In this study, activated carbon (AC) was synthesized by chemical activation process from rice husk, with the BET surface area of 2180 m²/g. Chitosan/poly(ethylene oxide) (PEO)/AC nanofibrous membrane (CPANM) was synthesized by electrospinning process. The average fiber diameter was found to be 83 ± 12.5 nm. Incorporation of AC lead to increase in the surface area of CPANM than chitosan/PEO fiber (CPF) by 371 m²/g. X-ray photoelectron spectroscopy survey and narrow scan analysis further proved the presence of AC in the membrane. CPANM showed higher adsorption capability than CPF. Analysis of the mechanism of heavy metals adsorption by CPANM and CPF hypothesized that, (NH2) is the only active group in CPF, whereas both (NH2) and (COOH) contributed in adsorption for CPANM. Maximum adsorption capacity of CPANM for Cr(VI), Fe(III), Cu(II), Zn(II), and Pb(II) ion was found to be 261.1, 217.4, 195.3, 186.2, and 176.9 mg g⁻¹ respectively.

In this study, the effect of graphene nanoplatelets (GNP)/distilled water nanofluid on the thermal performance of evacuated tube solar collector (ETSC) water heater was experimentally investigated. The mass percentage of GNP was considered at 0.025, 0.5, 0.075 and 0.1 wt%. The physical and thermal properties of the GNP nanofluids including stability, specific heat capacity, viscosity and thermal conductivity were investigated. The thermal efficiency tests on the solar collector were carried out for varying volumetric flow rate of 0.5, 0.1, and 1.5 L/min while the ASHRAE standard 93–2003 was considered to calculate the efficiency of the collector. The results indicated that the solar collector thermal efficiency gave enhancement up to 90.7% at a flow rate of 1.5 L/min when the GNP nanofluid was used as an absorption medium. The results indicated that by increasing the mass percentage of nanoparticles, thermal energy gain also increases, reaching a higher outlet temperature of the fluid when graphene nanosheets are used.