Copper-based coordination polymers from thiophene and furan dicarboxylates with high isosteric heats of hydrogen adsorption

Journal article (2014)
Department
ChemE/Catalysis Engineering (AS) (TU Delft)
Copyright: © 2014 RSC
DOI: https://doi.org/doi:10.1039/C4CE00145A
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Published Date

27-03-2014

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Source:

CrystEngComm, 2014,16

Faculty

Applied Sciences

Department

ChemE/Catalysis Engineering

Abstract

Self-assembled Cu-based coordination polymers derived from thiophene-2,5-dicarboxylic acid (Cu-TDC) and furan-2,5-dicarboxylic acid (Cu-FDC) were synthesized via a solvothermal method and their H2 adsorption behaviour was investigated and contrasted with isophthalic acid (Cu-m-BDC) and terephthalic acid (Cu-BDC) derivatives. Both heterocyclic-based coordination polymers exhibit low surface areas (

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