixed with boehmite dispersal. Pt is also deposited onto 3D-printed monolith using atomic layer deposition (ALD) to offer additional catalytic sites. The Ti-MOF-derived powder sample and the pyrolyzed 3D-printed monolith samples are...

3D Printed Scaffolds for Monolithic Aerogel Photocatalysts with Complex Geometries

Monolithic aerogels composed of crystalline nanoparticles enable photocatalysis in three dimensions, but they suffer from low mechanical stability and it is difficult to produce them with complex geometries. Here, an approach to control the geometry of the photocatalysts to optimize their photocatalytic performance by introducing carefully...

Surface functionalized N-C-TiO₂/C nanocomposites derived from metal-organic framework in water vapour for enhanced photocatalytic H₂ generation

Surface-functionalized nitrogen/carbon co-doped polymorphic TiO₂ phase junction nanoparticles uniformly distributed in porous carbon matrix were synthesized by a simple one-step pyrolysis of titanium based metal–organic framework (MOF), NH₂-MIL-125(Ti) at 700 °C under water vapour atmosphere. Introducing water vapour...

Tunable Photodetectors via In Situ Thermal Conversion of TiS₃ to TiO₂

In two-dimensional materials research, oxidation is usually considered as a common source for the degradation of electronic and optoelectronic devices or even device failure. However, in some cases a controlled oxidation can open the possibility to widely tune the band structure of 2D materials. In particular, we demonstrate the controlled...

Influence of SiO₂, TiO₂ and Fe₂O₃ nanoparticles on the properties of fly ash blended cement mortars

This study explores the effects of different types of nanoparticles, namely nano-SiO₂ (NS), nano-TiO₂ (NT), and nano-Fe₂O₃ (NF) on the fresh properties, mechanical properties, and microstructure of cement mortar containing fly ash as a supplementary cementitious material. These nanoparticles existed...

Synthesis of a rationally designed multi-component photocatalyst pt:Sio₂:Tio₂ (p25) with improved activity for dye degradation by atomic layer deposition

Photocatalysts for water purification typically lack efficiency for practical applications. Here we present a multi-component (Pt:SiO₂:TiO₂ (P25)) material that was designed using knowledge of reaction mechanisms of mono-modified catalysts (SiO₂:TiO₂, and Pt:TiO₂ ) combined with the...

Sub-nanoscale Surface Engineering of TiO₂Nanoparticles by Molecular Layer Deposition of Poly(ethylene terephthalate) for Suppressing Photoactivity and Enhancing Dispersibility

In this work, we report molecular layer deposition (MLD) of ultrathin poly(ethylene terephthalate) (PET) films on gram-scale batches of ultrafine particles for the first time. TiO2 P25 nanoparticles (NPs) are coated up to 50 cycles in an atmospheric-pressure fluidized-bed reactor at 150 °C using terephthaloyl chloride and ethylene glycol as...

Inkjet printing of Sc-Doped TiO₂ with enhanced photoactivity

Here we report the methodology for nanocomposite fabrication based on the inkjet printing technique. Doped TiO₂ nanoparticles with Sc contents up to 10 wt.% were synthesized and adapted towards a facile fabrication of microscale structures and thin film printing. Implementation of the state-of-the-art low-temperature synthesis...

The white of the 20th century: an explorative survey into Dutch modern art collections

White pigments were abundantly used in 20th century paintings, and relate to several degradation risks such as titanium white mediated photocatalytic binder degradation or zinc soap formation. Knowledge about the white pigments that were used is essential for risk assessments of 20th century collections. In this study, a representative set of...

Photocatalytic activity of functionalized nanodiamond-TiO₂ composites towards water pollutants degradation under UV/Vis irradiation

Pristine nanodiamonds (NDs) obtained by detonation, or functionalized by different treatments, namely oxidation, hydrogenation and amination, were used to synthesize composites by insertion in TiO₂ matrixes. The different treatments of the NDs lead to materials containing diverse texture properties and surface chemistry...

Selective Activation of C−H Bonds in a Cascade Process Combining Photochemistry and Biocatalysis

Selective oxyfunctionalizations of inert C−H bonds can be achieved under mild conditions by using peroxygenases. This approach, however, suffers from the poor robustness of these enzymes in the presence of hydrogen peroxide as the stoichiometric oxidant. Herein, we demonstrate that inorganic photocatalysts such as gold–titanium dioxide...