Effect of hydrodynamic slip on the rotational dynamics of a thin Brownian platelet in shear flow

Abstract

The classical theory by Jeffery predicts that, in the absence of Brownian fluctuations, a thin rigid platelet rotates continuously in a shear flow, performing periodic orbits. However, a stable orientation is possible if the surface of the platelet displays a hydrodynamic slip length comparable to or larger than the thickness of the platelet. In this article, by solving the Fokker-Plank equation for the orientation distribution function and corroborating the analysis with boundary integral simulations, we quantify a threshold Péclet number, above which such alignment occurs. We found that for smaller than, but larger than a second threshold, a regime emerges where Brownian fluctuations are strong enough to break the platelet's alignment and induce rotations, but with a period of rotation that depends on the value of. For below this second threshold, slip has a negligible effect on the orientational dynamics. We use these thresholds to classify the dynamics of graphene-like nanoplatelets for realistic values of and apply our results to the quantification of the orientational contribution to the effective viscosity of a dilute suspension of nanoplatelets with slip. We find a non-monotonic variation of this term, with a minimum occurring when the slip length is comparable to the thickness of the particle.