Control of interpenetration of copper-based MOFs on supported surfaces by electrochemical synthesis

Journal article (2016)
Department
Chemical Engineering (AS) (TU Delft)
Copyright: © 2016 RSC
DOI: https://doi.org/doi:10.1039/C5CE02462E
More Info
expand_more

Published Date

11-01-2016

Reuse Rights

Other than for strictly personal use, it is not permitted to download, forward or distribute the text or part of it, without the consent of the author(s) and/or copyright holder(s), unless the work is under an open content license such as Creative Commons.

Source:

CrystEngComm, 2016, Advance Article

Faculty

Applied Sciences

Department

Chemical Engineering

Abstract

A study of a copper-based metal–organic framework (MOF) synthesized by an electrochemical route is presented. Morphological and adsorption properties of the MOF synthesized as bulk powder and on supported copper surfaces were investigated. Differences in these properties and structural refinement studies indicate that when 4,4?,4??-s-triazine-2,4,6-triyl-tribenzoic acid (H3TATB) is used as linker interpenetration can be prevented when the structure is grown on a surface.

Files

C5ce02462e.pdf
(pdf | 1.71 Mb)