Modifying TiO2 Nanoparticles by Atomic Layer Deposition for Enhanced Photocatalytic Water Purification

Photocatalysts, contrary to conventional catalysts, utilize light to drive a reaction. By absorption of photons, electrons are excited and reach higher states to initiate a redox reaction. This principle can be broadly used to produce chemicals such as hydrogen via the reduction of water or transform carbon dioxide into solar fuels, i.e.,...

Aggregation Phenomena in Atomic Layer Deposition: Bridging Macro and Nano

Atomic layer deposition (ALD) is a gas-phase thin film technology that boasts atomic-level control over the amount of material being deposited. A great deal of research effort has been devoted to the exploitation of ALD precision for the synthesis of nanostructures other than thin films such as supported nanoparticles (NPs). ALD is not only...

Gas-phase Deposition of Thin Aluminium Oxide Films at Ambient Conditions

Particles are widely used in the chemical industry as raw material and end product. In many applications of particles, it is advantageous to give them a coating that can either protect the particle from outside influences or give it an additional function. Technologies to provide micron-sized particles with relatively thick coatings (in the...

Gas-Phase Deposition of Ultrathin Aluminium Oxide Films on Nanoparticles at Ambient Conditions

We have deposited aluminium oxide films by atomic layer deposition on titanium oxide nanoparticles in a fluidized bed reactor at 27 ± 3 °C and atmospheric pressure. Working at room temperature allows coating heat-sensitive materials, while working at atmospheric pressure would simplify the scale-up of this process. We performed 4, 7 and 15...

Continuous production of nanostructured particles using spatial atomic

In this paper, the authors demonstrate a novel spatial atomic layer deposition (ALD) process based on pneumatic transport of nanoparticle agglomerates. Nanoclusters of platinum (Pt) of ?1?nm diameter are deposited onto titania (TiO2) P25 nanoparticles resulting to a continuous production of an active photocatalyst (0.12–0.31?wt. % of Pt) at a...